• Title/Summary/Keyword: alkali contents

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CHEMICAL COMPOSITION OF WHEAT STRAW AS INFLUENCED BY UREA AND ALKALI TREATMENTS AT DIFFERENT MOISTURE LEVELS

  • Rasool, E.;Gilani, A.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.8 no.6
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    • pp.563-566
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    • 1995
  • To improve the nutritive value of wheat straw it as treated with 0, 3, 4 and 5 percent levels of urea, 0 and 4 percent level of alkali at 40, 50 and 60 percent moisture levels and stored at room temperature. Total nitrogen contents of the straw increased significantly, from 0.77 percent with no urea treatment to 0.87, 1.16 and 1.19 percent with 3, 4 and 5 percent urea levels, respectively. Percent retention of nitrogen was 63.73 percent. Alkali treatment at 4 percent level, lowered significantly the crude fibre contents of the straw from 41.86 percent in control to 40.21 percent in the treated straw. Moisture level of 40 percent significantly lowered (p < 0.05) the crude fibre contents. Total ash content of straw increased significantly by urea and alkali treatment. Alkali treatment improved significantly the sodium contents also. The results of the study indicated that most beneficial results were obtained with 4 percent urea, 4 percent alkali at 50 percent moisture level.

Modification of Wool Treated with Alkali and Alkali/CTAB (I) -Changes of chemical properties- (알칼리와 CTAB 처리에 의한 양모섬유의 개질(I) -화학적 성질의 변화-)

  • 김영리;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.5
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    • pp.728-737
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    • 1996
  • The purpose of this study is to investigate the change of the chemical properties of wool treated with six kinds of alkali (NaOH, Naac03, NH40H, NH2CH3CH30H, TMAH and BTMAH) with or without CTAB. Content of bound fatty acid liberated from wool surface, elemental composition and allw6rden time were measured to compare the surface modification of untreated and alkali treated wool. Also, the chemical degradation of the fiber was investigated by measuring cystine contents and urea-hydrogensulfite solubility. The result were as follows: 1. By the alkali treatment of wool, the covalently bound fatty acid of the epicuticle was removed and the allworden time was shortened, and in the case of wool treated with TMAH, BTMAH, the allw6rden sacs were formed unevenly and rarely. Also, cystine contents and urea-hydrogensulfite solubility were decreased by alkali treatment on wool. 2. The modification of epicuticle and the chemical degradation of wool were occurred due to alkaline hydrolysis in the order of TMAH, BTMAH > NaOH, Na3c03> NH2CH3CHaOH, NH40H. 3. As a treating time increased, the modification of epicuticle and chemical degradation of wool were accelerated. By the addition of CTAB to the alkali solution, the modification of epicuticle was increase, and the cystine contents and urea-hydrogensulfite solubility were reduced than that of wool teated with alkli without CTAB due to reduction of negative charge on the wool surface by the adhesion of CTAB.

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Preparations Purified Cellulose from Rice Hull (왕겨기반 고순도 셀룰로오스의 제조)

  • Lee, Young-Ju;Sung, Yong-Joo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.3
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    • pp.79-85
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    • 2012
  • In this study, purified cellulose was prepared from rice husk which is one of the major agricultural residues in Korea. The various bleaching processes such as ozone bleaching, $ClO_2$ bleaching and $H_2O_2$ bleaching were applied to remove residual lignin and impurities. In order to increase the contents of ${\alpha}$-cellulose contents, the effects of acid and alkali treatments were evaluated. Although the multi stages of the bleaching processes resulted in less than 0.5 % residual lignin contents, the application of ozone leaded to the decrease in DP(degree in Polymerization) and ${\alpha}$-cellulose contents. The alkali treatment after bleaching processes resulted in pure cellulose which showed more than 98% of ${\alpha}$-cellulose contents.

Effect of Cement Alkali Content on ASR Expansibility by the Test Method of ASTM C 1260 (ASTM C 1260 실험방법에 의한 시멘트 알칼리 함량이 ASR 팽창성에 미치는 영향)

  • Jeon, Sung Il;Son, Hyeon Jang;Kwon, Soo Ahn;Yun, Kyung Ku
    • International Journal of Highway Engineering
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    • v.14 no.6
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    • pp.37-43
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    • 2012
  • PURPOSES : This study is to evaluate the feasibility of setting the standard of cement alkali content by using ASTM C 1260(accelerated mortar bar test) METHODS : This study analyzes the ASR(alkali silica reaction) expansion of cement mortar bar based on the changes in the aggregate type(fine, coarse), cement type(ordinary, low alkali), and replacement contents of fly ash. ASR tests were conducted according to ASTM C 1260. RESULTS : In this test results, There is no big difference in the ASR expansion between ordinary cement and low alkali cement. From this test results, it was found that the variation of cement alkali content did not have a effect on ASR expansion because mortar bar was placed in a container with sufficient alkali aqueous solution at high temperature during the test process of ASTM C 1260. CONCLUSIONS : It is evidently clear that the alkali content of cement have a effect on ASR. But ASTM C 1260 is difficult to assess this effect.

Petrochemical Study of Alkali Granite in northern Area of the Uljin Mine (울진광산(蔚珍鑛山) 북부지역(北部地域)에 분포(分布)하는 알카리화강암(化崗岩)에 대(對)한 암석지화학적(岩石地化學的) 연구(硏究))

  • Kim, Yong Jun;Cho, Deung Lyong;Hong, Sei Sun
    • Economic and Environmental Geology
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    • v.19 no.2
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    • pp.123-131
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    • 1986
  • This study is focused on petrochemistry and petrogenesis of alkali granite which exposed at northern area of the Uljin mine in NE Korea. The rock is corresponded to the range of alkali feldspar granite and alkali feldspar quartz syenite on IUGS classification and contains characteristic Fe-rich biotite (annite) and sodic alkali amphibole (arfvedsonite). The alkali granite is the hypersolvus one-feldspar granite which is characterized by the absence of plagiclase except as a component of perthite and its normatve An contents are less than 5wt%. The bulk compositions of the alkali granite show reverse trends compared to Daly's. Tuttle and Bowen (1958) experimentally support that properties of the hypersolvus granite indicate that they have crystallized at high temperatures from a magma.

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Microstructural Characteristics of Alkali-Activated Cements Incorporating Fly Ash and Slag (플라이애시와 슬래그 혼합 알칼리 활성 시멘트의 미세구조 특성)

  • Jang, Jeong Gook
    • Journal of Urban Science
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    • v.7 no.1
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    • pp.39-43
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    • 2018
  • This study investigates microstructural characteristics of alkali-activated cements incorporating slag and fly ash. Samples were prepared with four fly ash:slag ratios, i.e., 100:0, 90:10, 70:30 and 50:50, and they were synthesized by using an alkali activator. Microstructural characteristics of the alkali-activated cements were determined by XRD, TGA, SEM, N2 gas adsorption/desorption methods, and compressive strength test. The results showed that properties of alkali-activated fly ash/slag were significantly affected by slag contents. Alkali-activated fly ash/slag with slag content of 30-50% showed higher compressive strength than ordinary Portland cement paste. An increase in slag content resulted in a denser microstructure, which composed of amorphous gel, therefore contributed to strength development of the material.

Changes in the Cell Wall Components of Persimmon Fruits during Maturation and Postharvest (감과실의 성숙과 추숙중의 세포벽 구성성분의 변화)

  • Shin, Seung-Ryeul;Kim, Ju-Nam;Kim, Soon-Dong;Kim, Kwang-Soo
    • Korean Journal of Food Science and Technology
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    • v.22 no.7
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    • pp.738-742
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    • 1990
  • Cell wall components were decreased during maturation and postharvest of persimmon fruits. Contents of pectin and alkali-soluble hemicellulose were increased during maturity, but those of acid-soluble hemicellulose were decreased. Contents of pectin and alkali-soluble hemicellulose were decrease in soft persimmon, whereas acid-soluble hemicellulose was increased remarkably. Cellulose contents were increased during maturation and this tend was notable in soft persimmon. Contents of cell wall polysaccharides per 100g-fresh weight were decreased. Contents of total pectin and insoluble pectin were increased during maturation but decreased in soft persimmon. Content of water-soluble pectin was increased during maturation and postharvest.

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Properties of Alkali Activated Inorganic Binder using Replacement Materials Alkali Activator with Red Mud (알칼리 자극제 대체재로써 레드머드를 사용한 알칼리 활성 무기결합재의 특성)

  • Park, Sun-Gyu
    • Proceedings of the Korea Contents Association Conference
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    • 2014.11a
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    • pp.139-140
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    • 2014
  • 최근 건선산업에서 문제점으로 지적되고 있는 것은 제조과정 중 이산화탄소를 다량 방생시키는 시멘트의 사용이다. 이는 알칼리활성 무기결합재로 대체함으로써 시멘트보다 이산화탄소 배출량을 저감할 수 있지만 고가의 알칼리 자극제를 다량 사용하기 때문에 경제적 측면 및 사용성을 고려하지 않으면 사용할 수 없기 때문에 이에 대한 대체재에 관한 연구가 필요한 실정이다. 이에 본 연구에서는 고로슬래그를 기반으로 하는 알칼리 활성 무기결합재에 알칼리 자극제의 사용량을 저감하기 위해 레드머드를 사용하고, 레드머드에 적합한 알칼리 자극제의 종류와 사용방법에 대하여 연구하고자 하였다.

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Alkali-Silica Reaction of Accelerating Agents in Shotcrete (숏크리트용 급결제의 알칼리-실리카 반응성 검토)

  • Choi, Bo-Ra;Hong, Byung-Tak;Lee, Jae-Wan;Lee, Su-Jin;Park, Hae-Kyun;Won, Jong-Pil
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.323-324
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    • 2010
  • The purpose of this study was to investigate alkali-silica reaction of accelerating agents in shotcrete. The test was performed with accelerating agents (aluminate, alkali-free, cement based mineral admixture) in the Type I cement. As a test result, using the nonreactive aggregates, detrimental expansion due to alkali-silica reaction doesn't occurred regardless of equivalent alkali contents of accelerating agent.

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