• 제목/요약/키워드: adsorption test

검색결과 526건 처리시간 0.026초

칼루마이트 및 VA/E/MMA 분말수지 병용 PMM의 자기방청기능 규명을 위한 기초적 연구 (A Basic Study on the Self-Corrosion Inhibition Function Identification of VA/E/MMA-Modified Mortar with Nitrite-Type Hydrocalumite)

  • 홍선희;김완기
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2011년도 추계 학술논문 발표대회
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    • pp.253-254
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    • 2011
  • The purpose of this study is to investigate chloride ion adsoption property of cement mortar using nitrite type hydrocalumite(calumite) with self-corrosion inhibition function. Superior corrosion inhibition function of the VA/E/MMA-modified mortars with calumite was ascertained from accelerated corrosion test in the previous study. In this study, VA/E/MMA-modified mortars with calumite were prepared with calumite contents of 0, 5, 10% and polymer-binder ratio of 0, 10%, and tested for chloride ion adsorption to make it clear how calumite gives self-corrosion inhibition function to cement mortar. As a result, chloride ion adsorption property of VA/E/MMA-modified mortars with calumite was improved by increasing calumite contents compared to unmodified mortar regardless of using VA/E/MMA terpolymer powder or not.

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기존 정수처리방법으로 제거가 어려운 유기물에 대한 실험적 연구 (Retrospect on Refractories in Water Treatment)

  • 우달식;남상호
    • 한국환경보건학회지
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    • 제21권4호
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    • pp.17-23
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    • 1995
  • As a basic experiment to develope biological pretreatment proces~ in water treatment, the experiments on biodegradability and isothermal adsorption of activated carbon were performed on refractories such as humic acid, $NH_3-N$, phenol and ABS which caused the problems in drinking water treatment. Also, the treatabilities on humic acid were examined in the continuous flow type reactors. The removal efficiencies of humic acid, $NH_3-N$, phenol and ABS in the biodegradable experiments for 5 days were 20.1%, 73.4%, 91.7% and 97.5%, respectively. In the isothermal adsorption test of refractories on activated carbon to be used as a media in the continuous flow type reactors, ABS and phenol are adsorbed easily, but humic acid and $NH_3-N$ are difficult to be done. The removal efficiencies of humic acid in granular activated carbon(GAC) reactor were about 7-8% higher than in biological activated carbon(BAC) reactor. The removal efficiencies of humic acid in biological fluidized bed(BFB) reactor were about 30% in GAC media, but were almost zero in sea sand media.

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라돈 흡착형 경화체의 시험 조건에 따른 흡착특성 (Properties Adsorption According to Test Condition of Radon Adsorption-type Matrix)

  • 임현웅;김헌태;권오한;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2016년도 추계 학술논문 발표대회
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    • pp.109-110
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    • 2016
  • This study is a absorbing Radon gas to occur indoor or outdoor. As a absorbent Radon gas, making cementless abso rbent matrix that accomplish experiment. In other to accomplish this experiment, Confirming Radon gas release ratio and accurating absorption, reduction of a half-life that 3,8 days from Radon gas source, we need to decide Radon absorbent experiment method. So, we accomplish to find Radon measurement method considering properties and a half-life that 3,8 days from Radon gas source. As the experimental factors, After stabilizing of Radon gas source and so on, we accomplish the experiment that is there or not and seal of Radon source.

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고분자 표면의 혈관내피세포 부착력에 관한 연구 (Evaluation of Endothelial Cell Attachment on Polymer Surface)

  • 최진욱;유규하;민병구
    • 대한의용생체공학회:의공학회지
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    • 제11권1호
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    • pp.131-140
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    • 1990
  • To improve antithrombogenicity of polymer that used in vascular graft and artificial organs, seeding of human endothelial cells on the polyurethane was studied. Human endothelial cells were ismlated from human umbilical veins, using type I collagenase, and identified with goat anti vWF antibodies. Human endothilial cell seeding was tried upon the polyurethane which has good mechanical property and resists stresses. The hydrophobic polyurethane surface was changed hydrophilic by corona discharf:e treatment. Surface hydrophilicity was measured with Wilhemly plate method and the goniometer. To evaluate matrix protein adsorption, fibronectin adsorption test was done. To eveluate cell adhesion, human endothelial cell attachment forces were measured rising a perfusion chamber of , ism diamter. Less cells were detached from the hydrophilically treated polyurethane. This showed that corona discharge on the polyurethane could improve matrix adsorption and endothelial cell attachment.

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평판형 유전체 장벽 방전 반응기에서 충진물질에 따른 아세토나이트릴의 분해 특성 (Decomposition of Acetonitrile Using a Planar Type Dielectric Barrier Discharge Reactor Packed with Adsorption and Catalyst Materials)

  • 김관태;송영훈;김석준
    • 한국대기환경학회지
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    • 제19권2호
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    • pp.157-165
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    • 2003
  • A combined process of non-thermal plasma and catalytic technique has been investigated to treat $CH_3$CN gas in the atmosphere. A planar type dielectric barrier discharge (DBD) reactor has been used to generate the non-thermal plasma that produces various chemically active species, such as O, N, OH, $O_3$, ion, electrons, etc. Several different types of the beads. which are Molecular Sieve (MS) 5A, MS 13X, Pt/alumina beads, are packed into the DBD reactor, and have been tested to characterize the effects of adsorption and catalytic process on treating the $CH_3$CN gas in the DBD reactor. The test results showed that the operating power consumption and the amounts of the by-products of the non-thermal plasma process can be reduced by the assistance of the adsorption and catalytic process.

천연 점토를 이용한 Pb(II)의 흡착에 관한연구

  • 김강우;이한섭
    • 한국환경보건학회지
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    • 제27권2호
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    • pp.138-144
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    • 2001
  • This study was carried out to investigate characteristics and Pb(II) removal effect of natural clays in the batch mode test. The effect of parameters such as temperature, adsorption time and coexisting cations on the sorption ability and characteristics was investigated to find out whether the clays could be used as adsorbents. Several natural clays from domestic have been investigated to have high specific surface area and have minerals such as SiO$_2$ and $Al_2$O$_3$. As a result, removal effects of Pb(II) on clays were reached at equilibrium in aqueous solutions by stirring about 20 minutes. The removal effect of Pb(II) was best for Kang Jin clay than other clays in terms of fixed time. Adsorption efficiency was not influenced by the possibility of continuous treatment system of wastewater which contain heavy metals by using natural clays from domestic.

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질소흡착법을 사용한 고온 가열 시멘트의 세공구조 측정 (Measurement of the construction structure of hot-heated cement using nitrogen adsorption method)

  • 김민혁;이건철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 봄 학술논문 발표대회
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    • pp.140-141
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    • 2020
  • Concrete has a lower thermal conductivity or thermal diffusion coefficient compared to other building materials, so it is widely used as fireproof compartment material or refractory material for structures. However, in the event of thermal damage such as fire, cement curing agents and aggregates act differently, resulting in heat generation or deterioration of tissue due to dehydration, resulting in deterioration of physical properties and fire resistance. Therefore, in this study, the processing structure of cement paste is measured through nitrogen absorption method. The test specimen is a cement paste of 40% W/C and is set at 1000 ℃ under heating temperature conditions. As the temperature rose, the micro-pore mass below was reduced based on about 0.01 감소m, but the air gap above that was increased.Thus, in the range of pores measured in nitrogen adsorption, the air mass tended to decrease under high temperature conditions.

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미분층반응기에서 양이온 교환수지에 의한 카드뮴(II)의 제거 (Removal of Cd(II) by Cation Exchange Resin in Differential Bed Reactor)

  • 김종태;정재관
    • 대한환경공학회지
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    • 제22권7호
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    • pp.1193-1203
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    • 2000
  • 본 연구는 흡착에 의한 Cd(II)의 제거를 위하여 일본 Diaion사에서 제조되고 있는 강산성양이온 교환수지(SK1B)를 흡착제로 사용하여 흡착평형실험, 탈착실험 및 흡착속도실험을 수행하였다. 흡착평형실험에서는 흡착능에 미치는 pH와 온도의 영향을 알아보았고 흡착등온식을 산출하였으며, 탈착실험에서는 재생회수에 대한 수지의 재생율의 변화에 대해서 알아보았다. 흡착속도실험에서는 수지를 미분층 반응기에 채워 유량별로 초기제거속도를 구하여 경막저항이 최소가 되는 최적유량을 구하였으며, 이 최적유량에서 흡착속도실험을 수행하여 총괄흡착속도식을 구하였다. 용액의 pH를 변화(2~7)시켜 제조하여 수지를 투여한 결과 pH가 증가할수록 흡착능이 증가하였으며 pH 6 이상에서는 흡착능이 일정한 경향을 나타내었다. 흡착능에 미치는 온도의 영향은 $10{\sim}50^{\circ}C$ 범위에서 온도가 증가할수록 흡착능도 증가함을 알 수 있었다. 회분식실험을 통해 얻은 자료를 각 흡착등온식에 적용해 본 결과 본 실험의 농도 영역(5~15ppm)에서는 Freundlich 흡착등온식과 Sips 흡착등온식이 Langmuir 흡착등온식보다 더 %편차가 적었다. 탈착제로서 0.01~2N 농도의 HCl 수용액을 사용할 경우에는 탈착제의 농도가 진할수록 흡착제의 재생율이 높았으며 재생 반복회수가 늘어날수록 재생율이 약간씩 감소하였다. 미분층 반응기를 이용한 연속공정실험($25{\pm}5^{\circ}C$)에서 경막확산저항이 최소가 되는 최적유량 $564m{\ell}/min$에서 수행한 수지에 대한 Cd(II) 수용액의 총괄흡착속도식은 다음과 같이 표현될 수 있다. $r=1.3785C_{fc}^{1.2421}-2.0907{\times}10^{0.0746C_i}\;q_e^{0.0121C_i-0.0301}$

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Ferrocyanide-음이온 교환수지에 의한 모의 토양제염 폐액 처리 (Treatment of Simulated Soil Decontamination Waste Solution by Ferrocyanide-Anion Exchange Resin Beads)

  • 원휘준;김민길;김계남;정종헌;박진호;오원진
    • 방사성폐기물학회지
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    • 제3권1호
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    • pp.41-47
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    • 2005
  • Cs$^{+}$ 이온에 대해 선택성을 갖는 ferrocyanide-음이온 교환수지를 제조하여 모의 제 염폐액 내에 존재하는 Cs$^{+}$ 이온에 대한 흡착실험을 수행하였다. 제조된 이온교환 수지가 citric acid를 주제염제로 하는 제염폐액 내에 존재하는 Cs+ 이온에 대한 흡착능력은 상용 양이온교환수지에 비해 4배 이상 효과적인 것으로 나타났다. 모의 제염폐액과 선택성 이온교환수지를 접촉시킨 후 360분이 경과하면 금속이온에 대한 흡착반웅이 평형에 도달하였다. 본 연구범위에서 Co$^{2+}$ 이온농도가 필요이상 증가하게 되면 Cs$^{+}$ 이온의 흡착율은 감소하였다. 과산화수소와 히드라진을 사용한 선택성 폐 이온교환수지의 재생실험 결과 전기중성화조건을 만족시키기 위해 Cs$^{+}$ 이온이 수지로부터 용출됨을 확인하였고 열화없이 재 사용가능성을 확인하였다.

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고도정수처리용 Filter/Adsorber Granular Activated Carbon 특성 평가: 마모지수, floater, water-soluble ash 및 흡착특성 평가 (Evaluation on Filter/Adsorber Granular Activated Carbon using in Advanced Drinking Water Treatment: Abrasion number, Floater, Water-soluble ash, and Adsorption characteristics)

  • 박병주;도시현;김태양;홍성호
    • 상하수도학회지
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    • 제30권1호
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    • pp.77-85
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    • 2016
  • The characteristics of filter/adsorber granular activated carbon (F/A GAC) were investigated by measuring various parameters, which include surface area, pore volume, abrasion number, floater, and water-soluble ash. The correlation between parameters was also evaluated. Moreover, rapid small-scale column test (RSSCT) was conducted for adsorption characteristics. Thirteen F/A GAC were tested, and the average values of abrasion number and water-soluble ash were 88.9 and 0.15%, respectively. F/A GAC with the larger external surface area and greater mesopore volume had the lower abrasion number, which indicated that it was worn out relatively easily. Water-soluble ash of coconut-based GAC (about 2.6%) was greater than that of coal-based GAC (less than 1%), and the pH of solution was increased with GAC, which had the higher water-soluble ash. On the other hand, floater of thirteen F/A GAC was divided as two groups, which one group had relatively higher floater (2.7~3.5%) and the other group had lower floater (approximately 0.5%). The results of RSSCT indicated that coconut-based GAC (i.e. relatively higher water-soluble ash) had less adsorption capacity. Moreover, adsorption capacity of coal-based GAC with larger surface area and greater mesopore volume was superior to others.