• Title/Summary/Keyword: alkali-activator

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An Experimental Study on the Freezing-Thawing and Chloride Resistance of Concrete Using High Volumes of GGBS (고로슬래그 미분말을 대량 사용한 콘크리트의 염해 및 동결융해 저항성에 관한 실험적 연구)

  • Ryu, Dong-Woo;Kim, Woo-Jae;Yang, Wan-Hee;You, Jo-Hyung;Ko, Jeong-Won
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.3
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    • pp.315-322
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    • 2012
  • The effect of ground granulated blast-furnace slag(GGBS) and alkali activator compressive strength, resistance of chloride attack and freezing-thawing is assessed to develop high volume slag concrete, the replacement rate of GGBS of which is more than 80 percent. result, as the replacement rate of GGBS increases, the compressive strength development properties of concrete in early and long term age decreased and resistance chloride attack and freezing-thawing is increased. The early strength development property, however, is extremely advanced by addition of the alkali activator, which is also found to improve resistance chloride attack and freezing-thawing.

Properties of Alkali Activated Inorganic Binder using Replacement Materials Alkali Activator with Red Mud (알칼리 자극제 대체재로써 레드머드를 사용한 알칼리 활성 무기결합재의 특성)

  • Park, Sun-Gyu
    • Proceedings of the Korea Contents Association Conference
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    • 2014.11a
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    • pp.139-140
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    • 2014
  • 최근 건선산업에서 문제점으로 지적되고 있는 것은 제조과정 중 이산화탄소를 다량 방생시키는 시멘트의 사용이다. 이는 알칼리활성 무기결합재로 대체함으로써 시멘트보다 이산화탄소 배출량을 저감할 수 있지만 고가의 알칼리 자극제를 다량 사용하기 때문에 경제적 측면 및 사용성을 고려하지 않으면 사용할 수 없기 때문에 이에 대한 대체재에 관한 연구가 필요한 실정이다. 이에 본 연구에서는 고로슬래그를 기반으로 하는 알칼리 활성 무기결합재에 알칼리 자극제의 사용량을 저감하기 위해 레드머드를 사용하고, 레드머드에 적합한 알칼리 자극제의 종류와 사용방법에 대하여 연구하고자 하였다.

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Estimation of Strength and Pore Structure of Alkali-Activated Fire Protection Materials at High Temperature (고온에서의 알칼리 활성화 내화성 결합재의 강도 및 공극구조 평가)

  • Song, Hun;Kim, Young-Ho;Kim, Wan-Ki;So, Hyung-Suk
    • Journal of The Korean Digital Architecture Interior Association
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    • v.12 no.4
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    • pp.59-66
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    • 2012
  • This study is interested in identifying the effectiveness of alkali-activated fire protection material compounds including the alkali-activator such as potassium hydroxide, sodium silicate and fly ash as the fire resistant finishing materials. Also, this paper is concerned with change in compressive strength and pore structure of the alkali-activated fire protection material at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. This study results show that compressive strength is rapidly degraded depending on a rise of heating temperature. Porosity showed a tendency to increase irrespective of specimen types. This is due to both the outbreak of collapse of gel comprising the cement and a micro crack by heating. However, alkali-activated fire protection material composed of potassium hydroxide, sodium silicate and fly ash has the thermal stability of the slight decrease of compressive strength and porosity at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate.

The Properties of Hardened Slag by Alkali and Curing Method (알칼리 첨가 및 양생방법에 따른 슬래그 경화체의 특성)

  • 김원기;소정섭;배동인
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.27-32
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    • 2002
  • In this research influences of type and concentration of alkali activator and curing condition on the hydration, and properties of alkali activated blast furnace slag(AAS) concrete were investigated. Sodium carbonate and sulfate were used as alkali activators and their concentration were 4~10 weight percent with Na$_2$O equivalent to binder. The curing conditions were standard curing using 23$^{\circ}C$ water and activated curing chamber at $65^{\circ}C$. Results show that in case of sodium carbonate addition high early strengths were gained by activation of early hydration, but later strength gained was slight. On the other side sodium sulfate strengths were continuously increased with adding amount and ages. Steam curing activated early hydration so that early strengths were improved but later strengths were similar to standard curing. The strength reduction of AAS mortar with sodium sulfate was less than OPC mortar in 5% sulfuric acid solution so that AAS concrete can be useful for acid-resistance concrete.

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Strength of Alkali-Activated GGBF Slag Mortar (활성제를 사용한 슬래그 미분말 혼합 모르타르의 강도)

  • 문한영;신화철;권태석
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.481-486
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    • 2001
  • Ground granulated blast-furnace slag shows very high strength when proper alkali-activator exists. This paper deals with setting time, heat evolution rate and the strength development of alkali-activated slag cement activated by KOH, Ca(OH$)_{2}$, $Na_{2}$ $So_{4}$ , and alum(potassium aluminum sulfate). Alkali-activated slag mortar is studied by comparison with GGBF slag cement mortar. The experimental results indicate that for moisture curing at $25^{\circ}C$, the addiction of either 4% $Na_{2}$ $So_{4}$ or 4% alum increases the strength of GGBF slag cement mortar consisting of 50% GGBF slag and 50% portland cement at early age. Strength of activated GGBF slag cement mortars at 1, 3 and 7 days exceeded that of GGBF slag cement mortar. A conduction calorimeter was used to monitor early age hydration.

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Effects of Moisture Absorption Coefficient of Alkali-Activated Slag-Red Mud Cement on Efflorescence (알칼리활성화 슬래그-레드머드 시멘트 모르타르의 흡수계수가 백화발생에 미치는 영향)

  • Kang, Hye Ju;Kim, Byeong gi;Kim, Jae Hwan;Kang, Suk Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.130-131
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    • 2016
  • In this study, moisture absorption coefficient and efflorescence properties of Ordinary Portland cement and alkali-activated slag cement mortar were assessed according to their red mud substitution ratio. Tests were conducted to determine the cause of efflorescence, which is a significant obstacle to the recycling of red mud as a sodium activator in alkali-activated slag cement, and to find a method to control efflorescence.

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Flowability Properties of Alkali Activated Mortar (알칼리 활성 모르타르의 유동특성)

  • Lee, Gun-Young;Lee, Gun-Cheol;Park, Ji-Woong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.205-206
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    • 2016
  • This study examines the effect of binding material and alkali activator on the rheology characteristics of alkali active mortar quantitatively, and a result is as follows. In the 1/2 slump flow, the higher mixing ratio of the fly ash has been shown to increase the table flow. the reason is that fly ash ball bearing action. When viewed in the consistency curve, the higher mixing ratio of the blast furnace slag powder was higher shear stress.

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Characteristic of Alkali-Activated Slag Red Mud Cement Concrete according to Liquefaction Red mud Input Method (액상 레드머드 첨가방식에 따른 ASRC 콘크리트의 특성)

  • Hwang, Byoung Il;Kang, Hye Ju;Park, Kyung Su;Kang, Suk Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.134-135
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    • 2018
  • In this paper, we investigate the characteristic of ASRC concrete with the addition of liquefaction red mud using red ud which can be used as an alkali activator of alkali-activated slag cement. as a result, the compressive strength and the efflorescence area increased, and as the amount of liquid red mud increased, the compressive strength decreased and the efflorescence area increased.

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Influence of Alkali Activator Type and Amount of Addition on CO2 Uptake of GGBFS Geopolymer Pastes Containing Zeolite (알칼리계 활성화제의 종류 및 첨가량이 고로슬래그-제올라이트 지오폴리머 페이스트의 탄소포집에 미치는 영향에 관한 연구)

  • Jang-Hyun Park;Hyo-Min Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.2
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    • pp.112-119
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    • 2023
  • In this study, the variations in CO2 uptake according to the type and amount of alkali-based activator (Ca(OH)2, CSA) of geopolymer paste were evaluated. As the amount of activator added to the geopolymer paste increased, the fluidity of the paste is decreased and the compressive strength increased. According to the type of activator, it was confirmed that the addition of Ca(OH)2 had a greater effect on improving the compressive strength than CSA. As a result of changes in chemical properties according to carbonation curing, the amount of C-S-H and C-A-S-H gels produced before carbonation increased as the amount of activator increased, and amount of CaCO3 produced after carbonation increased. The reactivity of the blast furnace slag and zeolite increased due to the addition of the activator, and the reactivity tended to increase as the amount of addition increased. As a result of CO2 uptake, 10.3 wt% when Ca(OH)2 10 % was added and 8.77 wt% when CSA 10 % was added was confirmed. It increased by 421 % and 388 % respectively, compared to the case where no activator was added.

Fundamental Study of Alkali Activated Cement Mortar for Evaluating Applicability of Partial-Depth Repair (도로포장 보수재 활용 가능성 평가를 위한 알칼리 활성 시멘트 모르타르 기초연구)

  • Jeon, Sung Il;An, Ji Hwan;Kwon, Soo Ahn;Yun, Kyung Ku
    • International Journal of Highway Engineering
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    • v.15 no.3
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    • pp.1-8
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    • 2013
  • PURPOSES : This study is to evaluate the feasibility of using the alkali activated cement concrete for application of partial-depth repair in pavement. METHODS : This study analyzes the compressive strength of alkali activated cement mortar based on the changes in the amount/type/composition of binder(portland cement, fly ash, slag) and activator(NaOH, $Na_2SiO_3$, $Na_2CO_3$, $Na_2SO_4$). The mixture design is divided in case I of adding one kind-activator and case II of adding two kind-activators. RESULTS : The results of case I show that $Na_2SO_4$ based mixture has superior the long-term strength when compared to other mixtures, and that $Na_2CO_3$ based mixture has superior the early strength when compared to other mixtures. But the mixtures of case I is difficult to apply in the material for early-opening-to-traffic, because the strength of all mixtures isn't meet the criterion of traffic-opening. The results of case II show that NaOH-$Na_2SiO_3$ based mixtures has superior the early/long-term strength when compared to NaOH-$Na_2SiO_3$ based mixtures. In particular, the NaOH-$Na_2SiO_3$ based some mixtures turned out to pass the reference strength(1-day) of 21MPa as required for traffic-opening. CONCLUSIONS : With these results, it could be concluded that NaOH-$Na_2SiO_3$ based mixtures can be used as the material of pavement repair.