• Journal of Environmental Science International
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• v.23 no.8
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• pp.1409-1418
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• 2014

Foundry has an important economic value in the industry. However, the generation of air pollutants like particulate and odor are serious. Due to the unavoidable usage of molding sand, particulate occurs in almost all the processes. That accounts for the majority of respirable dust in the size less than $10{\mu}m$ As well as particulate, over 22 species of odor-causing gases and VOCs including hydrogen sulfide and ammonia are occurred. Therefore, the development of equipment that can simultaneously remove TVOC and particulate is regarded as an essential research. In this study, the spraying absorbent system was connected with the shear bag filter for the purpose to remove TVOC and particulate simultaneously. Maximization of process efficiency for the affective factors like the powder combination and injection method is conducted. The experiment was performed at the de-molding process of one foundry plant. Through these devices, the removal efficiency of more than 95% for TVOC was achieved with the absorbent that composed by 800 mesh Activated carbon (80%) and 300 mesh zeolite (20%). Also, the durability and economic evaluation were assessed. In the result of Durability assessment, the available recovery to maintain the deodorizing effect at 90% was counted to 350 degree.

• Membrane and Water Treatment
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• v.9 no.1
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• pp.17-21
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• 2018

A series of laboratory scale experiments were performed to investigate the feasibility of membrane separation technology for natural rubber (NR) wastewater treatment and reuse. Three types of spiral wound membranes were employed in the cross-flow experiments. The NR wastewater pretreated by sand filtration and cartridge filtration was forced to pass through the ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes successively. The UF retentate, which containing abundant proteins, can be used to produce fertilizer, while the NF retentate is rich in quebrachitol and can be used to extract quebrachitol. The permeate produced by the RO module was reused in the NR processing. Furthermore, about 0.1wt% quebrachitol was extracted from the NR wastewater. Besides, the effluent quality treated by the membrane processes was much better than that of the biological treatment. Especially for total dissolved solids (TDS) and total phosphorus (T-P), the removal efficiency improved 53.11% and 49.83% respectively. In addition, the removal efficiencies of biological oxygen demand (BOD) and chemical oxygen demand (COD) exceeded 99%. The total nitrogen (T-N) and ammonia nitrogen (NH4-N) had approximately similar removal efficiency (93%). It was also found that there was a significant decrease in the T-P concentration in the effluent, the T-P was reduced from 200 mg/L to 0.34 mg/L. Generally, it was considered to be a challenging problem to solve for the biological processes. In brief, highly resource utilization and zero discharge was obtained by membrane separation system in the NR wastewater treatment.

• Journal of Environmental Science International
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• v.25 no.11
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• pp.1493-1498
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• 2016

The efficiencies of Gang-Byeon sewage treatment facilities, which are based on GPS-X modelling, were analysed and used to design recycle water treatment processes. The effluent of an aeration tank contained total kjeldahl nitrogen (TKN) of 1.8 mg/L with both C-1 and C-2 conditions, confirming that most ammonia nitrogen ($NH_3{^+}-N$) was converted to nitrate nitrogen ($NO_3{^-}-N$). The concentrations of $NH_3{^+}-N$ and $NO_3{^-}-N$ were found to be 222.5 and 227.2 mg/L, respectively, with C-1 conditions and 212.2 and 80.4 mg/L with C-2 conditions. Although C-2 conditions with higher organic matter yielded a slightly higher nitrogen removal efficiency, sufficient denitrification was not observed to meet the discharge standards. For the total nitrogen (T-N) removal efficiency, the final effluent concentrations of T-N were 293.8 mg/L with biochemical oxygen demand (BOD) of 2,500 mg/L, being about 1.5 times lower than that (445.3 mg/L) with BOD of 2,000 mg/L. Therefore, an external carbon source to increase the C/N ratio was required to get sufficient denitrification. During the winter period with temperature less than $10^{\circ}C$, the denitrification efficiency was dropped rapidly even with a high TKN concentration (1,500 mg/L). This indicates that unit reactors (anoxic/aerobic tanks) for winter need to be installed to increase the hydraulic retention time. Thus, to enhance nitrification and denitrification efficiencies, flexible operations with seasons are recommended for nitrification/anoxic/denitrification tanks.

• KSBB Journal
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• v.24 no.3
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• pp.291-295
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• 2009

This study performed verification experiment for the removal of total nitrogen in sewage from a Town M village sewage treatment plant using YPNR processes. The total nitrogen discharged after the denitrification process was maintained at a level of 8-15 mg/L, which results in the total nitrogen removal efficiency above 68% on average. The total nitrogen components in discharged water consisted of 16% of ammonia nitrogen, 6% of nitrite nitrogen, and 77% of nitrate nitrogen, which reaches a 95% nitrification efficiency. Hence, the YPNR advanced treatment process used in this study can be successfully applied to sewage treatment.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.6B
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• pp.669-675
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• 2006

Intermittent aerobic digestion experiments using a sequencing batch reactor (SBR) were carried out in this study. Aeration ratio was found to be an important operation factor for the reduction of solids and nitrogen. As the sludge digested, organic nitrogen was released from the solids and oxidized to nitrate nitrogen. Biological denitrification was also significant and the denitrification rate was limited by aeration ratio. Under the condition of 0.25-0.75 of aeration ratio, acclimation of ammonia nitrogen was not observed and pH were preserved near neutral in the intermittent aerobic digestion. As the aeration ratio increased, solids reduction was increased whereas dissolved nitrogen removal was decreased. Based on the experiments, 17-2% of VSS reduction and over 80% of dissolved nitrogen removal were practicable by intermittent aerobic digestion using a SBR when the MSRT were designed 8-32 days and aeration ratio was operated about 0.25-0.75.

• Journal of Korean Society of Water and Wastewater
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• v.13 no.2
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• pp.55-65
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• 1999

AF(anaerobic filter)/BAF(biological aerated filter) system and UASB(upflow anaerobic sludge blanket)/BAF system, of which system effluents were recirculated to the anaerobic reactors in each system, were operated in order to investigate the performance in simultaneous removal of organics and nitrogen in high-strength dairy wastewater. Advanced anaerobic treatment processes of AF and UASB were evaluated on applicability as pre-denitrification reactors, and BAF was also evaluated on the performance in oxidizing the remaining organics and ammonia nitrogen. At system HRTs of 4.0 to 4.5 days and recirculation ratios of one to three, the AF/BAF system could achieve more than 99% of organics removals and 64 to 78% of total nitrogen removals depending upon the recirculation ratio. Although the UASB/BAF system also showed more than 99% of organics removals, total nitrogen removals in the UASB/BAF system were 53 to 66% which are lower than those in the AF/BAF system at the corresponding recirculation ratios. Optimum recirculation ratios considering simultaneous removal of organics and nitrogen and cost-effectiveness, were in the range of two to three. The upflow AF packed with crossflow module media, as a primary treatment of the anaerobic reactor/BAF system, showed better performances in denitrification, SS removals, and gas production than the UASB. Higher loading rate of suspended solids from the UASB increased the backwashing times in the following BAF. Especially, at a recirculation ratio of three in the UASB/BAF system, the increase in head loss due to clogging in the BAF caused frequent backwashing, at least once d day. The BAF showed the high nitrification efficiency of average 99.2% and organics removals more than 90% at organics loading rate less than $1.4KgCOD/m^3/d$ and $COD/NH_3-N$ ratio less than 6.4. It was proved that the simplified anaerobic reactor/BAF system could maximize the organics removal and achieve high nitrogen removal efficiencies through recirculation of system effluents to the anaerobic reactor. The AF/BAF system can, especially, be a cost effective and competitive alternative for the simultaneous removal of organics ana nitrogen from wastewaters.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.9
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• pp.879-886
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• 2010

This study investigated the removal characteristics of highly concentrated $NH_4$-N and $PO_4$-P by struvite crystallization using converter slag as a seed crystal. The optimal pH range for removal and recovery of $NH_4$-N and $PO_4$-P by struvite crystallization was measured to be 8.0~8.75, in which total removal efficiencies for $NH_4$-N and $PO_4$-P by struvite precipitation and crystallization were 34.3~61.0% and 91.0~96.2%, respectively. The maximum removal efficiencies for $NH_4$-N and $PO_4$-P by struvite crystallization were 29.4% at pH 8.5 and 65.1% at pH 8.0, respectively. The removal efficiency of $NH_4$-N by struvite crystallization decreased with increasing calcium ion concentration. The analysis results of SEM, EDS and XRD exhibited that $NH_4$-N and $PO_4$-P in meta-stable region of struvite crystallization could be eliminated through formation of magnesium ammonia phosphate (MAP) and hydroxyapatite (HAp) on seed crystals by struvite precipitation and crystallization.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.32 no.2
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• pp.180-185
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• 1999

Rotating Biological Contactor (RBC) was tested for the treatment of artificial rearing water in n simulated aquaculture system. Performance of RBC on the removal of TAN and COD was evaluated by controlling hydraulic residence time (HRT). As HRT of RBC was increased, TAN removal rate ana removal efficiency of RBC and TAN concentration of rearing water were increased, but COD removal rate was decreased. Total alkalinity consumption rate was increased by increasing HRT of RBC. Ratio between total alkalinity consumption rate and TAN removal rate was 7.73. HRT for maintaining lowest TAN and COD concentration of artificial rearing water was 14,6 minutes and at that condition TAN and COD concentration of the water was 1.28 and $5.59 g/m^3$, respectively.

• Journal of Animal Environmental Science
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• v.11 no.3
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• pp.207-214
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• 2005

To reduce phosphorus and nitrogen from the swine wastewater, magnesium chloride $(MgCl_2)$ was used as a reaction material for both soluble phosphorus (SP) and ammonia-nitrogen (AN). The initial value of SP content were $471mg/\ell$ far aeration test and $515 mg/\ell$ for NaOH addition test, but treatment of $MgCl_2$ reduced SP value to $5mg/\ell$ and $4mg/\ell$. The removal efficiency of $MgCl_2$ for SP showed $99\%$ in both treatment, and the removal efficiency of $MgCl_2$ for AN showed $15\%$ with treatment of aeration and $18\%$ with NaOH. All the experiments were done in a low temperature of 6 to $8^{\circ}C$, suggesting that this methods are possibly able to apply to a cold weather conditions. Moreover, the struvite crystal structure was identified by electronic microscope, implying that $MgCl_2$ is an effective material for removal of SP from swine wastewater In addition to the increased removal rate of the AN in wastewater, both $MgCl_2$ and $KH_2PO_4$ were added. The SP value was reduced by $99\%$ with 2g addition of the phosphate. The SP removal rate by 4g addition of the phosphate was increased only as $15-19\%$, but the quantity of removed SP was higher than that of 2g addition test. The value of AN was not reduced as expected by adding $KH_2PO_4$. The AN removal rate were low as $18\%$ and $15\%$ like as the level of the former test with $MgCl_2$ alone. Therefore, it is needed to examine closely the reaction mechanism f3r reducing both SP and AN simultaneously.

• Korean Journal of Materials Research
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• v.26 no.12
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• pp.726-732
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• 2016

In this study, we used activated carbon(AC) as a carbon source, along with zeolite, to prepare spherical carbons using sucrose, starch and phenolic resin(PR) as binder material. The physicochemical characteristics of the three samples(AZ4P, AZ6P and AZ8P) were examined by BET, XRD, SEM, EDX, $H_2S/NH_3$ gas adsorption, compressive strength and ignition test techniques. Through comparative analysis of the compressive strength and ignition test results the AZ8P sample was found to have the best hardness and the highest temperature resistance capacity. After activation, the AZ8P sample had the best $H_2S$ adsorption capacity, and AZ6P was the most suitable for the adsorption of ammonia.