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Coercivity of Near Single Domain Size Nd2Fe14B-type Particles

  • Kwon, H.W.;Yu, J.H.
    • Journal of Magnetics
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    • v.17 no.3
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    • pp.185-189
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    • 2012
  • The coercivity of near single domain size $Nd_2Fe_{14}B$-type particles prepared by ball milling of HDDR-treated $Nd_{12.5}Fe_{80.6}B_{6.4}Ga_{0.3}Nb_{0.2}$ alloy was investigated. The feasibility of a surface nitrogenation for improving the coercivity stability of the fine $Nd_2Fe_{14}B$-type particles was also studied. The near single domain size $Nd_2Fe_{14}B$-type particles had a high coercivity of over 9 kOe. However, the coercivity radically deteriorated as the temperature increased in air (< 2 kOe at $200^{\circ}C$). This coercivity reduction was attributed to the soft magnetic phases, ${\alpha}$-Fe and $Fe_3B$, which formed on the surface of the fine particle due to oxidation. Surface nitrogenation of the fine particles significantly improved the stability of their coercivity. The improvement in coercivity stability was attributed to the formation of a thin nitrogenated layer on the surface of the fine $Nd_2Fe_{14}B$-type particles, which enhanced the anisotropy field and gave improved resistance to oxidation (dissociation).

The effect of geometrical parameters on the radon emanation coefficient and different radon parameters

  • Entesar H. El-Araby;A. Azazi
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4096-4101
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    • 2023
  • Radon is a radioactive gas produced from the uranium-238 series. Radon gas affects public health and is the second cause of lung cancer. The study samples were collected from one area of the city of Jazan, southwest of the Kingdom of Saudi Arabia. The influence of engineering and physical parameters on the emanation coefficient of gas and other gas parameters was studied. Parameters for radon were measured using a CR-39 Solid-State Nuclear Track Detector (SSNTD) through a sealed emission container. The results showed that the emanation coefficient was affected directly by the change in the grain size of the soil. All parameters of measured radon gas have the same behavior as the emanation coefficient. The relationship between particle size and emanation coefficient showed a good correlation. The values of the emanation coefficient were inversely affected by the mass of the sample, and the rest of the parameters showed an inverse behavior. The results showed that increasing the volume of the container increases the accumulation of radon sons on the wall of the container, which increases the emission factor. The rest of the parameters of radon gas showed an inverse behavior with increasing container size. The results concluded that changing the engineering and physical parameters has a significant impact on both the emanation coefficient and all radon parameters. The emanation coefficient affects the values of the radiation dose of an alpha particle.

Radon Measurement by Alpha Particle Track Method (Alpha 입자비적법(粒子飛跡法)에 의(依)한 Radon 측정(測定))

  • Kang, Yung-Ho;Park, Jang-Sick;Kim, Do-Sung
    • Journal of Radiation Protection and Research
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    • v.7 no.1
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    • pp.17-22
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    • 1982
  • Measurement of the radon concentration close to the ground surface can be used in search of environmental radiation for human safety, exploration for uranium, premonitory signals from earthquakes. We can detect radons in soil gas by alpha particle track method using the plastic track detectors, cellulose nitrate (LR115-Type 2 and CA80-15, Kodak $Path\'{e}$) and CR-39. For present works, radon cups having these detectors were made in our laboratory and their conversion factor was determined. A typical conversion factor was $1tr/cm^2{\cdot}30days=1.2{\times}10^{-2}pCi/l$. In the radon cups, some of $CaSO_4$ were used as desiccant for reducing the moisture effects on plastic track detectors. With these radon cups, underground radon concentrations of Kyungpook area were measured. Average radon concentration in Daegu from Jan. 1981 to Feb. 1982 was 39.7pCi/l. From Aug. 1981 to Feb. 1982, average radon concentrations of Daegu, Angang, Kyungju, Pohang, Chungha, and Andong were 31.8pCi/l, 124.5pCi/l, 127.0pCi/l, 79.1pCi/l, 144.4pCi/l, and 70.9pCi/l, respectively. The results were compared with the environmental radiation measured by TLD method.

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Simultaneous Analysis of Cholesterol Oxidation Products (COPs) in Powdered Milk Using HPLC/UV-Vis

  • Lee, Jin Joo;Myung, Seung-Woon
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2787-2794
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    • 2013
  • Cholesterol and cholesterol oxidation products (COPs) may accumulate in foods of animal origin during processing or storage. An effective and sensitive analytical method was developed by increasing the UV absorption of compounds through derivatization by attaching a chromophore to the functional groups of cholesterols (cholesterol, 20-hydroxycholesterol, 7-ketocholesterol, cholestane-$3{\beta}$-$5{\alpha}$-$6{\beta}$-triol, 25-hydroxycholesterol, and $5,6{\alpha}$-epoxycholesterol). The influences of the reaction time, volume of reaction solvent, amounts of derivatizing reagent, and extraction solvents were investigated, as they may influence the reaction and extraction yield. The derivatized COPs were analyzed simultaneously on a C18 column (2.1 mm i.d. ${\times}$ 100 mm length, $3.5{\mu}m$ particle size) using a gradient elution with water and acetonitrile. The derivatized COPs showed increased sensitivity and selectivity in HPLC/UV-Vis. The LOD and LOQ were in the concentration ranges of 0.018-0.55 mg/kg and 0.059-1.84 mg/kg from the powdered milk. And the accuracy and precision were 78.1-116.7% and 1.1-9.9%, respectively.

A Study on Starch-acrylic Graft Copolymerization by Emulsion Polymerization (유화중합에 의한 전분-아크릴 그래프트 공중합에 관한 연구)

  • Hwang, Ju-Ho;Ryu, Hoon;Cho, Ur-Ryong
    • Elastomers and Composites
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    • v.43 no.4
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    • pp.221-229
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    • 2008
  • Starch as matrix polymer was used to do graft copolymerization with 2-ethylhexylacrylate, methyl methacrylate and acrylic acid. The polymerization was carried out by radical emulsion polymerization with increasing contents of starch. When 0.174% of $\alpha$-amylase as enzyme for starch was added, it was found that it made the best stable emulsion. The glass transion temperature of the polymerized material was increased with starch contents. The particle size and viscosity of the emulsion increased with starch contents due to the increased hydroxy group. Peel strength also increased with contents of starch because the enhanced hydroxy group caused to increase affinity between substrate surface and polymer materials. However, the initial tackiness decreased with starch contents owing to film hardness by higher glass transion temperature.

Influence of Periodic Blowing and Suction on a Turbulent Boundary Layer (주기적인 분사/흡입이 난류경계층에 미치는 영향)

  • Park Young-Soo;Park Sang-Hyun;Sung Hyung Jin
    • Journal of the Korean Society of Visualization
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    • v.1 no.1
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    • pp.64-74
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    • 2003
  • An experimental study was carried out to investigate the effect of periodic blowing and suction on a turbulent boundary layer. Particle image velocimetry (PIV) was used to probe the characteristics of the flow. The local forcing was introduced to the boundary layer via a sinusoidally-oscillating jet issuing from a thin spanwise slot. Three forcing frequencies (f$^{+}$=0.044, 0.066 and 0.088) with a fixed forcing amplitude (A$^{+}$=0.6) were employed at $Re_{=690. The effect of the forcing angles ($\alpha$=60$^{\circ}$ , 90$^{\circ}$ and 120$^{\circ}$ ) was investigated under the fixed forcing frequency (f$^{+}$=0.088). The PIV results showed that the wall region velocity decreases on imposition of the local forcing. Inspection of phase-averaged velocity profiles revealed that spanwise large-scale vortices were generated in the downstream of the slot and persist further downstream. The highest reduction in skin friction was achieved at highest forcing frequency (f$^{+}$=0.088) and a forcing angle of $\alpha$=120$^{\circ}$. The spatial fraction of the vortices was examined to analyze the skin friction reduction.

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Nitrogen Incorporation of Nanostructured Amorphous Carbon Thin Films by Aerosol-Assisted Chemical Vapor Deposition

  • Fadzilah, A.N.;Dayana, K.;Rusop, M.
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.4
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    • pp.165-171
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    • 2013
  • Nanostructured pure a-C and nitrogen doped a-C: N thin films with small particle size of, ~50 nm were obtained by Aerosol-assisted CVD method from the natural precursor camphor oil. Five samples were prepared for the a-C and a-C: N respectively, with the deposition temperatures ranging from $400^{\circ}C$ to $600^{\circ}C$. At high temperature, the AFM clarifies an even smoother image, due to the increase of the energetic carbon ion bombardment at the surface of the thin film. An ohmic contact was acquired from the current-voltage solar simulator characterization. The higher conductivity of a-C: N, of ${\sim}{\times}10^{-2}Scm^{-1}$ is due to the decrease in defects since the spin density gap decrease with the nitrogen addition. Pure a-C exhibit absorption coefficient, ${\alpha}$ of $10^4cm^{-1}$, whereas for a-C:N, ${\alpha}$ is of $10^5cm^{-1}$. The high ${\sigma}$ value of a-C:N is due to the presence of more graphitic component ($sp^2$ carbon bonding) in the carbon films.

Mechanical properties of materials for spectacle lens cutting(II) (안경렌즈 절삭용 재료의 기계적 특성(II))

  • Lee, Young-Il;Kim, Jin-Koo
    • Journal of Korean Ophthalmic Optics Society
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    • v.5 no.1
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    • pp.61-65
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    • 2000
  • ${\beta}$-SiC powder and ${\alpha}$-SiC powders of different particle sizes, containing 5.7wt% $Al_2O_3$ and 4.3wt% $Y_2O_3$ as sintering aids, were hot-pressed at $1780^{\circ}C$ and subsequently annealed at $1950^{\circ}C$ to initiate grain growth. All the hot-pressed and annealed materials consisted of large SiC grains and elongated SiC grains. Typical hardness and fracture toughness of materials for spectacle lens cutting were 15.6 GPa and $5.7MPa{\cdot}m^{1/2}$, respectively.

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Enterotoxemia caused by Clostridium perfringens type A in Formosan deer (꽃사슴의 Clostridium perfringens A형에 의한 장독혈증 발생 보고)

  • 이청산;한성태;곽학구;박경재;현공율;조우영;이종인;배유찬;진영화
    • Korean Journal of Veterinary Service
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    • v.25 no.2
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    • pp.127-133
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    • 2002
  • The case reports for clostridium type A enterotoxemia in Formosan deer have rarely been reported. This paper describes a natural case of type A enterotoxemia in farmed Formosan deer in Cheongwon-gun. A dead, male 10-month-old Formosan deer was submitted to Chungbuk Livestock and Veterinary Research Institute, March 24, 2001 and examined. That deer was fed with assorted grain feed, oak leaves, acorn and bean curd. Grossly there was no visible external change. Despite of the carcass being examined within 12 hours of death, there was a quite degree of posonortem decomposition. There was severe hemorrhage in the serosa of abomasum and small intestine. Much blood tinged and watery contents were contained in those organs. Also there were severe swelling of spleen, some red foci in hepatic parenchyma. Microscopically there were severe congestion and hemorrhage in mucosa submucosa, muscular layer, and serosa of abomasum and small intestine. Also spleen and pancreas showed severe Congestion and hemorrhage. There were multifocal hemorrhage with hepatic necrosis in periportal area and focal mononuclear cell deposition in sinusoid. In bacterial culture for small intestine, Cl perfringens was isolated. By toxin typing for the strain, that had $\alpha$ -toxin belonged to type A. In electronmicroscopy for feces, no vims particle was detected. Considering clinical signs, gross lesions, microscopic lesions, bacterial culture, and toxin typing of the isolate, this case was diagnosed as enterotoxemia by Cl perfringens type A.

Study on Behavior of Cured Rubber Using Stress-Strain Method (응력-변헝 곡선을 이용한 가황고무의 거동에 관한 연구)

  • Kim, W.Y.;Kim, H.S.;Shin, H.C.;Hong, S.P.;Lee, B.C.
    • Applied Chemistry for Engineering
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    • v.5 no.6
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    • pp.943-948
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    • 1994
  • The properties of uncured rubber compound and swelling behavior of cured rubber compound with carbon black(N33O grade) increment. Bound Rubber content(BRC) increased according to carbon black increment and ${\alpha}_f$, behavior of uncured rubber compound filled with carbon black, was 1.46. Carbon black added to rubber compound showed behavior of spherical particle by bound rubber. The $C_1$ values of cured rubber compounds, which measured by the stress-strain method of Mooney-Rivlin, increased with carbon black increment.

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