• 한국항공우주학회지
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• 제44권9호
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• pp.789-795
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• 2016

이차 추진제로 많이 쓰이는 알루미늄을 고출력 레이저를 조사하여 공기 중의 산소와 반응시켜 발생되는 알루미늄과 산소의 화학 반응을 레이저 분광분석법을 이용하여 연구를 수행 하였다. 7ns의 펄스 주기와 1064nm의 주파수를 가진 Q-switched Nd:YAG 레이저로 40 - 2500mJ($6.88{\times}10^{10}-6.53{\times}10^{11}W/cm^2$)의 에너지가 공급되었으며, 플라즈마 빛은 echelle 회절 분광기와 ICCD 카메라로 감지하였다. 분광분석을 통하여 알루미늄과 산소의 원자/분자 신호 분석과 현상이 일어나는 플라즈마 환경의 특성 연구를 위해 들뜸 온도(2200K~6600K) 및 전자밀도($3.15{\times}10^{15}{\sim}2.38{\times}10^{16}cm^{-3}$) 계산, 그리고 알루미늄 표면의 크레이터(Crater) 분석을 수행하였다. 본 연구는 고 레이저 복사 조도 환경하에서 발생되는 화학 반응과 플라즈마의 특성을 파악하는 방법을 제시하고 있다.

• 한국분말재료학회지
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• 제20권5호
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• pp.332-337
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• 2013

Recently, self-propagating high-temperature synthesis (SHS), related to metallic and ceramic powder interactions, has attracted huge interest from more and more researchers, because it can provide an attractive, energy-efficient approach to the synthesis of simple and complex materials. The adiabatic temperature $T_{ad}$ and apparent activation energy analysis of different thermit systems plays an important role in thermodynamic studies on combustion synthesis. After establishing and verifying a mathematic calculation program for predicting adiabatic temperatures, based on the thermodynamic theory of combustion synthesis systems, the adiabatic temperatures of the NiO/Al aluminothermic system during self-propagating high-temperature synthesis were investigated. The effect of a diluting agent additive fraction on combustion velocity was studied. According to the simulation and experimental results, the apparent activation energy was estimated using the Arrhenius diagram of $ln(v/T_{ad}){\sim}/T_{ad}$ based on the combustion equation given by Merzhanov et al. When the temperature exceeds the boiling point of aluminum (2,790 K), the apparent activation energy of the NiO/Al aluminothermic system is $64{\pm}14$ kJ/mol. In contrast, below 2,790 K, the apparent activation energy is $189{\pm}15$ kJ/mol. The process of combustion contributed to the mass-transference of aluminum reactant of the burning compacts. The reliability of the simulation results was experimentally verified.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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• pp.175-180
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• 2004

Improving furnace efficiency is a high priority need for aluminum, glass, steel and other metal casting industries. Oxy-fuel combustion is considered to be one of the most effective method to improve thermal efficiency and reduce $NO_x$, SOx and $CO_2$ emissions for high temperature furnaces. The characteristics of an oxy-fuel flame, in particular its shape, radiation profile and exhaust gas composition are considerably different to those of an air-fuel burner. For this reason, a new approach is needed regarding factors such as burner design, power input levels, number and positioning strategies of burners and also control philosophies. In this paper will discuss the latest developments of high performance oxy-fuel combustion reheating furnace system. This high performance oxy-fuel combustion system will be shown to be technologically superior to other types of combustion systems in the areas of fuel efficiency, emissions and productivity.

• 한국추진공학회지
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• 제17권5호
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• pp.47-53
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• 2013

본 연구에서는 고에너지 금속 알루미늄 군입자 연소 화염 분석을 위한 측정기법 개발 연구로서 스펙트로메터를 사용하여 화염 온도와 자발광 스펙트럼을 측정하였다. 마이크로 크기의 알루미늄 군입자 연소 반응시 발생하는 화염온도는 약 2400 K 이상의 초고온이므로 비접촉식 광학 계측 방법을 사용하였으며, 측정을 위해 개발된 기법은 520 nm, 640 nm를 사용하는 이색법을 응용한 방법과 광대역 파장 비교법으로서 각각의 방법은 정밀하게 검증 후 실험에 적용되었다. 연소실 하단에서 화염온도 측정결과 두 방법 모두 2400 K 이상의 화염온도를 확인할 수 있었으며 자발광 측정 결과 알루미늄 연소 반응시 가장 지배적으로 발생하는 화학종인 AlO를 확인할 수 있었다.

• 한국주조공학회지
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• 제33권3호
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• pp.122-126
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• 2013

Recently, heat-resistant aluminum alloy has been re-focused as a downsizing materials for the internal combustion engines. Heat-resistant Al alloy development and many researches are still ongoing for the purpose of improving thermal stability, high-temperature mechanical strength and fatigue properties. The conventional principle of heat-resistant Al alloy is the precipitation of intermetallic compounds by adding a variety of elements is generally used to improve the mechanical properties of Al alloys. Heat resistant aluminum alloys have been produced by CrW homogeneous solid solution to overcome the limit of conventional heat resistant aluminum alloy. From EPMA, it is found that CrW homogeneous soild solution phases with the size of $50-100{\mu}m$ have been dispersed uniformly, and there is no reaction between aluminum and CrW alloy. In addition, after maintaining at high temperature of 573 K, there is no growth of hardening phase, nor desolved, but CrW still exists as a homogeneous solid solution.

• Corrosion Science and Technology
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• 제21권6호
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• pp.476-486
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• 2022

Recently, aluminum 6061 instead of copper alloy is used for cooling heat exchangers used in the internal combustion of engines due to its economic feasibility, lightweight, and excellent thermal conductivity. In this study, aluminum 6061 alloy was anodized with oxalic acid, phosphoric acid, or chromic acid as an anodizing electrolyte at the same concentration of 0.3 M. After the third anodization, FDTS, a material with low surface energy, was coated to compare hydrophobic properties and anti-icing characteristics. Aluminum was converted into an anodization film after anodization on the surface, which was confirmed through Energy Dispersive X-ray Spectroscopy (EDS). Pore distance, interpore distance, anodization film thickness, and solid fraction were measured with a Field Emission Scanning Electron Microscope (FESEM). For anti-icing, hydrophobic surfaces were anodized with oxalic acid, phosphoric acid, or chromic acid solution. The sample anodized in oxalic acid had the lowest solid fraction. It had the highest contact angle for water droplets and the lowest contact hysteresis angle. The anti-icing contact angle showed a tendency to decrease for specimens in all solutions.

• 한국연소학회지
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• 제5권1호
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• pp.31-41
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• 2000

A numerical study was conducted to investigate the combustion phenomena of regular start and unstart processes based on ISL#s RAMAC 30 experiments with different diluent amounts in a ram accelerator. The initial projectile launching speed was 1800m/s which corresponded to the superdetonative speed of the stoichiometric $H_2/O_2$ mixture diluted with $5CO_2\;or\;4CO_2$. In this study, it was found that neither shock nor viscous heating was sufficient to ignite the mixture at a low speed of 1800m/s, as was found in the experiments using a steel-covered projectile. However, we could succeed in igniting the mixtures by imposing a minimal amount of additional heat to the combustor section and simulate the regular start and unstart processes found in the experiments with an aluminum-covered projectile. The numerical results matched almost exactly to the experimental results. As a result, it was found that the regular start and unstart processes depended on the strength of gas mixture, development of shock-induced combustion wave stabilized by the first separation bubble, and its size and location.

• 한국화재소방학회논문지
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• 제26권2호
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• pp.105-111
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• 2012

본 연구에서는 건축외장재로 많이 사용되고 있는 알루미늄복합패널의 일반재와 난연재에 대한 화재성능 비교분석에 관해 연구하였다. 실험방법은 중소형 실험장치 중 콘칼로리미터 실험과 SBI(Single Burning Item)을 적용하여 분석하였다. 그 결과 콘칼로리미터 실험에서 최대 열방출률이 일반 알루미늄복합패널은 $1,293kW/m^2$($75kW/m^2$), 난연 알루미늄복합패널은 $70kW/m^2$($75kW/m^2$)가 측정되었다. SBI 실험에서 화재확산지수가 일반 알루미늄복합패널은 약 743W/s이고 난연 알루미늄복합패널은 약 97 W/s의 값이 측정되었다. 이는 일반 알루미늄복합패널의 경우 건축물 내장재의 성능기준에서 난연기준에도 훨씬 못 미치고, 플래쉬 오버(Flash over) 발생 가능성을 나타내었다. 따라서 이러한 알루미늄복합패널의 화재 위험성을 평가하여 외장재로서 사용 시 갖춰야 할 조건에 대한 기준마련이 시급히 요구된다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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• pp.605-610
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• 2004

Solid propellants allow thrusters to be light-weight, com-pact and robust because they require neither tank nor valve, Moreover, the solid propellant will not leak, spill or slosh. Consequently, the solid propellant thruster is one of the potential candidates for the microthruster. On the other hand, the control of the solid propellant combustion is difficult, since the conventional solid propellant continues to bum until all the stored propellant is consumed. Although particular devices like thrust reverser were designed to control the combustion, these devices were rarely used in the practical rocket motors. These devices rise thruster weight as well as complicate the thruster operation. In this study, a solid propellant microthruster using laser sustained combustion was designed in order to develop a high-efficiency microthruster overcoming the previously-mentioned difficulty. This designed thruster has semiconductor lasers and non-self-combustible solid propellants in addition to the conventional solid propellant thruster. In this designed thruster, the semiconductor laser controls the combustion of the non-self-combustible solid propellant. In order to demonstrate that the solid propellant combustion is controllable with laser, some non-self-combustible solid propellants were irradiated with the laser at a back-pressure of about 1㎪. A 40-W class Neodymium Yttrium Aluminum Garnet (ND:YAG) laser was used as a tentative alternate to the semiconductor laser. This experiment has shown that the solid propellant combustion was controllable with 10- W class laser irradiation.

• 한국화재소방학회논문지
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• 제24권2호
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• pp.89-96
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• 2010

본 연구에서는 건축외장재로 많이 사용되고 있는 알루미늄복합패널의 화재위험성을 평가하기 위하여 외장재 실물 연소실험을 실시하였다. 그 결과 알루미늄복합패널의 빠른 화재확산을 보였으며, 이는 알루미늄 복합패널에 내장된 폴리에틸렌이 연소되면서 화염의 수직확산이 급격히 일어난 것이다. 본 실험에서 알루미늄복합패널의 최고 열방출률은 1,144kW로 나타났으며, 열전대에 의해 측정된 표면온도는 알루미늄의 용융점인 $660^{\circ}C$를 넘는 최고 $903.3^{\circ}C$ 이상 상승하였다. 그러므로 알루미늄복합패널의 화재는 상층으로의 급격한 연소확대나 개구부를 통한 내부로의 화재확산에 의한 큰 피해를 줄 수 있을 것으로 판단된다. 이러한 실물실험에서 얻어낸 결과는 향후 알루미늄복합패널의 모델링 구현과 비교함으로써 알루미늄복합패널의 화재 확산 예측에 적용 될 수 있을 것이다.