• Title/Summary/Keyword: alkaline hydrolysis

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A Study on the Degradation Characteristics of EPN (EPN의 분해특성에 관한 연구)

  • 이용두;김현희;김창영
    • Journal of Environmental Science International
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    • v.11 no.10
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    • pp.1103-1108
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    • 2002
  • In order to evaluate the degradation organophosphorus pesticide, EPN, in water environment, the effects of water temp.(10$^{circ}C,\;30^{\circ}C$), pH(3-11) and sunlight on its degradation were investigated during 10 days. The degradation rate of EPN(200 rpm) was faster at higher water temp. and higher pH, i.e., its degradation rate at pH 3, 5, 7, 9, 11 was 57, 63, 66, 69, 75%(1$0^{\circ}C$), and 70, 74, 79, 91, 97%(3$0^{\circ}C$) after 10 days, respectively. The effect of water temp. on its degradation was little in acidic condition, but was rather great in alkaline condition, with time. EPN was degraded fast at the alkaline condition by photolysis. At the condition of pH 11, EPN was degraded fast at the early stage in the first 2 days, but after that the degradation rate was weakened.

The Effect of Subjective Evaluation of Fabric Hand on Judge's Age and specialty -Akaline hydrolyzed Polyester Fabrices- (평가자의 연령과 전문성이 직물의 태 평가에 미치는 영향 -알칼리 감량가공된 폴리에스테르 직물을 중심으로-)

  • 김경애
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.2
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    • pp.220-229
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    • 1999
  • The subjective hand and preference of alkaline hydrolized polyester fabrics were evaluated using the scale developed. The factors affecting consumer's taste for polyester fabrics was analyzed by the statistical technique. The effects of alkaline hydrolysis on the properties of polyester fabrics were evaluated by subjective and objective hand measurements. The lower the age the more senstive their feeling. As the age of evaluators decreased they felt fabrics light flexible refined thin flossy smooth fine soft more clinging. They also thought fabrics are colder, more flexible more spongy as the age increased. Experts were more sensitive and consistent when they evaluation the hand of fabrics than non-experts.

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Degradation Behaviors of Poly(l-lactide) using Model Systems (모델 시스템을 이용한 Poly(l-lactide)의 분해거동)

  • Min Seong-Kee;Moon Myong-Jun;Lee Won-Ki
    • Journal of Environmental Science International
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    • v.15 no.2
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    • pp.177-183
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    • 2006
  • The hydrolytic kinetics of biodegradable poly(l-lactide) (PLLA) have been studied by using two model systems, solution-grown single crystal (SC) and Langmuir monolayer techniques, for elucidating the mechanism for both alkaline and enzymatic degradations. The present study investigated the parameters such as degradation medium and time. The Langmuir mono layers of PLLA showed faster rates of hydrolysis when they were exposed to a basic subphase rather than they did when exposed to neutral subphase. Both degradation mediums had moderate concentrations to show a maximized activity, depending on their sizes. An alkaline degradation of SCs of PLLA showed the decrease of molecular weight of the remained crystals due to the erosion of chain-folding surface. However, the enzymatic degradation of SCs of PLLA occurred in the crystal edges thus the molecular weight of remained crystals was not changed. This behavior might be attributed to the size of enzymes which is much larger than that of alkaline ions; that is, the enzymes need larger contact area with monolayers to be activated.

The Characteristics of Alkaline Pretreatment Methods of Cellulosic Biomass (섬유소계 바이오매스의 분별을 위한 다양한 알칼리 전처리 특성)

  • Kim, Jun Seok
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.303-307
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    • 2013
  • This study compares the efficacy of soaking and percolation pretreatments with alkaline solutions for lignocellulosic biomass. Various biomass such as rice straw and barley were pretreated by soaking processes in various alkaline solutions including sodium hydroxide, potassium hydroxide, aqueous ammonia and sodium carbonate. The enzymatic digestibility of rice straw and barley that had been pretreated by soaking in aqueous ammonia was over 80%. Eucalyptus residue, Larix leptolepis and Pinus rigida exhibited relatively low enzymatic digestibility. Nevertheless, the enzymatic digestibility of pretreated eucalyptus residue was increased by five times compared to that of the initial biomass. And, the enzymatic digestibility of the percolation pretreated eucalyptus residue was increased 12 times.

Distribution of Phyrase in The Development Rat Organs (성장 발육에 따른 흰쥐 장기내 phytase의 분포성)

  • 양원진
    • Journal of Life Science
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    • v.7 no.2
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    • pp.127-133
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    • 1997
  • The phytase(myo-inositol hexkisphosphate phosphohydrolase ; EC 3.1.3.8) activity was observed only in the homogenate of intestinal mucosa, though the activity of alkaline phisphatase was measurable in various organs. In addition, no protein bands were detected in any other organs on immunoblotting using the anti-90kDa phytase antiserum. Thses results suggest that phytase is specifically present in small intestinal mucosa, and that hydrolysis of phytic acid(inositol-hexakisphosphate) can be allotted for a physiological role of the intestine-specific enzyme. The activities of phytase was increased during development of rat. The 70kDa phytase appeared just after birth, but the 90kDa phytase was not observed until adult period, suggesting that the 90kDa phytase was synthesized in response to weanling.

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Microbial Conversion of Woody Waste into Sugars and Feedstuff (I) - Optimal Delignification condition with alkaline peroxide for enzymatic hydrolysis of poplar wood (미생물(微生物)에 의한 목질자원(木質資源)의 당화(糖化) 및 사료화(飼料化)에 관(關)한 연구(硏究) (I) - alkaline peroxide에 의한 현사시나무의 효소가수분해를 위한 탈리그닌화의 적정조건)

  • Kim, Yoon-Soo;Bang, Joo-Wan;Chung, Ki-Chul;Myung, Kyu-Ho;Kim, Youn-Sik
    • Journal of the Korean Wood Science and Technology
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    • v.14 no.3
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    • pp.23-29
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    • 1986
  • Alakline peroxide pretreatment for the delignification of poplar wood was performed. sinceit is a simple and efficent method for enhancing the enzymatic digestibility of wood residues. Approximately one-half of their lignin and most of the hemicellulose present in poplar wood were removed when the wood sawdust was reacted at 25$^{\circ}C$ for 100 hrs in an alkaline solution (pH 11.5) of 1% peroxide. The rate of decomposition as well as the saccharification efficiency were enhanced up to 350% and 260% respectively in comparision with those of the controll. This enhancement is comparable with that pretreated with 1% sodium hydroxide and 20% peracetic acid successively. The advantages of alkaline peroxide as delignifying agents against other chemicals were also discussed.

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Reduction Mechansim of Organophosphorus Compounds (유기인제의 수소 환원)

  • Lee Myung Yun
    • Journal of the Korean Chemical Society
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    • v.13 no.2
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    • pp.141-147
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    • 1969
  • Organophosphorous compounds can be reduced by zinc metal in acidic solution after alkaline hydrolysis. Although phosphates and phosphonates did not evolve any gas, dithioates did evolve hydrogen sulfide and phosphine, thionates and thiolates did evolve only hydrogen sulfide. The evolved gases were qualitatively detected by means of lead acetate and silver nitrate or mercuric bromide papers and determined by spectrophotometrically. The reduction mechanism and analytical method of dithioates were proposed.

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Studies the Carotenoids in the Viscera of the Brine Schrimp(Penaeus Orientalis Kishinouye) (새우의 Carotenoid 성분에 관한 고찰)

  • Lee, In Kil
    • Journal of Environmental Health Sciences
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    • v.11 no.1
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    • pp.29-34
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    • 1985
  • The studies on the carotenoids in the viscera the brine shrimp(Penaeus Orientalis Kishinouye) have been carried out. The brine shrimps were caught around the western coastal area of Korea from Aug. to Oct. The individual carotenoids in the acetone extracts were separated and purified by the silica gel TLC. Two isolated carotenoids were investigated and identified by epoxide test, partition test, alkaline hydrolysis, reduction with sodium borohydride and visible absorption spectrophqtometry. As the results of the series of experiments, esterified Astaxanthin was discovered as one of main pigments of Penaeus Orientalis Kishinouye.

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Development of Biologically Active Compounds from Edible Plant Sources-IV. Isolation of Galactosyldiglyceride from the Allium monanthum Max. (식용 식물자원으로부터 활성물질의 탐색-IV. 달래(Allium monanthum Max.)로부터 Galactosyldiglyceridem의 분리)

  • 백남인;안은미;김해영;박영두;장영진;김세영
    • Journal of Life Science
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    • v.11 no.1
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    • pp.93-96
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    • 2001
  • n-BuOH fraction obtained from MeOH extracts of Allium monanthum was applied to repeated silica gel column chromatographies to give a glycosylglyceride. The chemical structure of the compound was determined to be 1-O-linolenoyl-2-O-linolenoyl-3-O-$\beta$-D-galactopyranosyl-누-glycerol on the basis of NMR data and by the adaptation of chemical methods.

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