• Bulletin of the Korean Chemical Society
• /
• 제27권12호
• /
• pp.2040-2044
• /
• 2006

Dielectric studies of methyl acrylate with 1-propanol, 1-butanol, 1-heptanol and 1-octanol binary mixtures have been carried out over the frequency range from 10 MHz to 10 GHz at temperatures of 283, 293, 303 and 313 K using Time Domain Reflectometry (TDR) for various concentrations. The Kirkwood correlation factor and excess inverse relaxation time were determined and discussed to yield information on the molecular structure and dynamics of the mixture. The values of the static dielectric constant, relaxation time and the Kirkwood correlation factor decrease with increased concentration of methyl acrylate in alcohol. The Bruggman plot shows a non-linearity of the curves for all the systems studied indicates the heterointeraction which may be due to hydrogen bonding of the OH group of alcohol with C=O of the methyl acrylate. The excess inverse relaxation time values are negative for all the systems at all the temperatures indicates that the solute-solvent interaction hinders the rotation of the dipoles of the system.

• KSBB Journal
• /
• 제9권4호
• /
• pp.406-411
• /
• 1994

용매추출에 의한 구연산발효를 시도하였다. 발효 배지내 구연산 농도와 추출용매의 독성이 구연산의 생산성을 결정하는 주 인자였다. 특히 이온화되지 않은 구연산은 강력한 발효억제효과를 가져 구연산 농도가 $5g/\ell$ 이상이면 구연산 생산은 거의 중지되었다. 구연산 추출효율을 높이기 위해 3차 아민과 oleyl alcohol의 혼합액을 용매로 사용하였다. 구연산의 추출발효에 척함한 용매조성은 30% 아민 70 % oleyl alcohol로 밝혀졌다. 이 조건에서 추출발효시 구연산농도는 $15.2g/\ell$ 로 동임한 조건에셔 용매 를 첨가하지 않고 발효하여 얻은 구연산농도 $5g/\ell$에 비해 3배 이상 높았다. 아빈 농도가 30%를 념으 면 추출능은 향상되나 용매의 독성효과로 생산성은 오히려 감소하였다. 균체에 대한 용매의 독성효과는 균체를 polyure-thane foam에 고정화함으로써 현저하게 줄일 수 있었다.

• Advances in Computational Design
• /
• 제8권2호
• /
• pp.113-131
• /
• 2023

The use of fibers has been commonly considered in engineered cementitious composites, but their behavior with coarse aggregate in concrete has not been studied significantly, which is needed to meet structural performance objectives for design, such as ductility. This research analyzes the behavior of fiber-reinforced concrete with coarse aggregate with 0.62%, 1.23%, and 2% PVA (Polyvinyl-alcohol) content, varying the maximum aggregate size. Tensile (direct and indirect) and compressive concrete tests were performed. The PVA fiber addition in coarse aggregate concrete increased the ductility in compression, especially for the fiber with a larger aspect ratio, with a minor impact on strength. In addition, the tensile tests showed that the PVA fiber increased the tensile strength of concrete with coarse aggregate and, more significantly, improved the ductility. A selected mixture was used to build short and slender reinforced concrete beams to assess the behavior of structural members. PVA fiber addition in short beams changed the failure mode from shear to flexure, increasing the deflection capacity. On the other hand, the slender beam tests revealed negligible impact with the use of PVA.

• 한국수소및신에너지학회논문집
• /
• 제34권6호
• /
• pp.767-772
• /
• 2023

In this study, combustion experiments were conducted at various engine speeds under full-load conditions using a single-cylinder diesel engine by blending butanol, pentanol, and octanol with diesel at a volume ratio of 10%. Experimental results revealed that higher alcohol-diesel blends resulted in lower brake torque and brake power than pure diesel due to the lower calorific value and the cooling effect during evaporation. An evident improvement in the brake thermal efficiency of the blended fuels was observed at engine speeds below 2,000 rpm, with the butanol blend exhibiting the highest thermal efficiency overall. Furthermore, the brake-specific fuel consumption of the higher alcohol-diesel blends was lower than that of pure diesel at speeds below 2,200 rpm. When using blended fuels, the exhaust gas temperature decreased under lean mixture conditions due to heat loss to the air and the cooling effect from fuel evaporation.

• Nuclear Engineering and Technology
• /
• 제39권6호
• /
• pp.731-736
• /
• 2007

Radioactive organic wastes containing acetone, alcohol, and particularly tributyl phosphate (TBP)/dodecane contaminated with uranium are extracted from the PUREX process and the decontamination of related equipment. An evaporation method that utilizes existing DU oxidation apparatuses and ventilation systems and a typical muffle furnace installed with an aspirating system are adopted. A separation method using phosphoric acid especially for the TBP/dodecane waste is also studied and evaluated. The results show that a simple evaporation process is utilizable for wastes containing acetone or alcohol with a lower boiling point. A modified muffle furnace is more appropriate to dispose directly of organic wastes having a higher boiling point, such as TBP/dodecane, without generating a condensed waste solution. It is recommended that, when the uranium concentration of TBP/dodecane waste is much higher than stipulated levels, separation technology should be applied to remove uranium from the mixture. Each type of solvent after separation can then be considered disposable below the regulatory limit in the modified furnace discussed in this study.

• Bulletin of the Korean Chemical Society
• /
• 제13권6호
• /
• pp.647-649
• /
• 1992

The critical micelle concentration (CMC) values of cetylpyridinium chloride (CPC) in some alcohol-aqueous solutions were determined by UV-Vis spectroscopy at 25$25^{\circ}C$. The CMC of CPC was increased with the addition of methanol and ethanol, while with the addition of propanol it was decreased because of the solubilization of propanol into the micelle of CPC. The ratio (${\beta}$) of the number of counterions to that of surfactant ions associated into micelles in alcohol (methanol, ethanol and propanol) aqueous solutions was measured by using the Shinoda $equation^{17}$. The ratio of counterion binding to the CPC micelles in methanol-and ethanol-water mixtures was larger than in pure water, while the ratio in propanol-water mixture might be much decreased.

• 교육시설 논문지
• /
• 제19권5호
• /
• pp.29-36
• /
• 2012

The goals of this study are to develop a sprayable strain-hardening cement composite (SHCC) and to investigate the potential of the sprayable SHCC for packing the joint between existing R/C building and seismic retrofit elements. This paper provides the procedure for the development of a sprayable SHCC, test results of fresh properties required to a sprayable SHCC, and mock-up test results of developed sprayable SHCC. Control mixture of polyvinyl alcohol (PVA) fiber-reinforced SHCC (PVA-SHCC) was predetermined based on available research results. The pumpability and sprayability of the SHCC mixture were depended on the fluid property of fresh SHCC mixture. In this study, the effects of admixtures such as AE agent and fly ash on the rheological and rebound properties of control SHCC mixture were investigated to determine a sprayable SHCC mixture. Flow values and air content during shotcreting procedure of sprayable SHCC were also evaluated. The results show that flow or flowability and amount of air of three SHCC mixtures decreased almost linearly according to shotcreting procedure from mixer to nozzle. And the pumpability and sprayability of mixture with AE agent and low amounts of fly ash were superior to the those of SHCC. Mock-up test result show that developed sprayable SHCC indicates much improved workability and shotcrete construction period than conventional method(nonshrinkage mortar).

• Biotechnology and Bioprocess Engineering:BBE
• /
• 제2권2호
• /
• pp.109-112
• /
• 1997

Morphology of carbonate crystals grown on the surface of artificial cell membranes was controlled by changing the interfacial chemistry. For octadecyltriethoxysilane (OTE) films with terminal methyl groups interacting little with an aqueous calcium carbonate solution calcite (104) crystals were formed. Polymerized pentacosadiynoic acid (PDA) films with terminal carboxylic acid groups induced deposition of calcite (012) crystals aligned along with each other within a polymer domain. On the other hand, stearyl alcohol (StOH) films with terminal hydroxyl groups induced deposition of aragonite crystals. When PDA was mixed with StOH, the 8:1 PDA:StOH (molar ratio) film produced dominating calcite (012) crystals without any crystal alignment, and the 4:1 mixture film produced minor calcite (012) crystals and major aragonite crystals. For the 2:1, 1:1, 1:2, and 1:4 mixture films, aragonite crystals were dominating. Hence, it is found that the chemical composition at the interface plays a very important role in controlling the morphology of deposited carbonate crystals.

• Bulletin of the Korean Chemical Society
• /
• 제30권10호
• /
• pp.2381-2386
• /
• 2009

The tetrakis(thio)-substituted-1,4-benzoquinone products 4a-e, 6, 7, and the mono(alkoxy)-tris(thio)-substituted-1,4- benzoquinone products 5a-e and 8a-e were synthesized from the reactions of p-chloranil with some thiols and mixture of two different thiol compounds in alcohol in the presence of $Na_2CO_3$ at room temperature. The structures of the novel S,S,S,S- and S,S,S,O- substituted products, which were obtained by the reactions of p-chloranil as a starting compound with n-propanethiol, n-pentanethiol, n-decanethiol, n-dodecanethiol, 2-methyl-2-propanethiol, and mixture of n-decanethiol and n-cyclohexanethiol as S-nucleophiles, were characterized by spectroscopic methods.

• Macromolecular Research
• /
• 제13권5호
• /
• pp.385-390
• /
• 2005

The electrospinning process is a fascinating method to fabricate small nanosized fibers of diameter several hundred nanometers. Surfactant-polymer solutions were prepared by adding poly(vinyl alcohol) (PVOH) to distilled water with cationic, anionic, amphoteric, and non-ionic surfactants. Average diameter of the electrospun PVOH fibers prepared from PVOH solution was over 300 nm, and was decreased to 150 nm for the mixture of PVOH/amphoteric surfactant. To explain the formation of ultra fine fiber, the characteristic properties in a mixture of PVOH/surfactant such as surface tension, viscosity, and conductivity were determined. In this paper, the effect of interactions between polymers with different classes of surfactants on the morphological and mechanical properties of electrospun PVOH nonwoven mats was broadly investigated.