• Title/Summary/Keyword: ammonia treatment

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Properties of Bentwood for Esthetic Designing by Microwave and Ammonia Solution Treatment

  • Lee, Won-Hee;Bae, Hyun-Mi
    • Journal of the Korea Furniture Society
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    • v.18 no.4
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    • pp.275-281
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    • 2007
  • This study was carried out to know bending process property of bentwood by treatment methods such as microwave and ammonia solution treatment. Bentwood processing was operated on bending-jig form with 60mm and 100mm radius of curvature (ROC). The species was used to Korean red pine (Pinus densiflora). No significant difference was shown in bentwood processing method on ROC. In treatment method, ammonia solution treatment for bentwood was better in dimensional stability and working ability than that of microwave treatment. However, bentwood stress was reduced with ammonia solution treatment. Color of bentwood surface appearance has a dark tendency in ammonia solution treatment. But it seems to beautiful effect of apparent annual ring is rising esthetically by ammonia solution treatment. To utilize wood as a exterior material for living amenity, it has to be closely examined from various angles including surface property, degree of swelling and shrinkage, drying state, retaining strength, durability, safety, and insect damage.

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Towards a novel approach to improve drinking water quality at Dhaka, Bangladesh

  • Serajuddin, Md.;Chowdhury, Md. Aktarul Islam
    • Environmental Engineering Research
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    • v.23 no.2
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    • pp.136-142
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    • 2018
  • The river water source of Saidabad Surface Water Treatment Plant at Dhaka, Bangladesh, is deteriorated too much to be treated by conventional treatment process due to excessive ammonia pollution. In order to improve the raw water quality before it enters into the main treatment chain, a pilot study was conducted for pre-treatment of the raw water. The objective is to investigate the rate of reduction of ammonia using the Meteor pilot, a biological pretreatment system, which is a laboratory scale Moving Bed Biofilm Reactor with a nominal volume of hundred liters, filled with 50 L of Meteor 660 media. The reduction of ammonia was quite significant on average 73%, while the reduction of COD was in a range from 20 to 60%. The Meteor pilot was able to treat and nitrify the raw water and produce an effluent that respects the guarantee of ammonia < $4.0mg\;NH_3-N/L$ when the raw water ammonia concentration was < $15mg\;NH_3-N/L$. The study identified operating parameters necessary to achieve the desired goal of adequate ammonia removal. The study results would benefit a range of systems across the country by providing guidance on the design and operation of a biological pre-treatment system for ammonia removal.

Development of Mass Transfer Models for Ammonia Flux Estimation from Sewage Treatment Plants (하수처리장에서의 암모니아 플럭스 산정을 위한 물질전달모형 개발)

  • Sa, Jae-Hwan;Jeon, Eui-Chan;Jeong, Jae-Hak
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.701-711
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    • 2006
  • Sewage treatment plants located near to large cities emit extremely higher concentration of odorous materials. This study evaluated flux profiles of ammonia emitted from the water surface of sewage treatment plants using a dynamic flux chamber. Also, an ammonia overall mass transfer coefficient and a mass transfer model was developed in order to estimate fluxes of ammonia using environment parameters and the flux from the sewage treatment plants. The developed mass transfer model was evaluated through a fitness analysis. Comparison modeled flux applying empirical overall mass transfer coefficients of ammonia and measured ammonia flux show a high linearity with 0.977. The flux ratio of 1.282 demonstrated highly statistical fitness, also. Modeled flux using the mass transfer model was compared with measured flux. In result, it indicated that empirical overall mass transfer coefficients were similar to measured flux. The mass transfer model using the empirical overall mass transfer coefficient developed in this study was proved to be an easy and effective method to make accurate and precise predictions for ammonia flux discharged from sewage treatment plants.

The Correlation between Ammonia Emissions and Bedding Materials in a Cow House

  • Phan, Nhu-Thuc;Sa, Jae-Hwan;Jeon, Eui-Chan;Lee, Sang-Rak
    • Asian Journal of Atmospheric Environment
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    • v.4 no.1
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    • pp.33-41
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    • 2010
  • Because ammonia from livestock production may substantially contribute to environmental pollution, emissions from all possible sources (housing systems, manure storage, manure application, outside grazing) should be reduced. The purpose of this study was to investigate the effect of different bedding materials on ammonia emissions in a cow house. By applying a combination of four treatment types: treatment $1-T_1$ (sawdust (50%)+sawdust pellets (50%)), treatment $2-T_2$ (sawdust (50%)+corn stalk pellets (50%)), treatment $3-T_3$ (sawdust (100%)), and treatment $4-T_4$ (sawdust (50%)+palm kernel meal pellets(50%)) as bedding materials in a cow house, the effects of such treatments on ammonia flux were assessed in approximately one month. The magnitude of ammonia emissions (mg $m^{-2}\;min^{-1}$) varied in the following order: $T_1$(2.226), $T_4$(2.052), $T_2$(1.845), and $T_3$(1.712). The patterns of pH had a decreasing trend for all bedding treatments during the experiment, and there was no significant relationship with ammonia flux. The results reveal that the most important factor influencing ammonia emissions is the physical structure of the bedding types.

Adsorption of Ammonia on the Sulfuric Acid Treated ACF

  • Kim, K.H.;Shin, C.S.
    • Carbon letters
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    • v.2 no.2
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    • pp.109-112
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    • 2001
  • For the adsorption of ammonia, activated carbon fibers (ACFs) were subjected to sulfuric acid treatment in order to modify the surface functional groups. The surface acid and base value of ACFs were measured using titration and FT-IR spectrometry. SEM was used to investigate the surface morphology. Acid treatments by $H_3PO_4$, $H_2SO_4$, and $HNO_3$ were performed to increase the adsorption capacity of $NH_3$. As a result, Cellulose-based ACF has high adsorption capacity for ammonia. The ammonia removal efficiency of ACF was the maximum which was treated by 15 wt% sulfuric acid at $100^{\circ}C$ for 60 min. The average pore diameter little increased from $19{\AA}$ to $20.8{\AA}$ and the specific surface area of ACF considerably decreased and acid values increased by 15 wt% sulfuric acid treatment. Ammonia reacted with sulfonyl radicals. After adsorption of ammonia, white material was grown on the surface of ACF through the adsorption of ammonia and it was determined to ammonium sulfate.

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Dyeing Behavior of Cotton Fibers Treated with Liquid Ammonia, NaOH, and NaOH/Liquid Ammonia (액체암모니아, 수산화나트륨, 수산화나트륨/액체암모니아 처리한 면의 염색성)

  • 배소영;이문철;김홍성;이영희;김경환
    • Textile Coloration and Finishing
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    • v.6 no.3
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    • pp.1-7
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    • 1994
  • Cotton fiber and NaOH-mercerized cotton fiber had been treated by liquid ammonia and were dyed with two direct dyes, C.I. Direct Red 2 and Blue 1. The effect of the treatment on the rate of dyeing, dye adsorption isotherm, and affinity were studied. The rate of dyeing was increased in the order of NaOH-mercerized> NaOH/liquid ammonia-treated > liquid ammonia-treated>Untreated cotton irrespective of kind of dyes. The rate of dyeing for NaOH-treated fiber considerably increased, whereas liquid ammonia-treated or NaOH/liquid ammonia-treated did not because the structural transformation was not enough for the dyes to penetrate easily into the liquied ammonia-treated cottons. The time of half-dyeing was considerably reduced by mercerizing with NaOH, but lengthened by liquid ammonia treatment because of increased equilibrium dye exhaustion especially in dyeing with C.I. Dierect Red 2. In spite of a short time of the ammonia treatment for 4 seconds, the equilibrium exhaustions of both of direct dyes, C.I. Direct Red 2 and C.I. Direct Blue 1, were increased in proportion to internal volume of treated cotton under a condition of fixed affinity.

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Plasticization of Domestic Wood Treated with Liquid Amonia(I)-Equipment and Preliminary Test (액체암모니아를 이용한 국산재의 가소화(I) -처리장치 및 기초실험)

  • 강호양
    • Journal of the Korea Furniture Society
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    • v.11 no.2
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    • pp.55-60
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    • 2000
  • Liquid ammonia treatment known as the most effective Wood plasticization method, was applied to two typical domestic species, Pinus densiflora, Castanea crenata. Small specimens of 30mm width, 300mm length and two thicknesses, 5 or 10mm, were used. For 5mm thick Specimens, Pinus densiflora was quite well plasticized iker 4 hour liquid ammonia treatment, while Castanea crenata was not plasticized even after 4 hour treatment. Specimens of 10mm thick Pinus densiflora were hardly plasticized, but those with kerfs were bent somewhat easily, With the increase of liquid ammonia treatment time the thermal conductivity of Pinus densiflora increased, while that of Castanea crenata didn't Presteaming before liquid ammonia treatment didn't improve the plasticization of both species.

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Development of Activated Graphite Felt Electrode Using Ozone and Ammonia Consecutive Post Treatments for Vanadium Redox Flow Batteries (오존, 암모니아 순차적 처리를 통한 바나듐 레독스 흐름 전지용 활성화 카본 펠트 전극 개발)

  • CHOI, HANSOL;KIM, HANSUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.4
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    • pp.256-262
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    • 2021
  • A carbon felt electrode was prepared using ozone and ammonia sequential treatment and applied as an electrode for a vanadium redox flow battery (VRFB). The physical and electrochemical analyses demonstrate that the oxygen groups facilitate nitrogen doping in the carbon felt. Carbon felt (J5O3+NH3), which was subjected to ammonia heat treatment after ozone treatment, showed higher oxygen and nitrogen contents than carbon felt (J5NH3+O3), which was subjected to ammonia heat treatment first and then ozone treatment. From the charging/discharging of VRFB, the J5O3+NH3 carbon felt electrode showed 14.4 Ah/L discharge capacity at a current density of 150 mA /cm2, which was 15% and 33% higher than that of J5NH3+O3 and non-activated carbon felt (J5), respectively. These results show that ozone and ammonia sequential treatment is an effective carbon felt activation method to increase the performance of the vanadium redox flow battery.

The Effect of Extrusion Treatment on Aqueous Ammonia Soaking Method in Miscanthus Biomass Pretreatment (억새 바이오매스 전처리에서 압출 처리가 액상 암모니아 침지 처리에 미치는 영향)

  • Bark, Surn-Teh;Koo, Bon-Cheol;Choi, Yong-Hwan;Moon, Youn-Ho;Ahn, Seung-Hyun;Cha, Young-Lok;Kim, Jung-Kon;An, Gi-Hong;Suh, Sae-Jung;Park, Don-Hee
    • New & Renewable Energy
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    • v.6 no.4
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    • pp.6-14
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    • 2010
  • Pretreatment of cellulosic biomass is necessary before enzymatic saccharification and fermentation. Extrusion is a well established process in food industries and it can be used as a physicochemical treatment method for cellulosic biomass. Aqueous ammonia soaking treatment at mild temperatures ranging from 60 to $80^{\circ}C$ for longer reaction times has been used to preserve most of the cellulose and hemicellulose in the biomass. The objective of this study was to evaluate the effect of extrusion treatment on aqueous ammonia soaking method. Extrusion was performed with miscanthus sample conditioned to 2mm of particle size and 20% of moisture content at $200^{\circ}C$ of barrel temperature and 175rpm of screw speed. And then aqueous ammonia soaking was performed with 15%(w/w) ammonia solution at $60^{\circ}C$ for 1, 2, 4, 8, 12 hours on the extruded and raw miscanthus samples respectively. In the combined extrusion-soaking treatment, most compositions removal occurred within 1~2 hours and on a basis of 1 hour soaking treatment values, cellulose was recovered about 85% and other compositions, including hemicellulose, are removed about 50% from extruded miscanthus sample. The combined extrusion-soaking treated and soaking only treated samples were subjected to enzymatic hydrolysis using cellulase and ${\beta}$-glucosidase. The enzymatic digestibility value of combined extrusion-2 hours soaking treated sample was comparable to 12 hours soaking only treated sample. It means that extrusion treatment can shorten the conventional long reaction time of aqueous ammonia soaking. The findings suggest that the combination of extrusion and soaking is a promising pretreatment method to solve both problems for no lignin removal of extrusion and long reaction time of aqueous ammonia soaking.

Ammonia half-saturation constants of sludge with different community compositions of ammonia-oxidizing bacteria

  • Kayee, Pantip;Rongsayamanont, Chaiwat;Kunapongkiti, Pattaraporn;Limpiyakorn, Tawan
    • Environmental Engineering Research
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    • v.21 no.2
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    • pp.140-144
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    • 2016
  • Owing to the kinetic differences in ammonia oxidation among ammonia-oxidizing microorganisms (AOM), there is no standard set of kinetic values that can be used as a representative set for nitrifying wastewater treatment plant (WWTP) design. As a result, this study clarified a link between the half-saturation constants for ammonia oxidation (Ks) and the dominant ammonia-oxidizing bacterial (AOB) groups in sludge from full-scale WWTPs and laboratory-scale nitrifying reactors. Quantitative polymerase chain reaction analyses revealed that AOB affiliated with the Nitrosomonas oligotropha cluster were the dominant AOM groups in the sludge taken from the low-ammonia-level WWTPs, while AOB associate with the Nitrosomonas europaea cluster comprised the majority of AOM groups in the sludge taken from the high-ammonia-level WWTPs and nitrifying reactors. A respirometric assay demonstrated that the ammonia Ks values for the high-ammonia-level WWTPs and nitrifying reactors were higher than those of the low-ammonia-level plants. Using the Ks values of available AOM cultures as a reference, the Ks values of the analyzed sludge were mainly influenced by the dominant AOB species. These findings implied that.different sets of kinetic values may be required for WWTPs with different dominant AOM species for more accurate WWTP design and operations.