• KSBB Journal
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• v.16 no.2
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• pp.128-132
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• 2001

Cyclodextrin glucanotransferase (EC 2.4.1.19 : 1,4-$alpha$-glucan 4-$alpha$-D-(1,4-glucano) transferase, cyclizing; CGTase) was recovered by starch adsorption. The adsorption and desorption of CGTase to starch was studied as a function of pH, temperature, and starch type. The optimal pH, temperature, and starch for adsorption were, 8.0, $4^{circ}C$, and 1% (w/v) corn starch, respectively, per 205 U/mL enzyme activity in the presence of 25% (w/v) ammonium sulfate. The maximum adsorption ratio was 95%. On the other hand, the optimal pH, temperature, and starch type for desorption were 8.0 (tris-buffer), $50^{circ}C$, and oxidized starch, respectively. The maximum desorption ratio was 98% by tris-buffer solution at pH 8.0. The efficiency of adsorption and desorption were affected slightly by the removal of cells from the fermentation broth.

• Polymer(Korea)
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• v.26 no.5
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• pp.551-558
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• 2002

It was observed that adsorption characteristics of sulfonated fabric ion-exchanger for separating nickel ion from electroplating rinse water. Swelling ratio was increased by increasing degree of sulfonation and polarity of solvent. Ion-exchange capacity was also increased by increasing degree of sulfonation and showed 3.38 meq/g at 16% sulfonated ion-exchanger. There was little effects of pH. Adsorption equilibrium was attained within 10 min, and adsorption rate was 7.5 mg/min. Adsorption capacity was not changed after 7 cycles of regeneration process. Regeneration adsorption capacity was slightly decreased to 2.01 meq/g. It confirmed that durability of sulfonated fabric ion-exchanger was suitable for adsorption process. Adsorption equilibrium time was linearly increased by increasing L/D and adsorption capacity showed the ion exchange capacity within the range of 2.71 ∼ 3.01 meq/g in continuous process. Design of adsorption column could be possible for L/D<2. Under constant L/D condition, there is no little pH effect when rinse water is acidic solution, and operation condition of adsorption process was optimized under pH 5.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3570-3576
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• 2013

Poly(methacrylic acid)-functionalized SBA-15 silicas (denoted as P-x-PMA/SBA-15 where x is molar ratio of TSPM/(TEOS+TSPM) in percentage in the initial mixture) were synthesized by co-condensation of tetraethoxysilane and varying contents of 3-(trimethoxysilyl)propyl methacrylate in acidic medium with the block copolymer Pluronic 123 as a structure directing agent and then polymerization by methacrylic acid in the presence of ammonium persulfate as an initiator. The functionalized materials were characterized by PXRD, TEM, SEM, IR, and $N_2$ adsorption-desorption at 77 K. The investigation of phenol adsorption in aqueous solution on the materials showed that the poly(methacrylic acid)-functionalized mesoporous silicas possess strong adsorption ability for phenol with interaction of various kinds of hydrogen bonds. The adsorption data were fitted to Langmuir isotherms and the maximum adsorption capacity of the three functionalized materials P-5-PMA/SBA-15, P-10-PMA/SBA-15, and P-15-PMA/SBA-15 to be 129.37 mg/g, 187.97 mg/g, and 78.43 mg/g, respectively, were obtained. The effect of the pH on phenol adsorption was studied.

• Journal of Korea Soil Environment Society
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• v.1 no.2
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• pp.43-50
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• 1996

The adsorption charateristics of lead(II) ions on Aspergillus niger and Rhizopus arrhizus were investigated. Adsorption amount of A. niger and R. arrhizus was about 95 mg/g and 25 mg/g, respectively. These biomass was approached to adsorption equilibrium within reaction time of 1hr because of their high reactivity. The uptake of lead ion by A. niger was less sensitivity than it by R. arrhizus on the inhibition effect of alkali metals and the decreasing ratio of uptake of lead ion of A. niger and R. arrhizus by inhibition effect of alkali metals was 37% and 50%, respectively. In pre-treatment on these biomass, NaOH treatment was contributed high adsorption capacity to these biomass. Then, adsorption amount of A. niger and R. allhizus was increased about 25 mg/g and 10 mg/g, respectively. In isotherm for the adsorption of lead ion based on Freundlich equation, 1/n value of A. niger and R. ar고izus was calculated the range of 0.28-0.56 and 0.44-0.67, respectively.

• Journal of the Korea Concrete Institute
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• v.16 no.2 s.80
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• pp.147-154
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• 2004

It is the aim of this study to propose the fundamental data for the establishment of the application and qualify standard of the mixed type superplasticizer after investigating and comparing the fluidity of high flowing concrete according to the component ratio of superplasticizer such as naphthalene sulfonated and melamine sulfonated. The results of this study were shown as the followings; 1) The fluidity and adsorption ratio of cement-paste were improved according to the increasing of naphthalene sulfonated component ratio, and apparent viscosity of cement-paste was improved according to the Increasing of melamine sulfonated component ratio. 2) In case of using the granulated blast-furnace slag, the fluidity of cement-paste was considerably good and the adsorption ratio was decreased and in case of using fly-ash, the apparent viscosity and adsorption ratio of cement-paste were improved. 3) The dispersive capacity performance of concrete can be improved by means of the increasing of naphthalene sulfonated component ratio. Also the viscosity and early strength can be improved by means of the increasing of melamine sulfonated component ratio.

• Journal of the Korea Concrete Institute
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• v.29 no.1
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• pp.65-75
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• 2017

C-S-H phase is the most abundant reaction product, occupying about 50~60% of cement paste volume. The phase is also responsible for most of engineering properties of cement paste. This is not because it is intrinsically strong or stable, but because it forms a continuous layer that binds together the original cement particles into a cohesive whole. The binding ability of C-S-H phase arises from its nanometer-level structure. In terms of chloride penetration in concrete, C-S-H phase is known to adsorb chloride ions, however, its mechanism is very complicated and still not clear. The purpose of this study is to examine the interaction between chloride ions and C-S-H phase with various Ca/Si ratios and identify the adsorption mechanism. C-S-H phase can absorb chloride ions with 3 steps. In the C-S-H phase with low Ca/Si ratios, momentary physical adsorption could not be expected. Physical adsorption is strongly dependent on electro-kinetic interaction between surface area of C-S-H phase and chloride ions. For C-S-H phase with high Ca/Si ratio, electrical kinetic interaction was strongly activated and the amount of surface complexation increased. However, chemical adsorption could not be activated for C-S-H phase with high Ca/Si ratio. The reason can be explained in such a speculation that chloride ions cannot be penetrated and adsorbed chemically. Thus, the maximum chloride adsorption capacity was obtained from the C-S-H phase with a 1.50 Ca/Si ratio.

• Journal of the Korean Chemical Society
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• v.14 no.4
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• pp.347-355
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• 1970

The state of carrier-free yttrium-90 has been studied by filtration method with membrane filters. The studies include the adsorption ratio of carrier-free yttrium-90 on membrane filters by the change of PH, concentration of yttrium-90, and the pore size of member filters. The adsorption followed to Freundlich adsorption isotherm. The adsorption mechanism was proposed by the adsorption of transient state as an ionic form of $Y^{3+}$, and the experimental results were explained satisfactorily by the proposal. The adsorbed state of yttrium was present in the forms of yttrium such as $Y^{3+},\;Y(OH)^{3+},\;Y(OH)^{2+},\;Y(OH)^+_3,\;and\;Y(OH)_3$,and the existing ratios of the forms of yttrium were sharply changed by PH. It seems to be valid tha the carrier-free yttrium-90 exists mostly in $Y^{3+}$ state.

• Journal of Environmental Science International
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• v.11 no.3
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• pp.257-262
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• 2002

The hydroxyapatite(HAp) for the present study was prepared with the wastewater sludge from semiconductor fabrication process and it was crystallized in an electric furnace for 30 min at 90$0^{\circ}C$. The adsorption characteristics of HAp for phosphate ion in aqueous solution has been investigated. The adsorbed ratio of phosphate ion for HAp were investigated according to the reaction time, amount of HAp, concentration of standard solution, pH of solution, and influence of concomitant ions. The amount of adsorbed phosphate ion decreased with the increase of pH due to the mutual electrostatic repulsion between adsorbed phosphate ions and competitive adsorption between phosphate ion and OH- ion in aqueous solution. The maxium amount of the adsorption equilibrium for phosphate ion was about 24 mg/g of HAp. The HAp would likely to be a possible adsorbent for the removal of phosphate ion in the waste water.

• Environmental Engineering Research
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• v.10 no.2
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• pp.45-53
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• 2005

Metal oxide particles with mole ratio of aluminum: titanium of 1:1 were synthesized by a sol-gel method. Langmuir (a) and Freundlich (b) adsorption isotherms of dissolved lead [Pb(Ⅱ)] ion on the metal oxide particles containing aluminum and titanium were determined as follows, respectively,(a) , (b) at pH 6where, correlation coefficients (R2) of Langmuir and Freundlich adsorption isotherms were 0.95 and 0.96, respectively.The overall adsorption rate of Pb(Ⅱ) on the metal oxide particles containing aluminum and titanium was determined by a differential bed reactor. The overall adsorption rate at pH 6 was as a following equation.at pH 6

• Environmental Engineering Research
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• v.24 no.1
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• pp.99-106
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• 2019

Using the abandoned agricultural by-product corncobs, the most commonly used methylene blue (MB) dyestuffs were removed. This experiment is very meaningful because it is the recycling of resources and the use of environmentally friendly adsorbents. According to the Hauser ratio and porosity analysis, the corncob has a good flow ability of the adsorbent material and many pores, which is very advantageous for MB adsorption. As a result of the experiment, MB concentration of less than 0.005 g/L was very efficiently removed with 10 g/L of bioadsorbent corncob and the maximum adsorption capacity of corncob for MB dyes was obtained at 417.1 mg/g. In addition, adsorption process of MB onto corncob was a physical process according to adsorption energy analysis. Corncob can efficiently and environmentally remove MB in aqueous solution, and is very cost effective and can recycle the abandoned resources.