• Title/Summary/Keyword: ambient $CO_2$

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C Gas Sensors Operating at Relatively Low Temperature (저 전력용 CO가스 감지소자)

  • Lee, Sung Pil;Lee, Yong Hyun;Lee, Duk Dong;Sohn, Byung-Ki
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.23 no.6
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    • pp.766-772
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    • 1986
  • SnO2/Pt CO gas sensors operating at relatively low temperature were fabricated, and their performance characteristics were measured. When the mixing weight ratio of SnO2/Pt was 99.5/0.5, a good sensitivity to CO gas was obtained. And the experimental results were in consistent with the gas sensing model. The optimum operating, temperature range of the fabricated devices was 50-80\ulcorner and the response time was 15 sec. at 80\ulcorner in 1000 ppm CO ambient. The humidity dependence of sensitibity to CO gas could be reduced by adding hydrophokbic silica to the mixture of SnO2 and Pt. For the practical application of the fabricated devices, a CO gas alarming system has been developed.

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Thermal instability of Co-silicides formed by Co and Co/Ti bilayer (Co 및 Co/Ti 이중막에 의해 형성된 Co-실리사이드의 열적 불안정성)

  • 장지근;엄우용;신철상;장호정
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.11
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    • pp.105-111
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    • 1996
  • We have invetigated the characteristics of thermal instability of Co-silicides annealed at 850$^{\circ}$C ~ 1000$^{\circ}$C for 10~90 minutes in a furance with N$_{2}$ ambient. In our experiments, Co-silicides and Co/Ti bilayer silicides were formed by depositing (Co, Ti) films on the clean Si substrates in an E-beam evaporator and performing the RTA annelaing. The sheet resistances of Co-silicides formed form Co exhibited the nearly constant value under the post-annealing time above 900$^{\circ}$C showing the increase of 30% and 60% under the conditions annealed at 900$^{\circ}$C and 1000$^{\circ}$C for 30minutes. On the other hand, there were no remarkable changes in the sheet resistance sof Co-silicides formed form Co/Ti bilayer under the post-annealing conditons below 1000$^{\circ}$C.

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An Expeditious Room Temperature Stirring Method for the Synthesis of Isoxazolo[5,4-b]quinolines

  • Niralwad, Kirti S.;Shingate, Bapurao B.;Shingare, Murlidhar S.
    • Journal of the Korean Chemical Society
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    • v.55 no.5
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    • pp.805-807
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    • 2011
  • The synthesis of different derivatives of isoxazolo[5,4-b]quinoline by the cyclization reaction of various substituted oximes of quinoline using mild base at ambient temperature. The formation of isoxazolo[5,4-b]quinoline, as a consequence of cheaper and more readily available $K_2CO_3$ and DMF participating in the reaction, is documented.

Low Temperature Storage of Rough Rice Using Cold-Air in Winter(I) - Storage Characteristics after Rough Rice Cooling - (겨울철 냉기를 이용한 벼의 저온저장(I) - 벼 냉각 후 저장특성 -)

  • Lee J. S.;Han C. S.;Ham T. M.;Yon K. S.
    • Journal of Biosystems Engineering
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    • v.30 no.3 s.110
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    • pp.155-160
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    • 2005
  • The objective of this research was to establish a domestically available cooling storage technique by cold-air in winter, using winter cool air ventilation fur determining rough rice cooling method in the storage and dry bin. The rough rice storage characteristics of two test conditions, winter cool-air ventilation storage and ambient temperature storage, were evaluated from January to July 2001, using a storage and dry bin of 300-ton capacity. Results of this research are as follows: Grain temperature was from $-5.1\~-8.5^{\circ}C$ after winter cool-air ventilation, and grain initial temperature for ambient temperature bin storage was $0.3\~1.9^{\circ}C$. Moisture content of rough rice decreased from $0.28\;to\;0.93\%$ and from $1.53\;to\;1.92\%$ to compare with original moisture contents for winter cool-air ventilation, and for ambient temperature bin storage, respectively. Broken ratio of brown rice from winter cool-air ventilation bin increased from $0.16\;to\; 0.92\%$, and brown rice broken ratio was from $2.24\;to\;2.86\%$ for ambient temperature bin storage to compare with initial broken ratio. Hardness of stored rice increased along storage period increase in alt storage methods, and cooling bin storage increased rice hardness of 0.271kgf: this increasing was lower then the other methods from 0.059 to 2.239kgf. Germination rates were decreased approximately 9.03, 3.14 and $3.20\%$ for upper, middle, and bottom of ventilating winter air bin, respectively, and germination rates of 2.70, 3.47 and $4.14\%$ were approximately decreased for upper, middle, and bottom parts of ambient temperature bin storage, respectively.

Ambient CO2 Adsorption and Regeneration Performance of Zeolite and Activated Carbon (제올라이트와 활성탄을 이용한 대기 중 CO2 흡착 및 재생 특성)

  • Park, Il-Gun;Hong, Min-Sun;Kim, Byum-Seok;Kang, Ho-Geun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.5
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    • pp.307-311
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    • 2013
  • Direct Air Capture (DAC) technology using reusable energy is a plausible process to capture $CO_2$ from non-point sources. In this paper, adsorption and desorption were repeatedly tested using low concentration $CO_2$. Three types of adsorbents were examined in cyclic $CO_2$ adsorption and thermal regeneration. Adsorption capacities of zeolite 5A, zeolite 13X and activated carbon were 21 mg/g, 12 mg/g and 6 mg/g, respectively. Zeolite 5A shows the highest adsorption capacities after cyclic thermal regeneration.

Behavior of contaminated liquid CO2 droplets in the deep sea

  • Nguyen, Thao;Hwang, Jin Hwan
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.257-257
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    • 2015
  • Carbon Capture and Storage with ocean sequestration is being considered as one of the most effective option for reducing the $CO_2$ net flux from atmosphere nowadays. But it is still possible for $CO_2$ substance to leaks out from transport pipeline or from the under seabed storage sites and causing damage to ambient environment. The behavior of liquid $CO_2$ under droplet shape would be strongly affected by the presence of other contaminants such as $SO_2$ comes from processing processes. This presentation shows the behavior in the sea water of pure liquid $CO_2$ droplets as well as droplets that consist of $SO_2$ substances. The study uses computational fluid dynamic models in comparison with experimental data from other previous researchers. Droplet of liquid $CO_2$ is assumed to be released at several depths in deep ocean, with other environmental conditions are set up respectively. All calculations are conducted with many different ratio of contaminant $SO_2$ to provide fundamental data of those particles rising characteristics. The effect of contaminants on the behavior of $CO_2$ droplets would be clearly shown through the results of particle deformation, terminal rising velocity happen due to buoyancy force driving from the difference in density of $CO_2$ substance and ocean water around.

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Effects of Elevated CO2 and Temperature on the Leaf Morphological Responses of Quercus serrata and Quercus aliena, Potential Natural Vegetation of Riverine (CO2농도 및 온도 상승이 하천변 잠재자연식생인 졸참나무와 갈참나무 잎의 형태학적 반응에 미치는 영향)

  • Cho, Kyu-Tae;Kim, Hae-Ran;Jeong, Heon-Mo;You, Young-Han
    • Journal of Wetlands Research
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    • v.15 no.2
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    • pp.171-177
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    • 2013
  • This study was conducted to find the leaf morphological responses of Quercus serrata and Q. aliena which are potential natural vegetation of riverine in Korea under elevated $CO_2$ and increased temperature. Rising $CO_2$ concentration was treated with 1.6 times than control(ambient) and increased temperature with $2.2^{\circ}C$ above the control(ambient) in the glass greenhouse. As a result, leaf width length, leaf lamina weight and leaf area of Q. serrata and Q. aliena was respectively increased, and number of leaves and specific leaf area(SLA) was decreased by elevated $CO_2$ and temperature. Leaf width length, leaf lamina length, leaf lamina weight, number of leaves, leaf area, and specific leaf area of Q. serrata were not statistically significant difference between control and treatment. Leaf width length and leaf weight of Q. aliena was increased, but specific leaf area was decreased. These results indicated that Q. aliena was to be sensitive than Q. serrata in response to global warming situation. According to the principal component analysis(PCA), two oak species were arranged based on factor 1 and 2 in the control and warming treatment. And change on the warming treatment was clearly distinguishable from the Q. aliena than Q. serrata.

Development of Relationship between Air Quality and Rain Acidity (대기질 - 강우산성도 관계식의 개발)

  • 구자공;유동준
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.3
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    • pp.45-51
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    • 1986
  • The simple and precise model for the estimation of rain acidity from the ambient air quality was developed using the theory of wet scrubber and the chemical equilibria of $SO_2, CO_2, and H_2O$ system. From the measured mixing height, and from the developed relationship between NTU (=number of transfer units) and the concentration of $SO_2$(aq) in rain drops, the HTU (= height equivalent to one transfer unit, i.e. mass transfer resistance) was estimated, and validated with the field-measured data. In Seoul, Korea where the effect of $SO_2$ on rainfall acidity is as high as 84% and the average mixing height is 1 km, the average HTU of $SO_2$ system was found to be 191.5m. The important parameters affecting HTU were identified as rainfall intensity and initial ambient concentration of $SO_2$, and their effects on the value of overall volumetric mass transfer coefficient were quantified.

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Effects of elevated CO2 concentration and increased temperature on leaf quality responses of rare and endangered plants

  • Jeong, Heon-Mo;Kim, Hae-Ran;Hong, Seungbum;You, Young-Han
    • Journal of Ecology and Environment
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    • v.42 no.1
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    • pp.1-11
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    • 2018
  • Background: In the study, the effects of elevated $CO_2$ and temperature on the nitrogen content, carbon content, and C:N ratio of seven rare and endangered species (Quercus gilva, Hibiscus hambo, Paliurus ramosissimus, Cicuta virosa, Bupleurum latissimum, Viola raddeana, and Iris dichotoma) were examined under control (ambient $CO_2$ + ambient temperature) and treatment (elevated $CO_2$ + elevated temperature) for 3 years (May 2008 and June 2011). Results: Elevated $CO_2$ concentration and temperature result in a decline in leaf nitrogen content for three woody species in May 2009 and June 2011, while four herb species showed different responses to each other. The nitrogen content of B. latissimum and I. dichotoma decreased under treatment in either 2009 and 2011. The leaf nitrogen content of C. virosa and V. raddeana was not significantly affected by elevated $CO_2$ and temperature in 2009, but that of C. virosa increased and that V. raddeana decreased under the treatment in 2011. In 2009, it was found that there was no difference in carbon content in the leaves of the six species except for that of P. ramosissimus. On the other hand, while there was no difference in carbon content in the leaves of Q. gilva in the control and treatment in 2011, carbon content in the leaves of the remaining six species increased due to the rise of $CO_2$ concentration and temperature. The C:N ratio in the leaf of C. virosa grown in the treatment was lower in both 2009 and 2011 than that in the control. The C:N ratio in the leaf of V. raddeana decreased by 16.4% from the previous year, but increased by 28.9% in 2011. For the other five species, C:N ratios increased both in 2009 and 2011. In 2009 and 2011, chlorophyll contents in the leaves of Q. gilva and H. hamabo were higher in the treatment than those in the control. In the case of P. ramosissimus, the ratio was higher in the treatment than that in the control in 2009, but in 2011, the result was the opposite. Among four herb species, the chlorophyll contents in the leaves of C. virosa, V. raddeana, and I. dichotoma did not show any difference between gradients in 2009, but decreased due to the rise of $CO_2$ concentration and temperature in 2011. Leaf nitrogen and carbon contents, C:N ratio, and chlorophyll contents in the leaves of seven rare and endangered species of plant were found to be influenced by the rise and duration of $CO_2$ concentration and temperature, species, and interaction among those factors. Conclusions: The findings above seem to show that long-term rise of $CO_2$ concentration, and temperature causes changes in physiological responses of rare and endangered species of plant and the responses may be species-specific. In particular, woody species seem to be more sensitive to the rise of $CO_2$ concentration and temperature than herb species.

Greenhouse Gas (CH4, CO2, N2O) Emissions from Estuarine Tidal and Wetland and Their Characteristics (온실기체 (CH4, CO2, N2O)의 하구언갯벌 배출량과 배출특성연구)

  • Kim, Deug-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.2
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    • pp.225-241
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    • 2007
  • A closed flux chamber system was used for measuring major greenhouse gas (GHG) emission from tideland and/or wetland soils in estuarine area at Saemankum, Kunsan in southwestern Korea during from months of February to June 2006. Hourly averaged GHG soil emissions were measured two to three times a day during the ebb tide hours only. Site soils were analyzed for soil parameters (temperature, pH, total organic contents, N and C contents in soil) in the laboratory. Soil GHG fluxes were calculated based on the GHG concentration rate of change measured inside a closed chamber The analysis of GHG was conducted by using a Gas Chromatography (equipped with ECD/FID) at laboratory. Changes of daily, monthly GHGs' fluxes were examined. The relationships between the GHG emissions and soil chemical contents were also scrutinized with respect to gas production and consumption mechanism in the soil. Soil pH was pH $7.47{\pm}0.49$ in average over the experimental period. Organic matter contents in sample soil was $6.64{\pm}4.98\;g/kg$, and it shows relatively lower contents than those in agricultural soils in Kunsan area. Resulting from the soil chemistry data, soil nitrogen contents seem to affect GHG emission from the tidal land surface. The tidal soil was found to be either source or sink for the major GHG during the experimental periods. The annual average of $CH_{4}\;and\;CO_{2}$ fluxes were $0.13{\pm}0.86\;mg\;m^{-2}h^{-1}\;and\;5.83{\pm}138.73\;mg\;m^{-2}h^{-1}$, respectively, which will be as a source of these gases. However, $N_{2}O$ emission showed in negative flux, and the value was $-0.02{\pm}0.66\;mg\;m^{-2}h^{-1}$, and it implies tidal land surface act as a sink of $N_{2}O$. Over the experimental period, the absolute values of gas fluxes increased with soil temperature in general. Averages of the ambient gas concentration were $86.8{\pm}6.\;ppm$ in $CO_{2},\;1.63{\pm}0.34\;ppm\;in\;CH_{4},\;and\;0.59{\pm}0.15\;ppm\;in\;N_{2}O$, respectively. Generally, under the presence of gas emission from agricultural soils, decrease of gas emission will be observed as increase in ambient gas concentration. We, however, could not found significant correlation between the ambient concentrations and their emissions over the experimental period. There was no GHG compensation points existed in tide flat soil.