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Synthesis and Photovoltaic Properties of New π-conjugated Polymers Based on Benzo[1,2,5]thiadiazole (Benzo[1,2,5]thiadiazole을 기본 골격으로 한 공액고분자의 합성 및 광전변환특성 연구)

  • Bea, Jun Huei;Lim, Gyeong Eun;Kim, Joo Hyun
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.396-401
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    • 2013
  • Alternating copolymers, poly[9-(2-octyl-dodecyl)-9H-carbazole-alt-4,7-di-thiophen-2-yl-benzo[1,2,5]thiadiazole] (PCD20TBT) and poly[9,10-bis-(2-octyl-dodecyloxy)-phenanthrene-alt-4,7-di-thiophen-2-yl-benzo[1,2,5]thiadiazole] (PN40TBT), were synthesized by the Suzuki coupling reaction. The copolymers were soluble in common organic solvents such as chloroform, chlorobenzene, 1,2-dichlorobenzene, tetrahydrofuran and toluene. The maximum absorption wavelength and the band gap of PCD20TBT were 535 nm and 1.75 eV, respectively. The maximum absorption wavelength and the band gap of PN40TBT were 560 nm and 1.97 eV, respectively. The HOMO and the LUMO energy level of PCD20TBT were -5.11 eV and -3.36 eV, respectively. As for PN40TBT, the HOMO and the LUMO energy level of PCD20TBT were -5.31 eV and -3.34 eV, respectively. The polymer solar cells (PSCs) based on the blend of copolymer and PCBM (1 : 2 by weight ratio) were fabricated. The power conversion efficiencies of PSCs based on PCD20TBT and PN40TBT were 0.52% and 0.60%, respectively. The short circuit current density ($J_{SC}$), fill factor (FF) and open circuit voltage ($V_{OC}$) of the device with PCD20TBT were $-1.97mA/cm^2$, 38.2% and 0.69 V. For PN40TBT, the $J_{SC}$, FF, and $V_{OC}$ were $-1.77mA/cm^2$, 42.9%, and 0.79 V, respectively.

Electrical Discharge Plasma in a Porous Ceramic Membrane-supported Catalyst for the Decomposition of a Volatile Organic Compound (다공질 세라믹지지 촉매 상에서의 플라즈마 방전을 이용한 휘발성유기화합물의 분해)

  • Jo, Jin-Oh;Lee, Sang Baek;Jang, Dong Lyong;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.433-437
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    • 2013
  • Electrical discharge plasma created in a multi-channel porous ceramic membrane-supported catalyst was applied to the decomposition of a volatile organic compound (VOC). For the purpose of improving the oxidation capability, the ceramic membrane used as a low-pressure drop catalyst support was loaded with zinc oxide photocatalyst by the incipient wetness impregnation method. Alternating current-driven discharge plasma was created inside the porous ceramic membrane to produce reactive species such as radicals, ozone, ions and excited molecules available for the decomposition of VOC. As the voltage supplied to the reactor increased, the plasma discharge gradually propagated in the radial direction, creating an uniform plasma in the entire ceramic membrane above a certain voltage. Ethylene was used as a model VOC. The ethylene decomposition efficiency was examined with experimental variables such as the specific energy density, inlet ethylene concentration and zinc oxide loading. When compared at the identical energy density, the decomposition efficiency obtained with the zinc oxide-loaded ceramic membrane was substantially higher than that of the bare membrane case. Both nitrogen and oxygen played an important role in initiating the decomposition of ethylene. The rate of the decomposition is governed by the quantity of reactive species generated by the plasma, and a strong dependence of the decomposition efficiency on the initial concentration was observed.

SHRIMP U-Pb Ages of Detrital Zircons from Metasedimentary Rocks in the Yeongheung-Seonjae-Daebu Islands, Northwestern Gyeonggi Massif (경기육괴 북서부 영흥도-선재도-대부도에 분포하는 변성퇴적암 내 쇄설성 저어콘의 SHRIMP U-Pb 연대)

  • Na, Jun-Seok;Kim, Yoon-Sup;Cho, Moon-Sup;Yi, Kee-Wook
    • The Journal of the Petrological Society of Korea
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    • v.21 no.1
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    • pp.31-45
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    • 2012
  • We investigated the various lithologies and zircon U-Pb ages of metasedimentary rocks from the Yeongheung-Seonjae-Daebu Islands, western Gyeonggi Massif, whose geologic and geochronologic features are poorly constrained in spite of their significance for tectonic interpretation. Major lithology consists of quartzites or meta-sandstones commonly alternating with semi-pelitic schists, together with lesser amounts of calcareous sandstones with matrix-supported quartzite clasts, calcareous schists, and pelitic schists. Pelitic schists uncommonly contain large porphyroblasts of garnet as well as quartz veins with large crystals of muscovite and andalusite or kyanite. SHRIMP U-Pb ages of detrital zircons from two analyzed metasandstones define four age populations: Neoarchean (~2.5 Ga), Paleoproterozoic (~2.0-1.5 Ga), Neoproterozoic (~1.1-0.7 Ga), and Early Paleozoic (~560-400 Ma). The youngest zircon ages are clustered at ~420 Ma. These results suggest that the deposition of meta-sandstones took place after the Silurian, possibly during the Devonian, and are analogous to those of the Taean Formation reported from the western part of the Gyeonggi Massif. Moreover, The age distribution patterns of detrital zircons and the Barrovian-type metamorphic facies of pelitic schists are similar to those reported from the Imjingang belt, suggesting that the Taean Formation likely corresponds to southwestward extension of the Imjingang Belt.

Response of Amylase and Peroxidase Activity of Emerging Rice Seeds to Different Temperatures (벼 종자 출아시 온도차이가 Amylase와 Peroxidase활성에 미치는 영향)

  • 소창호;노영덕;윤진일;김영채
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.40 no.4
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    • pp.525-532
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    • 1995
  • The periods of germination and seedling emergence, epidermal cell size and the activities of peroxidase and amylase of 6 rice cultivars were examined to clarify the response to 3 temperature conditions, constant temperatures of 27$^{\circ}C$ and 17$^{\circ}C$ and alternating temperature of 24/1$0^{\circ}C$, in the dark condition. The periods of germination and seedling emergence were increased and the germination was delayed greater than the seedling emergence under 17$^{\circ}C$ and 24/l$0^{\circ}C$, compared with 27$^{\circ}C$. Lengths of epidermal cell of coleoptile and first leaf were reduced, but the widths were increased in the 17$^{\circ}C$ and 24/1$0^{\circ}C$, compared with 27$^{\circ}C$. The activities of peroxidase in the emerging shoots and amylase in the germinating seeds were reduced in 17$^{\circ}C$ and 24/1$0^{\circ}C$. There were significant correlations between peroxidase activities and the widths of epidemal cell of first leaf and between amylase activities and periods of germination. Varietal differences of all observations were remarkable in 17$^{\circ}C$ and 24 /1$0^{\circ}C$.

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BETTI NUMBERS OF GAUSSIAN FIELDS

  • Park, Changbom;Pranav, Pratyush;Chingangbam, Pravabati;Van De Weygaert, Rien;Jones, Bernard;Vegter, Gert;Kim, Inkang;Hidding, Johan;Hellwing, Wojciech A.
    • Journal of The Korean Astronomical Society
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    • v.46 no.3
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    • pp.125-131
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    • 2013
  • We present the relation between the genus in cosmology and the Betti numbers for excursion sets of three- and two-dimensional smooth Gaussian random fields, and numerically investigate the Betti numbers as a function of threshold level. Betti numbers are topological invariants of figures that can be used to distinguish topological spaces. In the case of the excursion sets of a three-dimensional field there are three possibly non-zero Betti numbers; ${\beta}_0$ is the number of connected regions, ${\beta}_1$ is the number of circular holes (i.e., complement of solid tori), and ${\beta}_2$ is the number of three-dimensional voids (i.e., complement of three-dimensional excursion regions). Their sum with alternating signs is the genus of the surface of excursion regions. It is found that each Betti number has a dominant contribution to the genus in a specific threshold range. ${\beta}_0$ dominates the high-threshold part of the genus curve measuring the abundance of high density regions (clusters). ${\beta}_1$ dominates the genus near the median thresholds which measures the topology of negatively curved iso-density surfaces, and ${\beta}_2$ corresponds to the low-threshold part measuring the void abundance. We average the Betti number curves (the Betti numbers as a function of the threshold level) over many realizations of Gaussian fields and find that both the amplitude and shape of the Betti number curves depend on the slope of the power spectrum n in such a way that their shape becomes broader and their amplitude drops less steeply than the genus as n decreases. This behaviour contrasts with the fact that the shape of the genus curve is fixed for all Gaussian fields regardless of the power spectrum. Even though the Gaussian Betti number curves should be calculated for each given power spectrum, we propose to use the Betti numbers for better specification of the topology of large scale structures in the universe.

Characterization of a Micro Power Generator using a Fabricated Electroplated Coil (전기도금 방법으로 제작한 코일을 이용한 초소형 발전기의 특성분석)

  • Lee, Dong-Ho;Kim, Seong-Il;Kim, Young-Hwan;Kim, Yong-Tae;Park, Min-Chul;Lee, Chang-Woo;Baek, Chang-Wook
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.3 s.40
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    • pp.9-12
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    • 2006
  • We have designed and fabricated micro power generators by electroplating which is important in MEMS(micro electro mechanical system) technique. We have electroplated MEMS coils on the glass substrates and have chosen one of these coils for experiments. The thickness, width, and length of the coil are $7{\mu}m,\;20{\mu}m$, and 1.6 m, respectively. We have analyzed the structure of MEMS coil by SEM. We have made a vibrating system for reproducible results in measurement. With reciprocating a magnet on the surface of a fabricated winding coil, the micro power generator produce an alternating voltage. We have changed the vibrational frequency from 0.5 Hz to 8 Hz. The generated voltage was 106 mV at 3 Hz and 198 mV at 6 Hz. We aim at the micro power generator which can change vibration energy to useful electric energy.

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Transparent Rectangular Patch Antenna Using Square Metal Mesh Transparent Electrode (정방형 메탈메쉬 투명전극을 이용한 투명 사각 패치 안테나)

  • Kang, Seok Hyon;Jung, Chang Won
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.29 no.4
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    • pp.277-284
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    • 2018
  • This paper reports the transparent electrode, which would be applied to transparent displays and smart glasses. Herein, a squared metal mesh with the most widely used copper wire in microwaves is studied for the alternating thin-film-type transparent and conducting indium tin oxide(ITO), with a low conductivity(sheet resistance > $5{\Omega}/sq.$). The electromagnetic performance of a patch antenna with metal mesh is analyzed. This paper presents the results of the optical(OT, optical transparent) and electrical(sheet resistance) characteristics of a squared metal mesh, which is a basic design. To improve the OT, copper wire(w=0.2 mm) is used in fabricating the squared metal mesh and the relationship between the OT and the antenna performance(radiation gain, radiation pattern) was analyzed according to the mesh size(l=1, 2 mm). The measurement results show that the antenna performance and the optical characteristic are in inverse proportion to each other. In real applications, the optical and electrical characteristics, and the costs of production are to be considered.

Effects of Some Environmental Factors on the Germination of Seeds in Ambrosia artemisiifolia var. elatior (몇가지 환경요인이 돼지풀의 종자발아에 미치는 영향)

  • 김종홍;김원희;차승희
    • The Korean Journal of Ecology
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    • v.25 no.2
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    • pp.93-100
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    • 2002
  • In order to analyze the life cycle of A. artemisiifolia var. elation dormancy and some environmental factors inducing germination of the seeds were examined. The results were as follows : Dormancy of fertile seeds was broken in part within a month after seed collection in case of adequate moisture and alternating temperature was also effective in breaking dormancy. The temperature range, which allow germination was 12℃ ∼ 32℃. Optimum temperature for germination was 24℃. The seed of A. artemisiifolia var. elatior was light-independent. The difference of storage period appeared to have no particular effect on the viability of seeds at any time during the 9-month storage period. In the increasing temperature(IT) regime, A artemisiifolia var. elatior seeds started to germinate at 16℃, showing the higher temperature the greater germination rate, the final germination percentage was 99.34%. On the other hand, in the decresing temperature(DT) regime, seeds began to germinate at 20℃ with the 1.34% germination. An induced dormancy occurred at 12℃ making the 5.34% fecal germination in the DT regime. Low temperature was more effective to break dormancy than higher temperature Seeds of A. artemisiifolia var. elatior seems to be germinated in mid to late autumn or germination delayed until following spring. The above results suggest these variation of germination response in diverse environmental factors seems to be a physiological strategy to maintain their existence and to reproduce in the extreme thermal variation.

Electrical Anisotropy of the Okchon Belt Inferred from Magnetotelluric Data (자기지전류 탐사 자료에 나타나는 옥천대의 전기적 이방성 구조)

  • Lee, Choon-Ki;Lee, Heui-Soon;Kwon, Byung-Doo;Cho, In-Ky;Oh, Seok-Hoon;Song, Yoon-Ho;Lee, Tae-Jong
    • Journal of the Korean earth science society
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    • v.28 no.2
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    • pp.227-239
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    • 2007
  • The MT data at the Okchon Belt show peculiar phase responses exceeding $90^{\circ}$. A reasonable explanation is that those responses are due to an electrical anisotropy structure which is composed of a narrow anisotropic block and an anisotropic layer. Considering the dominant anisotropic strikes of the block (NE-trend) and the layer (NW-trend) inferred from the MT data, if existing, the electrical anisotropy in the Okchon Belt was probably produced by the deformations in the pre-Jurassic period, since the NE-trending shearing or thrusting should create alternating bands of metamorphic rocks and fractures with NE-trending. Correlation of the structural strike of 2-D block with the latest EW-trending deformation events demonstrates that the geometrical structure of the anisotropic block was formed by the latest Daebo and Bulgugsa orogeny.

THE EVALUATION OF THE REMOVAL TORQUE AND THE HISTOMORPHOMETRY OF THE CA-P COATING SURFACE IN RABBIT TIBIA (가토 경골에 식립된 Ca-P 박막코팅 임프란트의 뒤틀림 제거력 및 조직형태학적 평가)

  • Kwak Myeong-Bae;Lee Cheong-Hee
    • The Journal of Korean Academy of Prosthodontics
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    • v.42 no.5
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    • pp.556-571
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    • 2004
  • Statement of problem: Surface texture of the implant is one of the important factors of the implant success, especially in the immediate implant loading. Many methods of the surface treatment of implant have developed and introduced. Purpose : This study was to evaluate the effects of the Ca-P coating implant crystallized the hydroxyapatite on the surface by the removal torque test and the histomorphometric analysis in vivo. Material and methods: 135 screw type implants, 4.0mm in length and 3.75mm in diameter were used in this study. Implants were divided into 3 groups and treated in the different mothods. Group I was not treated, Group II was treated in the SLA method, and Group III was treated in the Ca-P coating with the anodizing method and the hydroxyapatite was crystallized on the surface with the hydrothermal treatment. Firstly, the surface roughness of each group was measured, 45 rabbits were used in this experiment. Two implants were inserted on right tibial metaphysis and one implant was inserted on left side with the alternating order. After the healing periods of 3, 5, and 12 weeks, the rabbits were sacrificed to evaluate the osseointergration by the removal torque test and the histomorphometric analysis. Results : 1. In the analysis for the surface roughness, Group II showed the highest roughness. And Group III showed higher secondly. There was a significant difference one another statistically 2. In the removal torque test, Group III and II were significantly higher than Group I. There was no statistical difference between Group III and Group II. 3. For all Groups, the removal torque values at 12th week were significantly higher than at 3rd and 5th week. 4. In histomorphometric analysis, the bone implant contact rates of Group III and II were higher than that of Group I at 3rd and 5th week. There was a significant difference at 5th week. 5. In histomorphometric analysis, the bone implant contact rate of Group III and II increased from 3rd week to 5th week, but decreased at 12th week. In Group I, the contact rate at 12th week was significantly higher than at 3rd week and 5th week.