• 콘크리트학회논문집
• /
• 제19권5호
• /
• pp.539-547
• /
• 2007

본 연구에서는 폴리머 개질 페이스트의 응결 시간, 건조수축, 강도, 동결융해저항성 및 흡수율에 미치는 결합재량 및 알루미나 분말 혼입량의 영향에 대하여 검토하였다. 그 결과, SBR 및 PAE폴리머 개질 페이스트의 응결 시간은 결합재량이 증가함에 따라 지연되는 경향을 보였다. 폴리머 종류에 관계없이 SBR PAE 폴리머 개질 페이스트의 건조수축은 결합재량 및 알루미나 분말 혼입량이 증가함에 따라 감소하는 경향을 나타내었다. 폴리머 종류에 관계없이 SBR 및 PAE 폴리머 개질 페이스트의 인장 및 부착강도는 결합재량 및 알루미나 분말 혼입량이 증가함에 따라 증가하는 경향을 나타냈다. SBR 및 PAE 폴리머 개질 페이스트의 내구성 지수는 폴리머 종류에 관계없이, 알루미나 분말 혼입량의 증가에 따라 증가하는 경향을 보였다. 폴리머 종류에 관계없이 SBR 및 PAE 폴리머 개질 페이스트의 흡수율은 결합재량 및 알루미나 분말 혼입량이 증가함에 따라 감소하는 경향을 나타내었다.

• Transactions on Electrical and Electronic Materials
• /
• 제16권6호
• /
• pp.338-341
• /
• 2015

Epoxy/micro-sized alumina composite was prepared, and the effects of alumina content on the dielectric properties were investigated in order to develop an insulation material for gas-insulated switchgears (GIS). Nano-sized alumina (average particle size: 30 nm) was also incorporated into the epoxy/micro-sized alumina composite. Dielectric tests were carried out in ASTM D 150, and capacitance (Cp) and dielectric loss (tanδ) were measured. The dielectric constant increased with increasing alumina content in the epoxy/micro-alumina system and the epoxy/micro-alumina/nano-alumina system. As 1,3-diglycidyl glyceryl ether (DGE) content increased, the dielectric constant decreased and dielectric loss increased. This ocurred as a result of the weak electric field enhancement due to homogeneous dispersion of micro- and nano-sized alumina particles in an epoxy composite.

• Transactions on Electrical and Electronic Materials
• /
• 제16권5호
• /
• pp.260-263
• /
• 2015

Epoxy/micro-sized alumina composite was prepared and the effects of alumina content on the electrical and mechanical properties were investigated in order to develop an insulation material for gas insulated switchgear (GIS). Nano-sized alumina (average particle size: 30 μm) was also incorporated into the epoxy/micro-sized alumina composite. An electrical insulation breakdown strength test was carried out in sphere-sphere electrodes and the data were estimated by Weibull statistical analysis. Tensile strength was measured at a crosshead speed of 10 mm/min using a universal testing machine. Alumina content was varied from 0 wt% to 70 wt%.). As micro-sized alumina content increased, insulation breakdown strength increased until 40 wt% alumina content and decreased after that content. The tensile strength of a neat epoxy system was 82.2 MPa and that value for 60 wt% alumina content was 91.8 MPa, which was 111.7% higher than inthe neat epoxy system. The insulation breakdown strength of micro-sized alumina (60 wt%)/nano-sized alumina (1 phr) glycerol diglycidyl ether (GDE) (1 phr) composite was 54.2 MPa, which was 116% higher than the strength of the system without nano-sized alumina.

• 한국전기전자재료학회논문지
• /
• 제31권7호
• /
• pp.496-501
• /
• 2018

In this study, we prepared 40, 45, 50, 55, 60, 65, and 70 wt% content composites filled in epoxy matrix for two micro silica and three micro alumina types for use as a GIS heavy electric machine. As a filler type of epoxy composite, micro silica composites showed excellent AC breakdown strength properties compared to micro alumina composites in the case of electrical properties of micro silica and alumina. The electrical breakdown properties of micro silica composites increased with increasing filler content, whereas those of micro alumina decreased with increasing filler content. In the case of mechanical properties, the micro silica composite showed improved tensile strength and flexural strength compared with the micro alumina composite. In addition, mechanical properties such as tensile strength and flexural strength of micro silica and alumina composites decreased with increasing filler content. This is probably because O-H groups are present on the surface of silica in the case of micro silica but are not present on the surface of alumina in the case of micro alumina.

• The Korean Journal of Ceramics
• /
• 제5권1호
• /
• pp.25-29
• /
• 1999

Complex viscosities of dense alumina slurries over 45% volume density measured with the oscillating method were correlated well with Casson model. Among several monosaccharides and disaccharides studied here, fructose and sucrose showed good rheological properties in making dense alumina slurry plastic compared to other monosaccharides and disaccharides like glucose, galactose, arabinose, xylose and maltose. Sucrose content or additional water content in dense alumina slurry with sucrose contributed to the plasticity of the slurries.

• 폴리머
• /
• 제37권1호
• /
• pp.47-51
• /
• 2013

본 연구에서는 알루미나 나노섬유의 함량을 20에서 100 phr까지 달리하여 알루미나 나노섬유와 분말이 첨가된 에폭시 복합재료의 열전도도 및 파괴인성에 미치는 영향에 대해서 살펴보았다. 열전도도는 열전도도분석기로 측정하였고, 파괴인성은 임계응력세기인자($K_{IC}$) 측정을 통하여 고찰하였다. 모폴로지는 주사전자현미경(SEM)으로 관찰하였다. 실험결과, 알루미나 나노섬유의 함량이 증가함에 따라 열전도도가 향상됨을 확인할 수 있었으며, 알루미나 나노섬유의 함량이 열전도도를 결정하는 중요한 요소임을 알 수 있었다. $K_{IC}$ 값도 알루미나 나노섬유의 함량이 증가할수록 큰 값을 가지는 것을 확인할 수 있었으나 40 phr 이상에서는 오히려 감소하였다. 이는 과량의 알루미나 나노섬유가 에폭시 내에서 서로 뭉침으로 인하여 $K_{IC}$ 값을 감소시킨 것으로 판단된다.

• Transactions on Electrical and Electronic Materials
• /
• 제14권2호
• /
• pp.105-109
• /
• 2013

In order to develop high voltage (HV) insulation materials, epoxy/spherical alumina composites with two different particle sizes (in ${\mu}m$) were prepared and a dynamic mechanical analysis (DMA) and electrical insulation breakdown strength test were carried out in sphere-sphere electrodes and the data were estimated using Weibull statistical analysis. Alumina content varied from 50 to 70 wt%. The electrical insulation breakdown strength for epoxy/alumina (50 wt%) was 44.0 kV/1 mm and this value decreased with increasing alumina content. The effects of insulation thickness and alumina particle size on the insulation breakdown strength were also studied. The insulation thickness varied from 1 mm to 3 mm, and the particle sizes were 7.3 or $40.3{\mu}m$.

• 한국결정성장학회지
• /
• 제10권1호
• /
• pp.48-54
• /
• 2000

kaolin과 수산화알루미늄을 이용하여 mullite를 합성하는데 있어서 출발원료의 조성을 silica rich, stoichiometric, alumina rich 조성으로 준비하여 각각의 원료로부터 mullite를 합성할 때 mullite-seed가 미치는 영향을 연구하였다. 그 결과 silica rich 조성과 stoichiometric 조성에서는 mullite-seed의 첨가량이 증가할수록 꺾임강도값이 증가하며, alumina rich 조성에서는 mullite-seed의 첨가량이 증가할수록 꺾임강도값은 감소하는 경향을 보였다. 같은 양의 mullite-seed를 첨가했을 때 미세구조는 alumina 첨가 함량이 증가할수록 치밀도가 감소하고, aspect ratio는 증가하는 경향을 나타내었다. 순도면에서는 mullite정량결과 모든 조성에서 mullite-seed의 첨가량이 많을수록 합성된 mullite 결정상의 함량이 증가하는 경향을 보였다.

• 한국결정성장학회지
• /
• 제8권1호
• /
• pp.145-150
• /
• 1998

8mol%의 이트리아 안정화 지르코니아에 알루미나를 첨가하여 복합체를 제조하고 이때 알루미나 함량에 따른 전기 및 기계적 성질을 조사하였다. 3-점 곡강도와 파괴강도 값은 알루미나 함량이 20wt%까지 증가하였고, 복합체의 평균입자크기는 알루미나 첨가량이 증가할수록 감소하였다. 5wt%의 알루미나를 첨가하여 $1600^{\circ}C$, 2시간 유지하여 제조한 복합체의 3점 곡강도는 310MPa, 이때 파괴강도는 $7.8MPa\cdot\textrm m^{1/2}$이였다. 복합체의 전기 전도도 값은 알루미나 첨가량이 10wt%까지는 약간 증가하다가 그 이후로는 감소하였다. 알루미나 5wt% 첨가하여 $1600^{\circ}C$, 2시간 소결한 복합체의 전기 전도도는 0.4S/cm이였다.

• 마이크로전자및패키징학회지
• /
• 제6권1호
• /
• pp.11-21
• /
• 1999

For microelectronic packaging application, the crystallizable glass powder in CaO-$A1_2O_3-SiO_2-B_2O_3$system was mixed with various amounts of alumina inclusions (\approx 4 $\mu \textrm{m}$), and its sintering behavior, crystallization behavior, and dielectric constant were examined in terms of vol% of alumina and the reaction between the alumina and the glass. Sintering of the CASB glass powder alone at $900^{\circ}C$ resulted in full densification (99.5%). Sintering of alumina-filled composite at $900^{\circ}C$ also resulted in a substantial denslfication higher than 97% of theoretical density, In this case, the maximum volume percent of alumina should be less than 40%. XRD analysis revealed that there was a partial dissolution of alumina into the glass. This alumina dissolution, however, did not show the particle growth and shape accommodation. Therefore, the sintering of both the pure glans and the alumina-filled composite was mainly achieved by the viscous flow and the redistribution of the glass. Alumina dissolution accelerated the crystallization initiation time at $1000^{\circ}C$ and hindered the densification of the glass. Dielectric constants of both the alumina-filled glass and the glass-ceramic composites were increased with increasing alumina content and followed rule of mixture. In case of the glass-ceramic matrix composites showed relatively lower dielectric constant than the glass matrix composite. Furthermore, as alumina content increased, crystallization behavior of the glass was changed due to the reaction between the glass and the alumina. As alumina reacted with the glass matrix, the major crystallized phase was shifted from wollastonite to gehlenite. In this system, alumina dissolution strongly depended on the particle size: When the particle size of alumina was increased to 15 $\mu\textrm{m}$, no sign of dissolution was observed and the major crystallized phase was wollastonite.