• Title/Summary/Keyword: air solution product

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Photolysis of Aqueous Ammonia in the Absence and the Presence of O₂

  • 박형련;김희정;성아영
    • Bulletin of the Korean Chemical Society
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    • v.17 no.9
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    • pp.798-802
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    • 1996
  • The photochemical decomposition of aqueous ammonia in the absence (saturated with argon) and the presence of O2 (saturated with air or oxygen) has been investigated using 184.9 nm UV light. The decomposition of ammonia depended on the concentration of oxygen in the solution. With increasing the concentration of oxygen, the decomposition of ammonia diminishes. Hydrazine is found the major product from the irradiation. In the presence of oxygen, hydrogenperoxide was also produced. The product yields depended also on the concentration of oxygen in the solution. The initial quantum yield of the products and of the ammonia decomposed were determined. Probable reaction mechanisms for the reaction were presented from the products analysis.

Research on Odor Analysis Technology to Secure the Reliability of Air Quality Improvement in Air Conditioners (에어컨디셔너 공기질 개선의 신뢰도 확보를 위한 냄새 분석 기술 연구)

  • Kang, Seok-Hyun;Huh, Pil-Ho;Ahn, Young-Chull
    • Journal of Environmental Science International
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    • v.30 no.1
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    • pp.45-55
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    • 2021
  • In this study, the odor of the parts and the odor of the surrounding environment were classified and verified. In order to increase the reliability of odor quantitative/qualitative analysis, the selection criteria for 5 sensory evaluators were established, and the n-Butanol control solution for each odor intensity was periodically trained to recognize the odor intensity before sensory evaluation. In addition, although various odor thresholds have been used through several studies, verification of whether the odor intensity value obtained through GC/MSD analysis is similar to the degree to which a person directly smells and feels it. It is important to select the odor threshold that has the best correlation with the odor intensity calculated by the person smelling the odor. Finally, sampling and measuring flowing airflow and temporary odors such as odor component analysis was experimentally difficult due to limited collection space and differences in concentration of generated components. In this study, a quantitative analysis was made possible by using the low temperature concentration (cooling) trap method. Through this, it was confirmed that the correlation with the actual odor intensity was not caused by the product itself, but by the environmental factor discharged from the product after creating the odor environment.

Processing of Dried Products of Ascidian , Halocynthia roretzi (우렁쉥이 건제품 개발에 관한 연구)

  • Lee, Kang-Ho;Hong, Byeong-Il;Jung, Byung-Chun;Cho, Ho-Sung;Lee, Dong-Ho;Jung, Woo-Jin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.4
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    • pp.625-633
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    • 1994
  • In this study, processing of dried products of adcidian , Haocynthia roretzi, were investigated, which has been cultured in the south and east coast of Korea in recent years. Raw ascidians were shucked , gutted, soaked and then drained. Seven kinds of dried ascidian meats were prepared : boiled in 5% slat solution for 10 min and hot-air dried (A)-sun dried (B) or hot-air dried (C) after soaking for 1 min in 0.2% NaHSO3 solution , sun dried (D) or hot -air dried (G) after treating for 15 sec in 5% liquid smoke solution, and sun dried (E) or hot -air dried (F) after blanching for 30 sec in boiling 5% salt solution added with 0.2% NaHSO3. The moisture contents, water activity of the products showed little change and VBN gradually increased during storage at 25 $\pm$2$^{\circ}C$. The TBA and POV values of the liquid smoked dried ascidian (product D, G0 were considerably lower than those of others, In fatty acid composition 22 : 6 , 20 : 5 : 16: 0 and 18 : 1 acid were predominant. Conditions adopted in products D and G had a good antioxidative effect on highly unsatuated fatty acids during the storage. The contents of inosine and AMP of products were higher than those of other nucleotide and their related compounds. Judging from the results of chemical experiments and sensory evaluation, the sample A, D and G were most desirable and they could be preserved more than 120 days at room temperature(25$\pm$2$^{\circ}C$).

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A Study on the Physical Property of concrete using Industrial by-product and Alkali Activators (산업부산물과 알칼리 활성제를 사용한 콘크리트의 물리적 특성에 관한 연구)

  • Lee, Sun-Kwan;Kim, Young-Su
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.54-55
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    • 2013
  • Recently, The economic growth has increased carbon dioxide emissions. so, It is caused by social problem to environmental damage and human health due to global warming. Accordingly, The method solution is to the amount of cement and to use industrial by-product such as Blast furnace slag, Fly Ash, and Red-mud. Thus, The purpose of this study is to analyze the physical property of concrete with red-mud. So, this study carries out the basic performance test of concrete such as, air content, slump, and compressive strength. In this work test is conducted according to sequence of materials using concrete twin mixer.

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Thermal Reaction of Iron Precipitates Prepared by Adding Sodium Carbonate Solution to Ferrous Chloride and Ferric Chloride Solutions (염화철과 탄산나트륨 용액에 의한 철 침전물의 열반응)

  • 이서우;김태옥;김종희
    • Journal of the Korean Ceramic Society
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    • v.18 no.2
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    • pp.105-111
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    • 1981
  • The iron precipitates were prepared by adding sodium carbonate solution to ferrous chloride and ferric chloride solutions to pH=9 and pH=4.5, respectively. The thermal reaction of the iron precipitates was investigated by means of TGA, DTA and X-ray diffraction. In the former the crystallization of $\alpha$-$Fe_2O_3$ begins at about 35$0^{\circ}C$, while in the latter at about 30$0^{\circ}C$, during the calclnation in air. In the iron precipitate from ferrous chloride solution, the activation energy for the crystallite-growth or $\alpha$-TEX>$Fe_2O_3$ in air is about 7.6$\times$104J/mole between 800 and 100$0^{\circ}C$. As the result of X-ray diffration for the reduction product of hematite, it was found that maghemite, magnetite and wustite are formed and that hematite is transformed to magnetite through maghemite.

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Atmosphere Effects in Low Temperature Pyrolysis of Chemical Solution Derived Pb(Zr, Ti) O3 Films

  • Hwang, Kyu-Seog;Lee, Hyung-Min;Kim, Byung-Hoon
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.199-203
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    • 1998
  • $Pb(Zr, Ti)O_3$ (Pb:Zr:Ti=1:0.52:0.48) thin films were prepared on single crystal MgO(100) substrates by dipping-pyrolysis process using a solution of constituent metal naphthenates as starting materials. The solution was spin-coated onto substrate and the precursor films were pyrolyzed at $200^{\circ}C$ in air or at $200^{\circ}C$ in argon for 1, 2, 5 and 24h, followed by final heat treatment at $750^{\circ}C$. For all the films, highly (h00)/(00l)-oriented Pb$Pb(Zr, Ti)O_3$ thin films with smooth surfaces and crack-free were obtained, whereas thin film pyrolyzed in air for 24 h exhibited polycrystalline character. According to the pole-figure analysis, epitaxy of the product films was found to depend on pyrolysis atmosphere.

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Photochemical Reaction of Nalidixic Acid in Methanol

  • Park, Hyoung-Ryun;Park, Ok-Hyun;Lee, Hong-Yune;Seo Jung-Ja;Bark, Ki-Min
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1618-1622
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    • 2003
  • The photochemical reactions of methanolic nalidixic acid (NAL) solution in the absence and in the presence of air have been investigated using 300 nm UV light. From the reactions, 1-ethyl-7-methyl-4-oxo-4-hydro-1,8-naphthyridine (EMDN),formic acid, and formaldehyde are produced. In the presence of air, hydrogen peroxide is also detected along with the products listed above. The presence of oxygen during the irradiation of methanolic NAL solution effects on the product yield. The initial quantum yields of the products and of the NAL decomposition are determined. Possible reaction pathways for the photochemical reaction are suggested on the basis of the products analysis.

Evaluation of Micro-defects and Air Tightness of Al Die-casting by Impregnation of Organic Solvent (유기용제 함침법을 통한 알루미늄 다이캐스팅의 미세결함 및 기밀성 평가)

  • Lee, Jin-Wook;Cho, Chang-hyun;Kim, Sung-Gye;Ko, Young-Gun;Kim, Dong-Ju
    • Journal of Korea Foundry Society
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    • v.42 no.4
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    • pp.218-225
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    • 2022
  • For hydrogen-vehicle applications (air pressure control valve housing, APCVH), an investigation was conducted to determine how micro-defects in a high- pressure die-casted Al alloy (industrial code: ALDC12) could be controlled by means of a post-treatment using an organic-based impregnation solution in order to improve the air- tightness of the die-casted Al sample. Two different impregnation solutions were proposed and its test results were compared to a imported product from Japan with respect to the processing variables used. A structural investigation of the components under study was conducted by means of computer tomography and 3D X-ray micro-CT. These observations revealed that the use of the impregnation treatment to seal micro-defects led to highly significant and beneficial changes which were attributed mainly to interconnections among inherent micro-pores. A leak test after impregnation revealed that the performance improvement rate of the die-casted Al sample was ~70% for INNO-01. Therefore, the developed impregnation solutions offer an effective strategy to control the micro-defects found in various vehicle parts via die-casting.

Development of Enhanced Interleaved PFC Boost Converter typed 650V Intelligent Power Module for up to 10kW HVAC Systems (10kW급 HVAC 시스템을 위한 Enhanced Interleaved PFC Boost 컨버터 형태의 650V IPM 개발)

  • Lee, Kihyun;Hong, Seunghyun;Kim, Taehyun;Jeong, Jinyong;Kwon, Taesung
    • Proceedings of the KIPE Conference
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    • 2018.07a
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    • pp.536-538
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    • 2018
  • This paper introduces an enhanced interleaved (IL) PFC (Power Factor Correction) boost converter typed 650V Intelligent Power Module (IPM), which is fully optimized hybrid IGBT converter modules; Silicon (Si) IGBT and Silicon Carbide (SiC) diode, for up to 10kW HVAC (Heating, Ventilation, and Air Conditioning) systems. It utilizes newly developed $4^{th}$ Generation Field Stop (FS) trench IGBTs, $EXTREMEFAST^{TM}$ anti-paralleled diodes, SiC Junction Barrier Schottky (JBS) diodes, Bridge rectifiers, Multi-function LVIC, and Built-in thermistor provide good reliable characteristics for the entire system. This module also takes technical advantage of DBC (Direct Bonded Copper) substrate for the better thermal performance. It is shown that the Si IGBT/SiC diode hybrid IL PFC module can achieve excellent EMI performance and greatly enhance the power handling capability or switching frequency of various applications compared to the Si IGBT/Diode. This paper provides an overall description of the newly developed 650V/50A Hybrid SiC IL PFC IPM product.

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Acoustic Signal based Optimal Route Selection Problem: Performance Comparison of Multi-Attribute Decision Making methods

  • Borkar, Prashant;Sarode, M.V.;Malik, L. G.
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.10 no.2
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    • pp.647-669
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    • 2016
  • Multiple attribute for decision making including user preference will increase the complexity of route selection process. Various approaches have been proposed to solve the optimal route selection problem. In this paper, multi attribute decision making (MADM) algorithms such as Simple Additive Weighting (SAW), Weighted Product Method (WPM), Analytic Hierarchy Process (AHP) method and Total Order Preference by Similarity to the Ideal Solution (TOPSIS) methods have been proposed for acoustic signature based optimal route selection to facilitate user with better quality of service. The traffic density state conditions (very low, low, below medium, medium, above medium, high and very high) on the road segment is the occurrence and mixture weightings of traffic noise signals (Tyre, Engine, Air Turbulence, Exhaust, and Honks etc) is considered as one of the attribute in decision making process. The short-term spectral envelope features of the cumulative acoustic signals are extracted using Mel-Frequency Cepstral Coefficients (MFCC) and Adaptive Neuro-Fuzzy Classifier (ANFC) is used to model seven traffic density states. Simple point method and AHP has been used for calculation of weights of decision parameters. Numerical results show that WPM, AHP and TOPSIS provide similar performance.