• Title/Summary/Keyword: agitation effect

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Changes in Fatty Acid Composition During Partial Hydrogenation of Soybean Oil (콩기름의 수소첨가 반응시 지방산 조성의 변화)

  • Kwon, Hye-Soon;Yum, Cho-Ae
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.2
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    • pp.57-63
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    • 1993
  • This study investigated the reaction and variation of fatty acid composition of soybean oil when it is partially hydrogenated until its iodine value(IV) shifts from 134 to 110. Experment was conducted under he outlined reactiion conditions of temperatures(170, 190 and $210^{\circ}C$), pressure(1.3, 2.8 and 4.2atm) and nickel(Ni) catalyst concentraons(0.005, 0.01, 0.05, and 0.1%) with a fixed agitation(350rpm). Further investigation was also made to see the effect of added lecithin on hydrogenation. When reaction temperature was gradually raised and catalyst concentration increased, the content of linolenic acid progressively decreased while the increase amount of stearic acid reduced(P<0.05). On he other hand when pressure gradually increased, the contents of stearic acid and linolenic acid increased(P<0.05). Meanwhile when lecithin was added, reaction time increased by two to six times more than when no addition was made.

Cellular Lipid Formation by Petroleum Hydrocarbon Fermentation (石油炭化水素 醱酵에 의한 脂質의 生成)

  • Park Tai Won;Suh Hyung Joon
    • Journal of the Korean Chemical Society
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    • v.21 no.6
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    • pp.449-452
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    • 1977
  • The effect of carbon number of hydrocarbon used as a carbon source in the production of cellular lipid of Rhodotorula sp. and its fatty acid composition were investigated. Using Rhodotorula sp. on n-tetradecane and n-hexadecane whose carbon numbers are even, fermentation was carried out in a jar fermentor of 2 liter-capacity at $28^{\circ}C$, with pH range of 4.0∼4.6 and at oxygen flowing rate of 0. 4 vvm and agitation velocity of 1000 rpm. Drying the produced cell after completion of fermentation, cellular lipid was extracted from the cell using soxhlet extractor and examined its fatty acid composition by gas-liquid chromatography. Cellular lipid content in the cell produced on n-tetradecane and n-hexadecane were 12.0 % and 25,8 % on the basis of dry cell weight, respectively and their fatty acids were mostly even numbered in carbon number.

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Formation of Cheese Flavor and EMC Technology (치즈 풍미성분의 형성과 EMC 제조기술)

  • Han, Kyeong-Sik;Jeon, Woo-Min
    • Journal of Dairy Science and Biotechnology
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    • v.21 no.2
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    • pp.88-96
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    • 2003
  • Cheese flavor is derived from three main pathways, that are proteolysis, lipolysis and glycolysis, the extent of which varies according to the cheese variety. Proteolysis is the most complex of the three primary events during cheese ripening. The basis of EMC technology is the use of specific enzymes acting at optimum conditions to produce required cheese flavors from suitable substrates. These enzymes consist of proteinases, peptidases, lipases, esterases. The key factors in EMC production are the type of cheese flavor required, the type and specificity of enzyme or cultures used, their concentration and some processing parameters, such as pH, temperature, agitation, aeration, and incubation time. The emulsifiers, bacteriocins, flavor compounds, and precursors also effect to it importantly. The dosage of enzyme or starter culture used is dependent on the intensity of flavor required, processing time and temperature and the quality of the initial substrate. To produce a consistent EMC product it is necessary to have a highly controlled process, and a detailed knowledge of the enzymatic reactions under the conditions used must be fully understood.

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Adsorption of Hydrophobic Fluid by Polyurethane Foam (폴리우레탄 폼을 이용한 친유성 유체의 흡착)

  • Chai, Joo-Byung;Kim, Byung-Kyu;Shin, Young-Jo
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.648-653
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    • 1998
  • This study examines the effects of cell size and structure on the oil adsorption by polyurethane (PU) foam. A series of oil-adsorptive PU foam has been prepared, using various molecular weight of polyether polyol (GP-1000, GP-3000, GP-4000, GP-5000), together with TDI-80, water and additives. It was found that the cell size of PU foam decreased with increasing the agitation speed and surfactant content. Oil-adsotption of PU foam increased over 2000% with the increase of molecular weight of polyol and with the decrease of cell size. Increase in the surfactant content and the viscosity of adsorbed oil also give a remarkable decrease in oil adsorption.

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A study on the fabrication of porous cermet electrode for molten carbonate fuel cell anode (용융탄산염 연료전지 양극용 다공성 cermet 전극제조에 관한 연구)

  • Lee, K. H.;Chang, D. Y.;Kim, M.;Kang, S. G.
    • Journal of the Korean institute of surface engineering
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    • v.26 no.6
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    • pp.291-298
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    • 1993
  • In order to substitute for porous nickel anode in Molten Carbonate Fuel Cell(MCFC), porous cermet elec-trode was fabricated with Ni and Ni-P coated ceramic powder. Ni and Ni-P were coated by electroless plat-ing method in the nickel solution containing of hydrazine and sodium hypophosphate as a reducing agent. The plating solution was stirred by air and mechanical agitator. Ultrasonic irradiation was applied to the plating bath to improved the effect of agitation and coating speed. Electorde was formed by pressing method and doc-tor blade method followed by sinterd at$ 800^{\circ}C$ for 6 hours in H2 environment. Anode performance test carried out by potentiodynamic polarization technique in the MCFC operating condition and 154-161mA/$\textrm{cm}^2$ as ob-tained as a anode current density at the+100mV overpotential.

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Effect of Process Parameters on Microhardness of Ni-Al2O3 Composite Coatings (Ni-Al2O3 복합코팅의 마이크로 경도에 대한 공정변수의 영향)

  • Jin, Yeung-Jun;Park, Simon
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.6_2
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    • pp.1037-1045
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    • 2022
  • In this study, nanoscale Al2O3 ceramic particles were used due its exceptionally high hardness characteristics, chemical stability, and wear resistance properties. These nanoparticles will be used to investigate the optimal process conditions for the electro co-deposition of the Ni-Al2O3 composite coatings. A Watts bath electrolytic solution of a controlled composition along with a fixed agitation speed was used for this study. Whereas the current density, the pH value, temperature and concentration of the nano Al2O3 particles of the electrolyte were designated as the manipulative variables. The experimental design method was based on the orthogonal array to find the optimum processing parameters for the electro co-deposition of Ni-Al2O3 composite coatings. The result of confirmation experimental based on the optimal processing condition through the analysis of variance ; EDX analysis found that the ratio of alumina increased to 8.65 wt.% and subsequently the overall hardness increased to 983 Hv. Specially, alumina were evenly distributed on Nickel matrix and particles were embedded more firmly and finely in Nickel matrix.

Effect on the Production of Toxin Protein of Bacillus thuringiesis by Culture Conditions (배양 조건이 Bacillus thuringiesis 독소단백질의 생산에 미치는 영향)

  • Kim, Tae Wan;Kim, Tae Hwan;Yu, Yong Man
    • The Korean Journal of Pesticide Science
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    • v.18 no.4
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    • pp.358-363
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    • 2014
  • We was investigated parasporal inclusion proteins change to use industrial medium of new strain Bacillus thuringiensis CAB 565, CAB 566. To confirm medium's oxygen efficient consist of glucose and yeast extract, we was conducted oxygen transfer coefficients (KLa) of medium's concentration and impeller in 20 l-Jar fermentor. When to increase air flow rate and medium concentration, KLa rate is rise. Also it is effective on agitation rate 200 rpm, but KLa rate is decrease when to rise agitation rate. To hold dissolved oxygen rate (upper 50%), Air flow rate is steadily increase on culture to use microsparger. When 16 hour of culture stage, B.t. CAB 565 and B.t. CAB 566 harvested respectively $2.3{\times}10^{10}$, $1.8{\times}10^{10}$ viable cell/ml. When 54 hour, B.t. CAB565, 566 harvested respectively $1.9{\times}10^{10}$, $1.4{\times}10^{10}spore/ml$. To resulting carbon's concentration, It is the most effective that glucose concentration is contained 5% in medium.

Optimization of Production Medium by Response Surface Method and Development of Fermentation Condition for Monascus pilosus Culture (Monascus pilosus 배양을 위한 반응표면분석법에 의한 생산배지 최적화 및 발효조건 확립)

  • Yoon, Sang-Jin;Shin, Woo-Shik;Chun, Gie-Taek;Jeong, Yong-Seob
    • KSBB Journal
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    • v.22 no.5
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    • pp.288-296
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    • 2007
  • Monascus pilosus (KCCM 60160) in submerged culture was optimized based on culture medium and fermentation conditions. Monacolin-K (Iovastatin), one of the cholesterol lowing-agent which was produced by Monascus pilosus may maintain a healthy lipid level by inhibiting the biosynthesis of cholesterol. Plackett-Burman design and response surface method were employed to study the culture medium for the desirable monacolin-K production. As a result of experimental designs, optimized production medium components and concentrations (g/L) were determined on soluble starch 96, malt extract 44.5, beef extract 30.23, yeast extract 15, $(NH_4)_2SO_4$ 4.03, $Na_2HPO_4{\cdot}12H_2O$ 0.5, L-Histidine 3.0, $KHSO_4$ 1.0, respectively. Monacolin-K production was improved about 3 times in comparison with shake flask fermentation of the basic production medium. The effect of agitation speed (300, 350, 400 and 450 rpm) on the monacolin-K production were also observed in a batch fermenter. Maximum monacolin-K production with the basic production medium was 68 mg/L when agitation speed was 500 rpm. And it was found that all spherical pellets (average diameter of $1.0{\sim}1.5mm$) were dominant during fermentation. Based on the results, the maximum production of 185 mg/L of monacolin-K with the optimized production medium was obtained at pH (controlled) 6.5, agitation rate 400 rpm, aeration rate 1 vvm, and inoculum size 3%.

Self Healing System for Concrete Surface Crack using Polymer based Coating Agent Incorporating Microencapsulated Healing Agent (마이크로캡슐을 함유한 폴리머 코팅제의 콘크리트 표면균열 자기치유시스템)

  • Shin, Ki-Su;Ryu, Byung-Chul;Wang, Xiao-Yong;Park, Ki-Bong
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.6
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    • pp.579-587
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    • 2015
  • In this paper, microencapsulated healing agent was embedded in the polymer matrix to obtain self healing properties. Microencapsulation of methacrylate using polyurea-formaldehyde as a shell material and studied the effect of agitation rate on capsule characteristics such as size, shell thickness, and surface morphology. The formation of microcapsules was confirmed by FTIR and TGA, and capsule characteristics were studied by optical microscopy and SEM. The self-healing effect was evaluated using permeability measurements and further confirmed by surface analytical tools including optical microscope. According to the experimental results, the microencapsulated healing system has the self-heaing ability for artificial cracks.

Effect of Oils on Emulsification for Soft Capsules of Ginseng Extract (인삼(人蔘)엑기스 연질(軟質)캡슐제조시(製造時) 첨가유(添加油)가 유화(乳化)에 미치는 영향(影響))

  • Park, Myung-Han;Sung, Hyun-Soon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.11 no.3
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    • pp.11-14
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    • 1982
  • Effect of the oil mixture on physical properties in soft capsule preparation with ginseng extract contained $36{\pm}1%$moisture content was investigated. The optimum condition was reached when it was emulsified for 5 minutes in $40^{\circ}C$ water bath at 10.000 r.p.m. by mixing with both palm shortening oil and corn oil in equal amount under agitation. Addible amount of ginseng extract was 50% for the total.

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