• 제목/요약/키워드: air oxidation

검색결과 951건 처리시간 0.027초

DPF 재생을 위한 버너-산화촉매 복합 적용 (Combined Application of Burner and Oxidation Catalyst for Diesel Particulate Filter Regeneration)

  • 심성훈;정상현
    • 한국연소학회지
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    • 제15권3호
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    • pp.25-31
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    • 2010
  • Combined technique of burner and DOC has been used for regeneration of Diesel Particulate Filter. Experiments has been performed to increase the temperature of engine exhaust gas to burn the collected soot in DPF at all conditions of operation of 3 liter diesel engine. Ignition temperature of soot can be successfully obtained by heats of burner flame and residual fuel oxidation at diesel oxidation catalyst even in the condition of oxygen deficiency. It is found that the load of air compressor and heat loss can be reduced to the level of practical application. It is also found that CO and THC emissions are not increase by additional combustion of regeneration burner.

강 기판위에 이온 플레이팅된 TiCrN 박막의 산화기구 (Oxidation Mechanism of TiCrN Coatings Ion-plated on Steel Substrate)

  • 이동복;김기영
    • 한국재료학회지
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    • 제13권7호
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    • pp.420-423
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    • 2003
  • Coatings of TiCrN ion-plated on a steel substrate was oxidized at $800^{\circ}C$ in air, and their oxidation mechanism was presented. During oxidation, substrate elements and Ti and Cr in the coating always diffused outwardly to form the oxide scale. Simultaneously, oxygen from the atmosphere diffused inward1y to react with Ti and Cr to form $TiO_2$and $Cr_2$$O_3$, respectively. Also, the counter-diffusion of cations and oxygen resulted in some oxygen dissolution in the unoxidized TiCrN coating, and Fe dissolution in the oxide scale. When the Ti content in the coating was high, the $TiO_2$-forming tendency was strong, while when the Cr content was high, the $Cr_2$$O_3$-forming tendency was strong.

반응소결에 의하여 제조된 $SiC/MoSi_2$ 복합체의 산화 거동 (Oxidation Behavior of $SiC/MoSi_2$ Composites Prepared by Reaction Sintering Method)

  • 양준환;한인섭;우상국;서동수
    • 한국세라믹학회지
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    • 제31권12호
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    • pp.1588-1598
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    • 1994
  • The SiC/MoSi2 composite materials were fabricated by infiltrating the mixture of molybdenum disilicide and metal silicon(MoSi2+Si=100) to a porous compact of silicon carbide and graphite under the vacuum atmosphere of 10-1 torr. The specimen were oxidized in dry air under 1 atm at 130$0^{\circ}C$~150$0^{\circ}C$ for 240 hours. The oxidation behavior was evaluated by the weight gain and loss per unit area of the oxidized samples. Also, SEM and XRD analysis of the oxidized surface of the samples were carried out. With increasing the MoSi2 content and oxidation temperature, the passive oxidation was found. The trend of weight gain of all samples was followed the parabolic rate law with the formation of a protective layer of cristobalite on the surface.

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화염편모델을 이용한 층류확산화염장의 매연 생성 및 산화과정 해석 (Flamelet Modelling of Soot Formation and Oxidation in a Laminar $CH_4$-Air Diffusion Flame)

  • 김군홍;김후중;김용모;김성구
    • 한국연소학회:학술대회논문집
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    • 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
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    • pp.3-9
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    • 2003
  • By utilizing a semi-empirical soot model, the applicability of the laminar flamelet concept for simulating the formation and oxidation of soot in the laminar diffusion flame has been studied. The source terms for two transport equations of the soot formation and oxidation are calculated in the mixture fraction/scalar dissipation rate space for laminar flamelets and stored in a library. In this study, emphasis is given to the interaction associated with radiation and soot formation. The radiative heat loss is obtained by solving the radiative transfer equation using the unstructured grid finite volume method with the WSGGM. The calculated temperatures and soot volume fractions agree relatively well with the experimental data and the previous numerical results of Kaplan et al. using the detailed chemistry.

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Effects of Cr and Nb on the nigh Temperature Oxidation of TiAl

  • D.B. Lee;K.B. Park;M. Nakamura
    • 소성∙가공
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    • 제8권3호
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    • pp.319-319
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    • 1999
  • From isothermal and cyclic oxidation tests on thermomechanically treated Ti-5%Al, Ti47%Al-4%Cr, and Ti-48%Al-2%Cr-2%Nb alloys at 800, 900, 1000℃ in air, it was found that Ti-48%Al-2%Cr-2%Nb and Ti-47%Al-4%Cr had the best and the worst oxidation resistance, respectively. The oxide scales consisted primarily of TiO₂and Al₂O₃, with and without a small amount of dissolved Cr and 7b ions, depending on the alloy composition. These ions were slightly enriched inside the inner oxide layer, and strongly enriched around the scale-matrix interface. The outer TiO₂-rich layer was formed by the outward diffusion of Ti ions, while the inner (TiO₂+A1₂O₃,) mixed layer was formed by the inward transport of oxygen. The outward movement of Al ions farmed the intermediate Al₂O₃-rich Iayer, above talc prepared alloys.

High Temperature Oxidation Behavior of Mg-6%Al-1%Zn-1%CaO Alloys

  • Lee, Dong Bok;Kim, Min Jung
    • 한국표면공학회지
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    • 제50권1호
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    • pp.42-45
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    • 2017
  • The magnesium-base AZ61 alloy was cast while adding 1% CaO powder into the melt. It was hot extruded, and oxidized at $550-650^{\circ}C$ in air in order to study its microstructure and oxidation behavior. Initially added CaO powder reacted with Al in the melt to $Al_2Ca$ particles that aligned along the extrusion direction. The formed $Al_2Ca$ particles increased the oxidation resistance through forming the superficial CaO scale at the upper part of the thin MgO oxide scale.

ZrO2/Al2O3 박막의 고온산화 (High-temperature Oxidation of ZrO2/Al2O3 Thin Films)

  • Park, Soon Young;Yadav, Poonam;Abro, Muhammad Ali;Lee, Dong Bok
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2014년도 추계학술대회 논문집
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    • pp.117-117
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    • 2014
  • Thin $ZrO_2/Al_2O_3$ films were deposited on a tool steel substrate using Zr and Al cathodes in a cathodic arc plasma deposition system (CAPD), and then oxidized at $600-900^{\circ}C$ in air for up to 50 h. They effectively suppressed the oxidation of the substrate up to $800^{\circ}C$ by acting as a barrier layer against the outward diffusion of the substrate elements and inward diffusion of oxygen. However, rapid oxidation occurred at $900^{\circ}C$ due mainly to the increased diffusion and subsequent oxidation of steel as well as the crystallization of amorphous $Al_2O__3$.

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일렉트로 슬래그로 재용해한 Fe-22Cr-5Al 합금의 미세조직 및 고온 산화 거동에 미치는 첨가 원소의 영향 (Effect of Alloying Elements on the Microstructure and High Temperature Oxidation Behavior of the Electro-Slag Remelted Fe-22Cr-5Al Alloy)

  • 김문현;이정근;주대헌;김명호
    • 한국주조공학회지
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    • 제22권6호
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    • pp.293-298
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    • 2002
  • The effects of alloying elements added on the microstructure and high temperature oxidation behavior of the electro-slag remelted Fe-22Cr-5Al alloy were investigated. The amount of casting defect was makedly reduced by the electro-slag remelting. The electro-slag remelted ingot had a directionally solidified structure and cleaner surface than that of air-melted one. The high temperature oxidation reststance was greatly improved by the addition of Be and Zr.

국산 Superalloy의 고온 산화 거동 (Isothermal Oxidation Behaviour of Domestic Superalloys at Elevated Temperature)

  • 강은철;전영건;김길식
    • 한국표면공학회지
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    • 제24권3호
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    • pp.151-161
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    • 1991
  • The isothermal oxidation behaviour of commercial superalloys produced in Korea was investigated by using Cahn-2000 microbalance in air at $1000^{\circ}C$ and $1100^{\circ}C$. The effect of alloying elements on the isothermal oxidation was studied by examination of the oxide structures, their morphologies, and EDS linescanning and mapping of cross-section of oxidized specimens. Generally, external Cr2O3 films were formed on all alloy surface, but were not pure, The effect on the oxidation behaviour of refractory elements such as Nb, Mo in Inconel 718 was considered to be deleterious, and the formation of internal Al oxide in Inconel 601 was beneficial.

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The Effect of Oxygen Introduction on Oxidation Resistance and Cutting Performance of Silicon Nitride Ceramics

  • Nagano, Mituyoshi;Sano, Hideaki;Sakaguchi, Shigeya;Zheng, Guo Bin;Uchiyama, Yasuo
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.857-858
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    • 2006
  • In order to clarify the wear resistance as cutting tools, the effect of oxygen addition on oxidation behavior of the ${\beta}-Si_3N_4$ ceramics with 5 mass% $Y_2O_3$ and 2 or 4 mass% $Al_2O_3$ was investigated by performing oxidation tests in air at $1300^{\circ}$ to $1400^{\circ}C$ and cutting performance tests. From test results, we could conclude that the mechanical properties of ${\beta}-Si_3N_4$ ceramics depending on oxygen introduction are much effective on cutting performance improvements of ${\beta}-Si_3N_4$ ceramics.

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