• Journal of Environmental Science International
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• v.7 no.6
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• pp.761-772
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• 1998

This study was performed to determine the optimum coagulant dosing amount for effective treatment of raw water. The removal rate of turbidity and the variations of water qualities according to various dosage of coagulants such as Alum, PAC and PACS were investigated. The optimum coagulant dosing amount to make the lowest turbidity of water were 35mg/ι t of Alum, 30mg/ι of PAC and 10mg/ι of PACS in case of 5 NTU of raw water turbidity, and 30mg/ι of Alum, 25mg/ι of PAC and 10mg/ι of PACS in case of 10 NTU of that, respectively. The removal rates of turbidity at 4 min. and 8 min. of settling time were 10 and 72% of Alum, 44 and 62% of PAC and 25 and 55% of PACS in case of 5 NTU, and 52 and 70% of Alum, 90 and 95% of PAC and 10 and 28% of PACS in case of 10 NTU, respectively. Judging from the settling capability of floc., the reaction time of floe. formation and removal efficiency of turbidity, PAC was evaluated as more effective coagulant than Alum and PACS. Also PAC was regarded as the most effective coagulant when the water supply was changed sharply and the fluctuation of the surface loading occured with wide and sharp in settling basin. pH and alkalinity of the water were decreased with increasing coagulants dosage. But pH and alkalinity were not decreased below 5.8 which is the standard for drinking water quality, and 10mg/ι which is the limit concentration of floc. breakage, respectively. Residual Al of the treated water was decreased with increasing coagulants dosage in case of 5 and 10NTU of raw water turbidity. $KMnO_4$ consumption of the water was decreased with increasing coagulants dosage. The reduction rate of $KMnO_4$ consumption at the optimum coagulants dosage were 39% of Alum. 18% of PAC and 11% of PACS in case of 5 NTU of raw water turbidity, and 42% of Alum, 27% of PAC and 36% of PACS in case of 10 NTU of that, respectively. Any relationship was not found between the removal rate of turbidity and KMnO$_4$ consumption. TOC of the water was a bit decreased with increasing coagulants dosage up to 30mg/ι but not changed above 30mg/ι of coagulants dosage. The degree of TOC reduction was increased in the order of Alum, PAC and PACS treatment. Zeta potential of the colloidal floe. at the optimum coagulants dosage was in the range of -20~-15mV in case of 5 NTU of raw water turbidity and 0~0.5mV in case of 10 NTU of that. respectively. Although the kinds and dosages of coagulants were different, zeta potential range were fixed under the conditions of the best coagulation efficiency.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.1
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• pp.85-89
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• 2008

The purpose of this study is to understand the removal possibility of microalgae using inorganic coagulants in coagulation and sedimentation process for water treatment. Removal of microalgae was studied according to coagulant type(Alum and PAC), coagulation factors(alkalinity, coagulant dosage, and setting time), and size fraction of microalgae. The contribution of applied coagulants for removal of microalgae was also examined. The removal rate of the microalgae by change of alkalinity was most high in 25 mg/L of alkalinity(Alum) as 87.2% and 30 mg/L of that(PAC) as 90.1%. Optimal coagulant dosage to remove the microalgae was 40 mg/L(removal effi.; 88.1%), and PAC was 50 mg/L(removal effi.; 90.1%). Alum was better than the PAC to remove the microlgae. In the water treatment processes such as rapid slow mixing and sedimentation the removal efficiency of microalgae with coagulants was 2 times higher than that of without. In optimal condition, the removal efficiencies of microalgae were nanoplankton > microplankton > picoplankton. Especially, the removal efficiency of the picoplankton was very low as below 30%.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.7
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• pp.495-502
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• 2013

This work was performed to investigate proper condition of coagulation treatment as UF process pretreatment that consider UF permeate flux and residual Al concentration. The coagulant used an alum as $Al_2(SO_4)_3{\cdot}16H_2O$ and PACl (r = 1.5) made this study. The experiment was tested in adjusting conditions such as alum dose, flocculation time and coagulation pH of seawater. Consequently, higher coagulant dose lead to elevation of UF permeate flux while residual aluminium also increased in condition of pH 8.0. The most suitable condition which has a good permeate flux and low residual aluminium, in this works, was coagulant dose of 0.7 mg/L (as Al, alum) and 1.2 mg/L (as Al, PACl) and coagulation pH 6.5. In addition, applying the flocculation time with 1.2 mg/L of PACI reduced. The flocculation time reduced UF permeate flux in using alum.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.3
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• pp.2321-2327
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• 2015

Three coagulants, alum sulfate(alum), poly aluminum chloride(PAC) and poly aluminum silicate chloride (PASC), were used to remove low to high turbidity and TOC in surface and ground blended water. Laboratory experiments and pilot plant experiments were carried out to evaluate the optimal coagulant and its dosage. To determine the optimized coagulant and its dosage, the turbidity, TOC and pH were measured. The experimental results showed the best removal performance using PASC. The optimal dosage of PASC between 3-20 NTU was found to be 15 mg/L in the jar test. In the pilot test, a 15 mg/L PASC dosage was applied and resulted in the efficient removal of turbidity and TOC between 3.6-27 NTU. The removal efficiency of PASC increased with increasing turbidity and TOC.

• Applied Chemistry for Engineering
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• v.17 no.1
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• pp.37-43
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• 2006

The coagulation efficacy of Al-based coagulants (such as Alum, PACS, and PACC) was investigated to ascertain removal efficiencies of turbidity and phosphate with variation of solution pH, coagulant dosages, and pre-dilution ratios. The efficacy of Al-based coagulants was maximized in the pH range of 6~9. Under the initial condition of pH 8, $10mg/L\;{PO_4}^{3-}$, and 20 NTU, Al-based coagulants exhibited a similar efficacy in the removal of turbidity, whereas the removal efficiency of phosphate was clearly dependent on the basicity of coagulants: Alum (0%) > PACS (45~50%) > PACC (70%). At high initial turbidity of 100 NTU, polymeric coagulants, such as PACS and PACC, exhibited a higher removal efficiency of turbidity compared to Alum. In comparison to direct injection of coagulants at low initial turbidity (20 NTU), 500~2000 times pre-diluted Alum, exhibited reduced coagulation efficacy; however, removal efficiencies of turbidity and phosphate increased with the increase of retention time. Pres-diluted PACC exhibited the enhanced coagulation efficacy followed by silght decrease of the removal efficiencies with increase of the retention time. At high initial turbidity of 100 NTU, pre-diluted Alum and PACC exhibited higher removal efficiencies of turbidity and phosphate.

• Journal of Korean Society of Water and Wastewater
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• v.21 no.2
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• pp.243-252
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• 2007

Effects of alum dosage on the particle growth were investigated by monitoring particle counts in a rapid mixing process. Kaolin was used for turbid water sample and several other chemicals were added to adjust pH and ionic strength. The range of velocity gradient and mixing time applied for rapid mixing were $200{\sim}300sec^{-1}$ and 30~180 sec, respectively. Particle distribution in the synthetic water sample was close to the natural water where their turbidity was same. The number of particles in the range of $10.0{\sim}12.0{\mu}m$ increased rapidly with rapid mixing time at alum dose of 20mg/L, however, the number of $8.0{\sim}9.0{\mu}m$ particles increased at alum dose of 50mg/L. The number of $14.0{\sim}25.0{\mu}m$ particles at alum dose of 20mg/L was 10 times higher than them at alum dose of 50mg/L. Dominant particle growth was monitored at the lower alum dose than the optimum dose from a jar test at an extended rapid mixing time(about 120 sec). The number of $8.0{\sim}14.0{\mu}m$ particles was lower both at a higher alum doses and higher G values. At G value of $200sec^{-1}$ and at alum dose of 10-20mg/L, residual turbidity was lower as the mixing time increased. But at alum dose above 40mg/L and at same G value, lower residual turbidity occurred in a short rapid mixing time. Low residual turbidity at G value of $300sec^{-1}$ occurred both at lower alum doses and at shorter mixing time comparing to the results at G value of $200sec^{-1}$.

• Korean Journal of Environmental Agriculture
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• v.19 no.1
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• pp.13-19
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• 2000

Seasonal variations of dominant algae species and the effects of these algae on coagulation and filteration of water treatment were investigated at Chilseo water treatment plant in downstream of Nakdong river from January in 1995 to Desember of 1998. The water quality of Nakdong river was found to be a hyper eutrophic state during the investigation periods. In the measurement, Chlorophyll-a contents ranged $20.7{\sim}180.9{\mu}g/l$ and total nitrogen contents(T-N) and total phosphorus contents(T-P) exceeded more than 3.4mg/l and 0.1mg/l, respectively. The changes in dominant algae species was in the order of Stepanodiscus sp., Asterionella sp., Melosira sp., Microcystis sp. and Synedra sp. from spring to winter. Microcystis sp. especially, was blooming during summer and Synedra sp. and Stepanodiscus sp. during winter. Although most diatomous algae appeared in the water treatment process caused filter clogging and reduced efficiency of coagulation and sedimentation, Synedra sp. and Stepanodiscus sp were revealed as the main trouble algae. Malfunction of water treatment process caused by Synedra sp. and Stepanodiscus sp. started at the algae concentrations of 800cells/ml and 1,820cells/ml, respectively. When chlorophyll-a content was $18.9{\mu}g/l$, the optimum amounts of coagulant were found to be 40mg/l of Alum and 16mg/l of PACS. Under condition of chlorophyll-a content of $154.1{\mu}g/l$, addition of Alum at the level of 75mg/l and PACS at the level of 35mg/l showed the lowest turibidity. The result indicates that increased amounts of the coagulants should be added for a better water treatment as chlorophyll-a contents increased. Addition of Alum at the amount of 60mg/l and 30mg/l of PACS removed Stepanodiscus sp. algae at the rate of 85% and 83%, respectively. In case of Synedra sp., 50mg/l of Alum and 25mg/l of PACS showed removal rates of 79% and 81%, respectively. Synedra sp. algae at the standing crops of 1,500cells/ml started filter clogging and a filtering process was completely inhibited after 8 hours. At this situation the filter clogging by Synedra sp. algae occurred at the depth of 5cm from the top anthracite layer. On the other, other algae did filter clogging at the depth of 10cm.

• Membrane Journal
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• v.16 no.3
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• pp.182-187
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• 2006

The purpose of this study was to investigate effect of coagulation on filtration performance of membrane in submerged MBR system and influence of continuous aeration to reduce fouling of membrane surface on coagulated floc. For this purpose, aeration tank sludge of MBR system was compared with jar-test sludge. The experimental results were analysed in terms of floc size and SRF (Specific resistance of Filtration). The more alum was added, the more content of floc below $10{\mu}m$ reduced and SRF decreased. But compared with jar-test results, it was found that effect of coagulation on MBR floc was reduced. Operation time of membrane in alum added MBR was longer than that in control MBR. But operation time was not proportional to alum dose. It was thought that the result was reason that floc below $10{\mu}m$ was not reduced sufficiently by shear force of continuous aeration. Moreover it was founded that if alum is added more than proper dose, it brings filtration resistance to increase.

• Journal of Environmental Science International
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• v.8 no.5
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• pp.625-631
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• 1999

This study was performed to determine the optimum coagulant dosing for effective treatment of raw water in Chinyang lake. Removal rates of algae and characteristics of the water according to coagulants dosage were investigated by treatment with Microcystis aeruginosa, which is a kind of blue-green algae, to the raw water below 5NTU. The coagulants dosage for maximum removal rate of algae were 30 mg/$\ell$ of Alum, 30 mg/$\ell$ of PAC and 10 mg/$\ell$ of PACS, respectively. The removal rate of algae in 30 mg/$\ell$ of PAC was highest as 85% compared with the other treatments. At the point of maximum removal rate of algae, the removal rates of turbidity were 34%, 66% and 22% in Alum, PAC and PACS, respectively. Residual Al was decreased depend upon decreasing turtidity in water by treatment of Alum or PAC, but decreased depend upon increasing turbidity in water by treatment of PACS. The removal rate of ${Mn}_{2+}$ in water was high in the order of Alum, PAC and PACS treatment. And ${Fe}_{2+}$ in water was not changed by treatemnt of these coagulants. Particle numbers distributions according to the particle size of suspended solids that were not precipitated at 8 min. of settling time after treatment of coagulants dosage for the maximum removal rate of algae were investigated. Most of the particle sizes were below 30 $\mu$m and particle numbers distributions below 10 $\mu$m were 64%, 56% and 66% by treatment of Alum, PAC and PACS, respectively. Zeta potential was in the range of -6.1~-9.7 mV at optimum coagulants dosage for algae removal.

• Journal of the Korea Organic Resources Recycling Association
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• v.12 no.2
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• pp.101-109
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• 2004

In this study, the solid-liquid separation characteristics of swine wastewater were investigated for the coagulation and dissolved air flotation (DAF). Coagulation characteristics were studied using jar-tester with the different coagulants and dosage amounts. DAF characteristics were also investigated in terms of the different flotation conditions with the raw swine wastewater, pH adjustment only, and adding coagulants. When the raw swine wastewater was coagulated with the only inorganic coagulants, the proper inorganic coagulants were founded as $FeCl_3$ > PAC > Alum orderly, and the optimal coagulant dosages were founded as $1,000mg/{\ell}$, $1,500mg/{\ell}$, $1,500mg/{\ell}$, respectively. As the raw swine wastewater was treated with the polymer coagulants, the only cationic polymer coagulant showed an effective coagulation and the optimal dosage of cationic coagulant was founded as $200mg/{\ell}$. When the different dosages of cationic polymer was added to each $500mg/{\ell}$ of the inorganic coagulants, the proper inorganic coagulants were founded as $FeCl_3$ > Alum > PAC orderly, and optimal cationic polymer dosages was founded as $25mg/{\ell}$, $25mg/{\ell}$, and $100mg/{\ell}$, respectively. Resulting from the raw swine wastewater experiments using DAF without coagulation, the proper operation conditions of DAF were set to 400% of recycling ratio, 4 atm in air dissolving tank, and under pH 3. But the raw swine wastewater was difficult to successfully operate DAF without pre-coagulation. While the DAF separation after pre-coagulation using inorganic coagulants was not accomplished due to the low intensity of the floc, DAF after pre-coagulation using both the inorganic and cationic polymer coagulants was accomplished very well. Optimal dosage of cationic polymer coagulant in case of $500mg/{\ell}$ Alum dosage was founded as $500mg/{\ell}$.