• Title/Summary/Keyword: after-treatment process

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Production of Nanosized WC Powder by Vapor Phase Reaction

  • Cho, Gi-Chul;Lee, Gil-Geun;Ha, Gook-Hyun;Kim, Byung-Kee
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.625-626
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    • 2006
  • In the present study, the focus is on the synthesis of nanosized WC powder by the chemical vapor condensation proces. The synthesized W-C system powder by the CVC process shows W2C, W, WO3 phases and can not shows WC phase. After recarburization heat treatment under mixture gas atmosphere of argon and hydrogen gases, the synthesized W-C system powder fully transformed to the pure WC. The synthesized WC powder after recarburization heat treatment has an average particle size of 20 nm. The nano-sized WC powder can be prepared by the combination of the CVC process and heat treatment methods.

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Effect of Pre/Post-Treatment on the Performance of Cu(In,Ga)(S,Se)2 Absorber Layer Manufactured in a Two-Step Process (KCN 에칭 및 CdS 후열처리가 Cu(In,Ga)(S,Se)2 광흡수층 성능에 미치는 영향)

  • Kim, A-Hyun;Lee, GyeongA;Jeon, Chan-Wook
    • New & Renewable Energy
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    • v.17 no.4
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    • pp.36-45
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    • 2021
  • To remove the Cu secondary phase remaining on the surface of a CIGSSe absorber layer manufactured by the two-step process, KCN etching was applied before depositing the CdS buffer layer. In addition, it was possible to increase the conversion efficiency by air annealing after forming the CdS buffer layer. In this study, various pre-treatment/post-treatment conditions wereapplied to the S-containing CIGSSe absorber layerbefore and after formation of the CdS buffer layer to experimentally confirm whether similareffects as those of Se-terminated CIGSe were exhibited. Contrary to expectations, it was noted that CdS air annealing had negative effects.

Study on the Effect of Sputtering Process on the Adhesion Strength of CrN Films Synthesized by a Duplex Surface Treatment Process (복합표면처리된 CrN박막의 밀착력에 미치는 스퍼터링 효과에 관한 연구)

  • Kim M.K.;Kim E.Y.;Kim J.T.;Lee S.Y.
    • Journal of the Korean institute of surface engineering
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    • v.39 no.1
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    • pp.1-8
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    • 2006
  • In this study, effect of sputtering after plasma nitriding and before PVD coating on the microstucture, microhardness, surface roughness and the adhesion strength of CrN thin films were investigated. Experimental results showed that this sputtering process not only removed surface compound layer which formed during a plasma nitriding process but also induced an alteration of the surface of plasma nitrided substrate in terms of microhardness distribution and surface roughness, which in turn affected the adhesion strength of PVD coatings. After sputtering, microhardness distribution showed general decrease and the surface roughness became increased slightly. The critical shear stress measured from the scratch test on the CrN coatings showed an approximately twice increase in the binding strength through the sputtering prior to the coating and this could be attributed to a complete removal of compound layer from the plasma nitrided surface and to an increase in the surface roughness after sputtering.

Estimation of Characteristics Treatment for Food Waste using Ultra Thermophilic Aerobic Composting Process (초고온 호기성 퇴비화 공정을 이용한 음식물쓰레기 처리 특성 평가)

  • Park, Seyong;Oh, Dooyoung;Cheong, Cheoljin;Jang, Eunsuk;Song, Hyoungwoon
    • Journal of Korea Society of Waste Management
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    • v.34 no.2
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    • pp.140-147
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    • 2017
  • This study was conducted to evaluate the effects of physical characteristics. Twelve specific odorous compounds and various sources of bacteria were tested via treatment of food waste using an ultra-thermophilic aerobic composting process. Food waste was mixed with seed material and operated for 47 days. During composting, the temperature was maintained at $80-90^{\circ}C$. The variations in $O_2$, $CO_2$ and $NH_3$ production suggested typical microorganism-driven organic decomposition patterns. After composting, the concentrations of 12 specific odorous compounds other than ammonia did not exceed the allowable exhaust limits for odor. After composting, thermophiles represented 50% of all bacteria. After composting, the percentage of thermophile bacterial increased by 15%. Therefore, both stable composting operation and economic benefit can be expected when an ultra-thermophilic composting process is applied to food waste.

The applications of ozone-based advanced oxidation processes for wastewater treatment: A review

  • Hussain, Mujtaba;Mahtab, Mohd Salim;Farooqi, Izharul Haq
    • Advances in environmental research
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    • v.9 no.3
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    • pp.191-214
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    • 2020
  • The rise in population and industrialization accounts for the generation of a huge amount of wastewaters. The treatment of this wastewater is obligatory to safeguard the environment and various life forms. Conventional methods for high strength wastewater treatment coming out to be ineffective. Advanced oxidation processes (AOPs) for such wastewater treatment proved to be very effective particularly for the removal of various refractory compounds present in the wastewater. Ozone based AOPs with its high oxidizing power and excellent disinfectant properties is considered to be an attractive choice for the elimination of a large spectrum of refractory compounds. Furthermore, it enhances the biodegradability of wastewaters after treatment which favors subsequent biological treatments. In this review, a detailed overview of the AOPs (like the Fenton process, photocatalysis, Electrochemical oxidation, wet air oxidation, and Supercritical water oxidation process) has been discussed explicitly focusing on ozone-based AOPs (like O3, O3/H2O2, O3/UV, Ozone/Activated carbon process, Ozone/Ultrasound process, O3/UV/H2O2 process). This review also comprises the involved mechanisms and applications of various ozone-based AOPs for effective municipal/industrial wastewaters and landfill leachate treatment. Process limitations and rough economical analysis were also introduced. The conclusive remarks with future research directions also underlined. It was found that ozonation in combination with other effective AOPs and biological methods enhances treatment efficacies. This review will serve as a reference document for the researchers working in the AOPs field particularly focusing on ozone-based AOPs for wastewater treatment and management systems.

Manufacturing and Properties of CGI-based Composite Coating Layer Utilizing a Warm Spray Process and Cu-Ga and Cu-In Mixed Powders (Warm Spray 공정과 Cu-Ga 및 Cu-In 혼합 분말을 이용한 CGI계 복합 코팅층의 제조 및 특성)

  • Jeon, Min-Gwang;Lee, Myeong-Ju;Kim, Hyeong-Jun;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.21 no.3
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    • pp.229-234
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    • 2014
  • This study manufactured a CIG-based composite coating layer utilizing a new warm spray process, and a mixed powder of Cu-20at.%Ga and Cu-20at.%In. In order to obtain the mixed powder with desired composition, the Cu-20at.%Ga and Cu-20at.%In powders were mixed with a 7:1 ratio. The mixed powder had an average particle size of $35.4{\mu}m$. Through the utilization of a warm spray process, a CIG-based composite coating layer of $180{\mu}m$ thickness could be manufactured on a pure Al matrix. To analyze the microstructure and phase, the warm sprayed coating layer underwent XRD, SEM/EDS and EMPA analyses. In addition, to improve the physical properties of the coating layer, an annealing heat treatment was conducted at temperatures of $200^{\circ}C$, $400^{\circ}C$ and $600^{\circ}C$ for 1 hour each. The microstructure analysis identified ${\alpha}$-Cu, $Cu_4In$ and $Cu_3Ga$ phases in the early mixed powder, while $Cu_4In$ disappeared, and additional $Cu_9In_4$ and $Cu_9Ga_4$ phases were identified in the warm sprayed coating layer. Porosity after annealing heat treatment reduced from 0.75% (warm sprayed coating layer) to 0.6% (after $600^{\circ}C/1hr$. heat treatment), and hardness reduced from 288 Hv to 190 Hv. No significant phase changes were found after annealing heat treatment.

A Study of Production, Hot Consolidation, Secondary Recrystallization and Mechnical Property Assesment of Mechanically Alloyed $NiAl-Fe-AiN-Al_2O_3$ (기계적 합금화에 의한 $NiAl-Fe-AIN-Al_2O_3$ 합금분말의 제조, 열간 성형, 이차재결정화 및 기계적 성질 평가에 관한 연구)

  • 이순철
    • Journal of Powder Materials
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    • v.6 no.1
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    • pp.111-118
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    • 1999
  • Ni(Fe)Al powders containing a homogeneous distribution of the in-situ formed AIN and $Al_2O_3$ dispersoids have been produced by mechanical alloying process in a controlled atmosphere using high energy attrition mill. The powders have been successfully consolidated by hot extrusion process. The phase information investigated by TEM and XRD analysis reveals that Fe can be soluble up to 20% to the NiAl phase ($\beta$) at room temperature after MA process. Subsequent thermomechanical treatment under specific condition has been tried to induce secondary recrystallization (SRx) to improve high temperature properties, however, the clear evidence of SRx was not obtained in this material. Mechanical properties in term of strength at room temperature as well as at high temperatures have been improved by the addition pf AIN, and the room temperature ductility has been shown to be improved after heat treatment, presumably due to the precipitation of second phase of $\alpha$ in this material.

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Evaluation of Physical Shear Pre-treatment and Biogas Characteristics using Mixed Sludge (물리적 파쇄 가용화를 이용한 혼합슬러지의 가용화 효율 및 바이오가스 특성 평가)

  • Choi, Jae-Hoon;Jeong, Seong-Yeob;Kim, Ji-Tae
    • Journal of Korean Society on Water Environment
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    • v.35 no.4
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    • pp.362-369
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    • 2019
  • In this study, biodegradation efficiency improvement of mixed sludge for the anaerobic digestion process in wastewater treatment plant was investigated. In order to release the organic material contained in the sludge cell and promote the hydrolysis step, mixed sludge of 7% TS (Total Solids) was physically shear-treated at a shear strength of 1,000 ~ 4,000 rpm and a maximum of 120 mins. As a result of the comparison between mixed sludge before and after the treatment, the concentration of $SCOD_{Cr}$(Soluble Chemical Oxygen Demand-chromium method) was increased through the conversion of granular organic matter into dissolved organic matter as shear strength and treatment time increases. The solubilization efficiency increased rapidly after 30 min of solubilization application time, and they were 11.23 %, 20.10 %, 22.52 % and 25.43% at 120 min for each shear strength conditions, respectively. Additionally, the BMP(Biochemical Methane Potential) test was conducted with the optimized samples to determine the increase of methane production by the shear pre-treatment. Consequently, methane production of each samples were 0.275, 0.310, 0.323 and $0.335m^3/kg\;VS_{add}$, which indicates that methane production was increased to a maximum of 21.28% compared to the control without the solubilization process ($0.262m^3/kg\;VS_{add}$). As a result, the physical shear-treatment is a promising process for sewage sludge pre-treatment to reduce the organic waste and increase the energy production.

Detection of Equipment Faults at Sequencing Batch Reactor Using Dynamic Time Warping (동적시간와핑을 이용한 연속회분식 반응기의 장비고장 감지)

  • Kim, Yejin
    • Journal of Environmental Science International
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    • v.25 no.4
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    • pp.525-534
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    • 2016
  • The biological wastewater treatment plant, which uses microbial community to remove organic matter and nutrients in wastewater, is known as its nonlinear behavior and uncertainty to operate. Therefore, operation of the biological wastewater treatment process much depends on observation and knowledge of operators. The manual inspection of human operators is essential to manage the process properly, however, it is impossible to detect a fault promptly so that the process can be exposed to improper condition not securing safe effluent quality. Among various process faults, equipment malfunction is critical to maintain normal operational state. To detect equipment faults automatically, the dynamic time warping was tested using on-line oxidation-reduction potential (ORP) and dissolved oxygen (DO) profiles in a sequencing batch reactor (SBR), which is a type of wastewater treatment process. After one cycle profiles of ORP and DO were measured and stored, they were warped to the template profiles which were prepared already and the distance result, accumulated distance (D) values were calculated. If the D values were increased significantly, some kinds of faults could be detected and an alarm could be sent to the operator. By this way, it seems to be possible to make an early detecting of process faults.

Healthcare Process Pattern Analysis with Triage in the Emergency Department (환자의 중증도 분류를 고려한 응급실의 진료 프로세스 패턴 분석)

  • Sim, Seungbae;Choi, Jaehyung;Kim, Bosung;Oh, Jisoo;Kim, Seungho;Park, Yooseok;Park, Incheol;Chung, Taenyoung;Oh, Kyounghwan;Jeong, Bongju;Lee, Young Hoon
    • Journal of the Korean Operations Research and Management Science Society
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    • v.37 no.4
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    • pp.111-124
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    • 2012
  • Emergency room process is very important in the whole hospital processes because it is first diagnosis for patient. Above all, triage is important activity which quickly diagnose the status of emergency patient and sets the priority for treatment. This paper analyzes the treatment process pattern by triage type. The results show that the treatment process after triage such as residence time, diagnosis and checkup type, and joint treatment are dependent on triage types. We can use these analysis results for improving the current triage system and developing the new triage system considering a domestic emergency medical service environment.