• Title/Summary/Keyword: ammonia nitrogen

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Estimation of influening factors for efficient anaerobic digestion of high strength ammonia-nitrogen wastewater (고농도 암모니아성 질소 폐수의 효과적인 혐기성 처리를 위한 영향 인자 평가)

  • Park, Seyong;Park, Junghoon;Na, Hoysung;Kim, Moonil
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.5
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    • pp.649-658
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    • 2012
  • In this study, the influencing factors for efficient anaerobic digestion of high strength ammonia-nitrogen wastewater removal were investigated by testing biochemical methane potential test. In the influencing factors, the trace metals which could increase activity of anaerobic microorganisms, microbial concentration and types were evaluated. In the results, trace metals supplementation showed gas production amount higher than those without addition of trace metals. Among the tested trace metals, B, Ni, and Se were preferable to gas production. In the result of gas production according to the microbial concentration, the amount of gas production was proportional to the microbial concentration. In addition, the shortest lag time and the fastest gas production rate were achieved when the highest microbial concentration was tested. granule-type microorganism produced more gas than suspended-type microorganism. In conclusion, the efficient anaerobic digestion for high strength ammonia-nitrogen wastewater removal could be achieved by applying necessary trace metals injection and high concentration granule type microorganism.

Synthesis of High Purity Aluminum Nitride Nanopowder in Ammonia and Nitrogen Atmosphere by RF Induction Thermal Plasma (RF 유도결합 열 플라즈마를 이용한 암모니아와 질소분위기에서 고순도 AlN 나노 분말의 합성)

  • Kim, Kyung-In;Choi, Sung-Churl;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Journal of the Korean Ceramic Society
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    • v.51 no.3
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    • pp.201-207
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    • 2014
  • High-purity aluminum nitride nanopowders were synthesized using an RF induction thermal plasma instrument. Ammonia and nitrogen gases were used as sheath gas to control the reactor atmosphere. Synthesized AlN nanopowders were characterized by XRD, SEM, TEM, EDS, BET, FTIR, and N-O analyses. It was possible to synthesize high-purity AlN nanoparticles through control of the ammonia gas flow rate. However, additional process parameters such as plasma power and reactor pressure had to be controlled for the production of high-purity AlN nanopowders using nitrogen gas.

Treatment of Piggery Wastewater by Anoxic-Oxic Biofilm Process (준혐기-호기 생물막 공정을 이용한 돈사폐수 처리)

  • 임재명;한동준
    • Journal of environmental and Sanitary engineering
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    • v.12 no.2
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    • pp.1-12
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    • 1997
  • This research aims to develop biofilm process for the nutrient removal of piggery wastewater. The developed process is the four stage anoxic-oxic biofilm process with recirculation of the final effluent. In summery, the results are as follows: 1. Nitrification in the piggery wastewater built up nitrite because of the high strength ammonia nitrogen. The nitrification of nitrobacter by free ammonia was inhibited in the total ammonia nitrogen loading rate with more than 0.2 kgNH$_{3}$-N/m$^{3}$·d. 2. The maximal total ammonia nitrogen removal rate was obtained at 22$\circ $C and without being affected by the loading rate. But total oxidized nitrogen production rate was largely affected by loading rate. 3. Autooxidation by the organic limit was a cause of the phosphorus release in the aerobic biofilm process. But the phosphorus removal rate was 90 percent less than the influent phosphorus volumetric loading rate of above 0.1 kgP/m$^{3}$·d. Therefore, the phosphorus removal necessarily accompanied the influent loading rate. 4. On the anoxic-oxic BF process, the total average COD mass balance was approximately 67.6 percent. Under this condition, the COD mass removal showed that the cell synthesis and metabolism in aerobic reactor was 42.8 percent and that the denitrification in anoxic reactor was 10.7 percent, respectively.

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Mechanical properties of epoxy composites reinforced with ammonia-treated graphene oxides

  • Park, Mi-Seon;Lee, Sangmin;Lee, Young-Seak
    • Carbon letters
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    • v.21
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    • pp.1-7
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    • 2017
  • The effects of ammonia-treated graphene oxide (GO) on composites based on epoxy resin were investigated. Ammonia solutions of different concentrations (14-28%) were used to modify GO. Nitrogen functional groups were introduced on the GO surfaces without significant structural changes. The ammonia-treated GO-based epoxy composites exhibited interesting changes in their mechanical properties related to the presence of nitrogen functional groups, particularly amine ($C-NH_2$) groups on the GO surfaces. The highest tensile and impact strength values were 42.1 MPa and 12.3 J/m, respectively, which were observed in an epoxy composite prepared with GO treated with a 28% ammonia solution. This improved tensile strength was 2.2 and 1.3 times higher than those of the neat epoxy and the non-treated GO-based epoxy composite, respectively. The amine groups on the GO ensure its participation in the cross-linking reaction of the epoxy resin under amine curing agent condition and enhance its interfacial bonding with the epoxy resin.

Ammonia-nitrogen Removal in Sea Water by Using Electrolysis (전기분해법에 의한 해수내의 암모니아성 질소 제거)

  • 이병헌;이제근;길대수;곽순열
    • Journal of Aquaculture
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    • v.10 no.4
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    • pp.435-438
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    • 1997
  • Biological ammonia removal system have been used conventionally for the seawater fish farming. But this process requires long hydraulic retention times and large area. Also it has a trouble of NO3-N accumulation in the system. Therefore, this study was conducted to find out the feasibility of effective nitrogen removal efficiency in the sea water fish farming system by electolysis. As the result, electrolysis system showed a good ammonia and nitrate nitrogen removal and E. coli sterilization efficiencies. Because of the high salinities in the seawater for electron transfer, electrolysis is an effictive water treatment process for seawater fish farming. The relation among ammonia removal efficiency, hydraulic retention time (HRT) and electric wattage (watt) with 10 mm electrod distance isas follow ; log [$NH_4^$+-N(%)]=0.431log(HRT(sec)$\times$Watt)+0.88(r=0.950) And the relation between ammonia removal efficiency and residual chlorine concentration in the seawater is as follow; $$NH_4^+-N(%)=48\cdotlog[Residual\;chlorine(mg/\ell)+28(r=0.892)$$

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Effects of phosphorus concentration and nitrogen sources on photoautotrophic microalgae Scenedesmus dimorphus applied wastewater treatment (인 농도 및 질소원이 광합성 미세조류인 Scenedesmus dimorphus를 이용한 하수고도처리에 미치는 영향)

  • Kim, Tae-Hyeong;Cho, Yong-Beom;Park, Jeong-Eun;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.3
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    • pp.325-329
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    • 2013
  • A result of estimating the effects of initial phosphorus concentration and nitrogen sources on removal of nitrogen and phosphorus in wastewater treatment using Scenedesmus dimorphus shows that there was no difference in microalgae growth amount and nitrogen removal amount by phosphorus concentration(5 ~ 60 mg/L). On the other hand, as initial phosphorus concentration increased, phosphorus removal amount was increased by luxury uptake of microalgae. Scenedesmus dimorphus preferred to ammonia when ammonia(40 mg/L) and nitrate(40 mg/L) are simultaneously presented and nitrogen removal rate of ammonia was high at approximately 20 mg/L/day.

Removal of ammonia by packed bed bioreactor using immobilized nitrifiers (고정화 생물 반응기에 의한 암모니아 제거)

  • 김병진;이경범;서근학
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.177-182
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    • 1999
  • Nitrifier consortium entrapped in Ca-alginate bead were packed into aerated packed bed bioreactor and non aerated packed bed bioreactor and the performances of two bioreactors were evaluated for the removal of ammonia nitrogen from synthetic aquaculture water. Total ammonia nitrogen(TAN) removal rate was decrease in aerated packed bed bioreactor below 0.3hr of hydraulic residence time(HRT), but increased in non aerated packed bed bioreactor until 0.5hr of HRT. At HRT of 0.05hr, TAN removal rate of non aerated packed bed bioreactor was about 335g TAN/㎥/day and the optimum ratio of packing height and inside diameter of reactor (H/D) was 4. The performance of two bioreactors indicated that non aerated packed bed bioreactor was better than aerated packed bed bioreactor in ammonia removal from synthetic aquaculture water.

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Determination of Ammonia Nitrogen by Color Saturation Measurement System (채도측정시스템을 이용한 암모니아성 질소의 정량방법)

  • Lee, Hyeong-Choon
    • Journal of Environmental Health Sciences
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    • v.38 no.2
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    • pp.136-141
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    • 2012
  • Objectives: The objective of this study was to investigate whether the ammonia nitrogen concentration of aqueous samples such as drinking water can be determined by measuring the saturation of the samples colored by indophenol method. Methods: A color saturation measurement system was constructed by connecting a notebook computer to an image acquisition device composed of a PC camera and a light source, and was then used to measure the saturation of samples colored by blue indophenol complex. Results: Between two available light sources, a fluorescent lamp was selected due to its demonstrating better linearity between color saturation and ammonia nitrogen concentration. Prediction by quadratic regression was more accurate than by linear regression, and prediction by quadratic regression in the concentration range of 0.1-1.0 $mg/l$ was more accurate than in the concentration range of 0.0-1.0 $mg/l$. Regression-based predictions over 0.25 $mg/l$, 0.55 $mg/l$ and 0.75 $mg/l$ concentrations were implemented both by spectrophotometric method and by measuring color saturation. In the case of 0.25 $mg/l$, the predicted concentration by spectrophotometric method was $0.256{\pm}0.0076\;mg/l$ and the predicted concentration by measuring color saturation was $0.246{\pm}0.0086\;mg/l$ (p=0.051). In the case of 0.55 $mg/l$, they were $0.561{\pm}0.0068\;mg/l$ and $0.564{\pm}0.0166\;mg/l$ (p=0.660). In the case of 0.75 $mg/l$, they were $0.755{\pm}0.0139\;mg/l$ and $0.762{\pm}0.0088\;mg/l$ (p=0.215). Conclusions: There were no statistically significant differences (p>0.05) between the data from the two methods in all three of the concentrations. Therefore, the color saturation measurement method proposed in this paper may be considered applicable for determining the ammonia nitrogen concentration of aqueous samples such as drinking water.

Removal of Ammonia Nitrogen, Manganese and Arsenic in The Ion Exchanged Natural Zeolite (이온 치환된 천연 제올라이트를 활용한 암모니아성 질소, Mn, As의 제거)

  • Lee, Kyung-Han;Kil, Bo-Min;Ryu, Cheol-Hwi;Hwang, Gab-Jin
    • Membrane Journal
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    • v.29 no.5
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    • pp.237-245
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    • 2019
  • Ammonia nitrogen is well known as a substance that causes the eutrophication with a phosphorus in the water, because it is contained in the industrial wastewater, agricultural and the stockbreeding wastewater. In addition, manganese (Mn) and arsenic (As) are included in the mine treated water, etc., and are known as a source of water pollution. Natural zeolites are used to remove ammonia nitrogen in water but it have a low adsorption capacity. In order to improve the low adsorption capacity of the natural zeolite, ion substitution was carried out with $Na^+$, $Ca^{2+}$, $K^+$ and $Mg^{2+}$. The adsorption capacity and removal rate of ammonia nitrogen ($NH_4-N$) were the highest at 0.66 mg/g and 89.8% in $Na^+$ ion exchanged zeolite. Adsorption experiments of Mn and As were performed using ion exchanged zeolites. Ion exchanged zeolite with $Mg^{2+}$ showed high adsorption capacity and removal rates of Mn and As.

Influence of the Novel Urease Inhibitor Hydroquinone on Growing Lamb Nitrogen Utilization

  • Zhang, Y.G.;Shan, A.S.;Bao, J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.7
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    • pp.992-997
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    • 2002
  • Two in vivo experiments were conducted to evaluate the effect of novel urease inhibitor hydroquinone (HQ) on ammonia release rate from urea hydrolysis, nitrogen balance, nutrient digestibility and efficiency of microbial protein synthesis. In Exp. 1, twelve crossbred cannulated lambs were randomly assigned within initial body weight block to one of four HQ treatments, which included 0 (control), 30, 60 or 80 mg HQ/kg DM intake. Ammonia concentration and pH of ruminal fluid were immediately measured at 0, 2, 4, 6 and 8 h after feeding. Increasing the dose of HQ tended (p<0.15) to linearly decrease NH3 formation. The ammonia peak concentration (2 h post-feeding) in animals receiving HQ was approximately one-half of that in animals not receiving HQ (p<0.01), and a relatively sustained ammonia release could be obtained at the dose of 30 or 60 mg HQ/kg DM. In Exp. 2, sixteen intact crossbred lambs (weight $40{\pm}0.8kg$) were used in a $2{\times}2$ factorial design experiment. The four rations consisting of soybean meal-based (SBM) or urea-based (Urea) nitrogen source with or without HQ (S1, S0, U1 and U0) were fed in digestion and N balance trials. Apparent digestibility of major nutrients except that of ADF was not affected by either nitrogen source or addition of HQ. Regardless of nitrogen source, supplementation of HQ significantly improved ADF digestibility (p<0.05). The various ration had no effects on N metabolism in the presence of HQ. There was significant difference between total purine derivatives (PD), estimated efficiency of microbial N synthesis (p<0.05) and urea-N excretion (p<0.01) in the urine for the SBM ration and for the Urea ration. However, HQ had little influence on efficiency of microbial N synthesis as proportion of daily intake of total tract digestible OM (p>0.05). No interactions between main nitrogen source and HQ were measured throughout the trial. Results of this study suggest that addition of HQ to ration may improve ADF digestion with having no negative effect on N metabolism and microbial protein production.