• 제목/요약/키워드: advanced composite material

검색결과 510건 처리시간 0.033초

Magnetic and Magnetotransport Properties of (1-x) $La_{0.7}Sr_{0.3}MnO_3-xRE_2O_3$ (RE=La, Nd) Composites

  • Kim, Hyo-Jin;Kang, Young-Min;Yoo, Sang-Im
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2009년도 정기총회 및 동계학술연구발표회
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    • pp.192-192
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    • 2009
  • Magnetic and magnetotransport properties of (1-x) $La_{0.7}Sr_{0.3}MnO_3-xRE_2O_3$ (RE=La, Nd) (x = 0.025, 0.05, 0.075, 0.1, 0.2, 0.3) composite polycrystalline samples were systematically studied. Samples were prepared using conventional solid-state reaction. LSMO and $RE_2O_3$ react at high temperature and become chemically compatible. The ferromagnetic-paramagnetic transition temperatures ($T_c$) of the LSMO-$Nd_2O_3$ composite samples were decreased 313K~349K with increasing x, while the $T_c$ values of the LSMO-$La_2O_3$ composite samples were almost unaltered in the range of 355K~358K, representing that the ferromagnetism of LSMO might be more seriously degraded by Nd substitution on the ($La_{0.7}Sr_{0.3}$) site. However, LSMO-$RE_2O_3$ composite samples exhibit greatly enhanced low field magnetoresistance (LFMR) and dMR/dH value without an appreciable increase in its resistivity. Remarkably improved LFMR properties are attributed to LSMO grain boundaries acting as effective spin-dependent scattering centers. The relationship among the $RE_2O_3$ addition, microstructure, magnetic and magnetotransport properties will be discussed in this paper.

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초고층빌딩 경량화를 위한 복합신소재 슬래브에 관한 연구 (A Study of the Advanced Composite Material Slab for Light Weight of Tall Building)

  • 한봉구
    • Composites Research
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    • 제27권1호
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    • pp.7-13
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    • 2014
  • 대형구조물 설계 건설시 가장 큰 제약은 모든 건설재료에는 치수의 한계가 있다. 본 논문에서는 고전적인 보이론에 의하여 단순 지지된 비등방성 슬래브의 처짐값을 구한 후 그 값을 비교하였고, 특별 직교이방성 판이론에 의하여 콘크리트와 샌드위치 교량의 물성을 비교하여 그 결과에 따른 처짐비와 강성값을 비교하였다. 경계조건은 임의의 경계조건을 갖는 판에 대한 해석해가 없기 때문에 부득이하게 네변이 모두 단순지지 되었을 경우로 해석을 하였고 복합재료의 인장강도는 콘크리트나 강재보다 훨씬 높으므로 비교대상은 처짐으로 하였다. 즉, 철근콘크리트 슬래브보다 자중이 1/10이면서 처짐이 작은 몇 가지 형태의 샌드위치패널을 고려하였다.

Layer-by-Layer 코팅법을 적용한 복합막 제조와 투과성능 평가 (Preparation and Performance of Composite Membrane Prepared by Layer-by-Layer Coating Method)

  • 전이슬;임지원
    • 멤브레인
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    • 제25권6호
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    • pp.538-546
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    • 2015
  • 폴리설폰막 위에 친수성 고분자를 Layer-by-Layer법으로 코팅하여 복합막을 제조하였다. FE-SEM 분석을 통하여 복합막 표면과 기공 내 코팅층을 확인하였다. 또한 100 ppm NaCl 용액에 대한 복합막의 투과성능 평가를 실시하였다. 복합막 제조를 위한 코팅 고분자는 PVSA, PEI, PAA, PSSA, PSSA_MA를 사용하였다. 폴리설폰막 표면에 8,000 ppm PAA (이온세기 0.35) 수용액을 3분 동안 코팅한 뒤 10,000 ppm PEI 수용액을 4분 동안 코팅하였다. 그 결과 PAA-PEI 복합막의 투과도는 101 LMH, 제거율은 66.7%로 가장 좋은 투과성능을 나타내었다. PAA-PEI 복합막의 투과성능은 도레이케미칼의 NE 4040-70 (투과도 = 30 LMH, 염 배제율 = 40~70%) 제품과 유사한 성능을 보여주는 우수한 투과 특성을 나타내었다.

고에너지 전자빔 투사방법으로 제조된 Zr계 비정질 합금 표면복합재료의 탄도충격 성능 (Ballistic Properties of Zr-based Amorphous Alloy Surface Composites Fabricated by High-Energy Electron-Beam Irradiation)

  • 도정현;전창우;남덕현;김충년;송영범;이성학
    • 대한금속재료학회지
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    • 제48권12호
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    • pp.1047-1055
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    • 2010
  • The objective of this study is to investigate the ballistic properties of Zr-based amorphous alloy surface composites fabricated by high-energy electron-beam irradiation. The mixture of Zr-based amorphous powders and $LiF+MgF_2$ flux powders was deposited on a pure Ti substrate, and then an electron beam irradiated this powder mixture to fabricate a one-layer surface composite. A four-layer surface composite, in which the composite layer thickness was larger than 3 mm, was also fabricated by irradiating the deposited powder mixture by an electron beam three times on the one-layer surface composite. The microstructural analysis results indicated that a small amount of fine crystalline particles were homogeneously distributed in the amorphous matrix of the surface composite layer. According to the ballistic impact test results, the surface composite layers effectively blocked a fast traveling projectile, while many cracks were formed at the composite layers, and thus the surface composite plates were not perforated. The surface composite layer containing ductile ${\beta}$ dendritic phases showed a better ballistic performance than the one without dendrites because dendritic phases hindered the propagation of shear bands or cracks.

마찰교반프로세스를 이용한 금속기 복합소재 제조 및 특성 (Manufacturing and Properties of Metal Based Composite Produced By Friction Stir Processing)

  • 최돈현;연윤모;정승부
    • Journal of Welding and Joining
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    • 제30권5호
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    • pp.27-33
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    • 2012
  • Friction stir processing (FSP), developed based on the basic principles of friction stir welding(FSW), a solid-state joining process originally developed for various metal alloys, is an emergingmetalworking technique that can provide localized modification and control of microstructures in near-surface layers of processed metallic components. The FSP causes intense plastic deformation, material mixing, and thermal exposure, resulting in significant microstructural refinement, densification, and homogeneity of the processed zone. The FSP technique has been successfully used for producing the fine-grained structure and surface composite, modifying the microstructure of materials, and synthesizing the composite and intermetallic compound in situ. In this review article, the current state of the understanding and development of FSP is addressed.

Sequential adsorption - photocatalytic oxidation process for wastewater treatment using a composite material TiO2/activated carbon

  • Andriantsiferana, Caroline;Mohamed, Elham Farouk;Delmas, Henri
    • Environmental Engineering Research
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    • 제20권2호
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    • pp.181-189
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    • 2015
  • A composite material was tested to eliminate phenol in aqueous solution combining adsorption on activated carbon and photocatalysis with $TiO_2$ in two different ways. A first implementation involved a sequential process with a loop reactor. The aim was to reuse this material as adsorbent several times with in situ photocatalytic regeneration. This process alternated a step of adsorption in the dark and a step of photocatalytic oxidation under UV irradiation with or without $H_2O_2$. Without $H_2O_2$, the composite material was poorly regenerated due to the accumulation of phenol and intermediates in the solution and on $TiO_2$ particles. In presence of $H_2O_2$, the regeneration of the composite material was clearly enhanced. After five consecutive adsorption runs, the amount of eliminated phenol was twice the maximum adsorption capacity. The phenol degradation could be described by a pseudo first-order kinetic model where constants were much higher with $H_2O_2$ (about tenfold) due to additional ${\bullet}OH$ radicals. The second implementation was in a continuous process as with a fixed bed reactor where adsorption and photocatalysis occurred simultaneously. The results were promising as a steady state was reached indicating stabilized behavior for both adsorption and photocatalysis.

복합적층판 이론에 의한 철근콘크리트 슬래브교의 해석 (Analysis of Reinforced Concrete Slab Bridges by the Composite Laminates Theory)

  • 한봉구;김덕현
    • 복합신소재구조학회 논문집
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    • 제1권1호
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    • pp.9-15
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    • 2010
  • In this paper, A reinforced concrete slab bridges is analyzed by the composite laminates theory. Both the geometry and the material of the cross section of the reinforced concrete slab bridge are considered symmetrical with respect to the mid-surface so that the bending extension coupling stiffness, Bij = 0, and D16 = D26 = 0. Each longitudinal and transverse steel layer is regarded as a lamina, and material constants of each lamina is calculated by the use of rule of mixture. This slab with simple support is under uniformly distributed vertical and axial loads. In this paper, the finite difference method and specially orthotropic laminates theory are used for analysis. The result of specially orthotropic laminates theory analysis is modified to obtain the solution of the beam analysis. The result of this paper can be used for reinforced concrete slab analysis by the engineers with undergraduate study in near future.

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회전하는 복합재-VEM 박판보의 GHM 기법을 이용한 진동해석 (The Vibration Analysis of Composite-VEM Thin-Walled Rotating Beam Using GHM Methodology)

  • 박재용;나성수
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2004년도 춘계학술대회논문집
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    • pp.337-341
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    • 2004
  • This paper concerns the analytical modeling and dynamic analysis of advanced rotating blade structure implemented by a dual approach based on structural tailoring and viscoelastic materials technology. Whereas structural tailoring uses the directionality properties of advanced composite materials, the passive materials technology exploits the damping capabilities of viscoelastic material(VEM) embedded into the host structure. The structure is modeled as a composite thin-walled beam incorporating a number of nonclassical features such as transverse shear, warping restraint, anisotropy of constituent materials, and warping and rotary inertias. The VEM layer damping treatment is modeled by using the Golla-Mushes-McTavish(GHM) method, which is employed to account for the frequency-dependent characteristic o the VEM. The displayed numerical results provide a comprehensive picture of the synergistic implications of the application of both techniques, namely, the tailoring and damping technology on vibration response of thin-walled beam structure exposed to external time-dependent excitations.

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고인성 열가소성 복합재료 AS4/PEEK의 피로강도에 관한 기초적 검토 (A Preliminary Study on Fatigue Strength of High Toughness Thermoplastic Composite Material AS4/PEEK)

  • 송지호;강재윤
    • 대한기계학회논문집A
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    • 제24권4호
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    • pp.1055-1064
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    • 2000
  • First, various specimen geometries, namely, coupon type, waisted type and dog-bone type, were examined to determine appropriate fatigue specimen of thermoplastic composite material AS4/PEEK and the n, fatigue strength of smooth and notched specimens of AS4/PEEK [-45/0/+45/90]2s was investigated. Fatigue tests were performed under load controlled condition at a stress ratio of 0. 1 at a frequency of 5Hz. Stiffness degradation of specimens with fatigue cycling was monitored using an automated unloading compliance technique. The waisted type specimen is found appropriate for smooth fatigue specimen geometry of AS4/PEEK. As for the effect of stress concentration, it is found that fatigue strength is higher for a 2mm-diameter hole notched specimen than a 5mm-diameter one. Fatigue notch factor decreases with the increase of fatigue life. These results are far different from the trend of fatigue strength of metallic materials. The stiffness variation of smooth specimen was only 4% at maximum until final fracture. On the other hand, the stiffness of hole notched specimen was reduced by 45% at maximum. Notched fatigue strength was compared between thermoplastic composite AS4/PEEK and thermosetting composite Graphite/Epoxy. In long-life fatigue (>104), the AS4/PEEK composite shows superior fatigue strength, but in short-life fatigue, the fatigue strength of the Graphite/Epoxy composite is nearly equal or somewhat higher than that of the AS4/PEEK composite.

실란유기화제를 이용한 에폭시/클레이 나노복합재료의 기계적 계면 물성 향상 (Improvement of Mechanical Interfacial Properties of Epoxy/Clay Nanocomposites Using Silane Intercalant)

  • Park, Soo-Jin;Seo, Dong-Il;Lee, Jae-Rock
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 추계학술발표대회 논문집
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    • pp.125-128
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    • 2001
  • In this wort, the $Na^+-MMT$ has organically modified with silane intercalant to prepare the polymer/clay nanocomposites. The pH. X-ray diffraction (XRD), and contact angles were used to analyze the surface properties of clay and the exfoliation phenomenon of clay interlayer, The mechanical interfacial properties of epoxy/clay nanocomposites were investigated by three-point bending test. From the experimental results. the surface modification made by silane intercalant on clay surface leads to an increase of distance of silicate layers, surface acid value. and electron acceptor parameter of organoclay. The treatments are also necessary and useful for epoxy to intercalate into the interlayer by interacting of electron donor-accepter between basic epoxy and clay surface. The mechanical interfacial properties of the nanocomposites was improved by the presence of dispersed clay nanolayer containing low content of organoclay in comparison with the conventional, which increase the interfacial adhesion between dispersed clay and epoxy resins.

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