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http://dx.doi.org/10.5012/bkcs.2013.34.12.3570

Synthesis of Poly(methacrylic acid)-functionalized SBA-15 and its Adsorption of Phenol in Aqueous Media  

Vo, Vien (Department of Chemistry and Nano Science, Ewha Womans University)
Kim, Hee-Jin (Department of Chemistry and Nano Science, Ewha Womans University)
Kim, Ha-Yeong (Department of Chemistry and Nano Science, Ewha Womans University)
Kim, Youngmee (Department of Chemistry and Nano Science, Ewha Womans University)
Kim, Sung Jin (Department of Chemistry and Nano Science, Ewha Womans University)
Publication Information
Abstract
Poly(methacrylic acid)-functionalized SBA-15 silicas (denoted as P-x-PMA/SBA-15 where x is molar ratio of TSPM/(TEOS+TSPM) in percentage in the initial mixture) were synthesized by co-condensation of tetraethoxysilane and varying contents of 3-(trimethoxysilyl)propyl methacrylate in acidic medium with the block copolymer Pluronic 123 as a structure directing agent and then polymerization by methacrylic acid in the presence of ammonium persulfate as an initiator. The functionalized materials were characterized by PXRD, TEM, SEM, IR, and $N_2$ adsorption-desorption at 77 K. The investigation of phenol adsorption in aqueous solution on the materials showed that the poly(methacrylic acid)-functionalized mesoporous silicas possess strong adsorption ability for phenol with interaction of various kinds of hydrogen bonds. The adsorption data were fitted to Langmuir isotherms and the maximum adsorption capacity of the three functionalized materials P-5-PMA/SBA-15, P-10-PMA/SBA-15, and P-15-PMA/SBA-15 to be 129.37 mg/g, 187.97 mg/g, and 78.43 mg/g, respectively, were obtained. The effect of the pH on phenol adsorption was studied.
Keywords
Mesoporous materials; Functionalization; Methacrylate; Phenol adsorption;
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1 Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. D.; Chu, C. T. W.; Olson, D. H.; Sheppard, E. W.; McCullen, S. B.; Higgins, J. B.; Schlenker, J. L. J. Am. Chem. Soc. 1992, 114, 10834.   DOI   ScienceOn
2 Kresge, C. T.; Leonowicz, M.; Roth, W. J.; Vartuli, J. C.; Beck, J. C. Nature 1992, 359, 710.   DOI
3 Kresge, C. T.; Leonowicz, M.; Roth, W. J.; Vartuli, J. C.; Beck, J. C. Nature 1992, 359, 710.   DOI
4 Lasseter, T. L.; Clare, B. H.; Abbott, N. L.; Hamers, R. J. J. Am. Chem. Soc. 2004, 126, 10220.   DOI   ScienceOn
5 Kim, E.; Kim, H. E.; Lee, S. J.; Lee, S. S.; Seo, M. L.; Jung, J. H. Chem. Commun. 2008, 33, 3921.
6 Dai, Z. H.; Bao, J. C.; Yang, X. D.; Ju, H. X. Biosens. Bioelectron. 2008, 23, 1070.   DOI   ScienceOn
7 Giri, S.; Trewyn, B. G.; Stellmaker, M. P.; Lin, V. S. Y. Angew. Chem. Int. Ed. 2005, 44, 5038.   DOI   ScienceOn
8 Yan, B.; Zhou, L.; Li, Y. Colloids and Surfaces A: Physicochem. Eng. Aspects 2009, 350, 147.   DOI   ScienceOn
9 Yan, B.; Zhou, L.; Li, Y. Colloids and Surfaces A: Physicochem. Eng. Aspects 2009, 350, 147.   DOI   ScienceOn
10 Agirrezabal-Telleria, I.; Requies, J.; Guemez, M. B.; Arias, P. L. Appl. Catal. B: Environ. 2012, 169, 115.
11 Zhu, J.; Xie, X.; Carabineiro, S. A. C.; Tavares, P. B.; Figueiredo, J. L.; Schomacker, R.; Thomas, A. Energy Environ. Sci. 2011, 4, 2020.   DOI   ScienceOn
12 Zhao, D.; Huo, Q.; Feng, J.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc. 1998, 120, 6024.   DOI   ScienceOn
13 Dai, S.; Burleigh, M. C.; Ju, Y. H.; Gao, H. J.; Lin, J. S.; Pennycook, S. J.; Barnes, C. E.; Xue, Z. L. J. Am. Chem. Soc. 2000, 122, 992.   DOI   ScienceOn
14 Brown, J.; Mercier, L.; Pinnavaia, T. J. Chem. Commun. 1999, 69.
15 Jaroniec, C. P.; Sayari, A.; Kruk, M.; Jaroniec, M. J. Phys. Chem. B 1998, 102, 5503.   DOI   ScienceOn
16 Antochshuk, V.; Jaroniec, M. J. Phys. Chem. B 1998, 103, 6252.
17 Anbia, M.; Amirmahmoodi, S. Scientia Iranica C 2011, 18, 446.   DOI   ScienceOn
18 Baccile, N.; Babonneau, F. Micropor. Mesopor. Mater. 2008, 110,534.   DOI   ScienceOn
19 Inumaru, K.; Nakano, T.; Yamanaka, S. Micropor. Mesopor. Mater. 2006, 95, 279.   DOI   ScienceOn
20 Huang, J.; Wang, X.; Jin, Q.; Liu, Y.; Wang, Y. J. Environ. Manage. 2007, 84, 229.   DOI   ScienceOn
21 Buscaa, G.; Berardinelli, S.; Resini, C.; Arrighi, L. J. Hazard. Mater. 2008, 160, 265.   DOI   ScienceOn
22 Ahalya, N.; Ramachandra, T. V.; Kanamadi, R. D. Res. J. Chem. Environ. 2003, 7, 71.
23 Ku, Y.; Lee, K C. J. Hazard. Mater. 2000, 80, 59.   DOI   ScienceOn
24 Mukherjee, S.; Kumar, S.; Misra, A. K.; Fan, M. Chem. Eng. J. 2007, 129, 133.   DOI   ScienceOn
25 Tor, A.; Cengeloglu, Y.; Aydin, M. E.; Ersoz, M. J. Colloid Interface Sci. 2006, 300, 498.   DOI   ScienceOn
26 Rengaraj, S.; Moon, S.; Sivabalan, R.; Arabindoo, B.; Murugesan, V. J. Hazard. Mater. 2002, 89, 185.   DOI   ScienceOn
27 Senturka, H. B.; Ozdesa, D.; Gundogdua, A.; Durana, C.; Soylakb, M. J. Hazard. Mater. 2009, 172, 353.   DOI   ScienceOn
28 Tang, E.; Cheng, G. X.; Ma, X. L.; Pang, X. S.; Zhao, Q. Appl. Surf. Sci. 2006, 252, 5227.   DOI   ScienceOn
29 Azhgozhinova, G. S.; Güven, O.; Pekel, N.; Dubolazov, A. V.; Mun, G. A.; Nurkeeva, Z. S. J. Colloid Interface Sci. 2004, 278,155.   DOI   ScienceOn
30 Anirudhan, T. S.; Rijith, S. J. Environ. Radioactivity 2012, 106, 8.   DOI   ScienceOn
31 Huang, L.; Yuan, S.; Lv, Li; Tan, G.; Liang, B.; Pehkonen, S. O. Journal of Colloid and Interface Science 2013, 405, 171.   DOI   ScienceOn
32 Anirudhan, T. S.; Rijith, S.; Tharun, A. R. Colloids and Surfaces A: Physicochem. Eng. Aspects 2010, 368, 13.   DOI   ScienceOn
33 Wang, W. Process Safety and Environmental Protection 2011, 89,127.   DOI   ScienceOn
34 Anirudhan, T. S.; Rejeena, S. R. Carbohydrate Polymers 2013,93, 518.   DOI   ScienceOn
35 An, F.; Gao, B.; Feng, X. Chem. Eng. J. 2009, 153, 108.   DOI   ScienceOn
36 An, F.; Feng, X.; Gao, B. J. Hazard. Mater. 2010, 178, 499.   DOI   ScienceOn
37 Phuong, T. T. T.; Hang, T. D.; Hung, N. P.; Nga, N. T. V.; Kim, S. J.; Vo, V. J Porous Mater. 2012, 19, 295.   DOI
38 Wang, X.; Lin, K. S. K.; Chan, J. C. C.; Cheng, S. J. Phys. Chem. B 2005, 109, 1763.   DOI   ScienceOn
39 Mercier, L.; Pinnavaia, T. J. Chem. Mater. 2000, 12, 188.   DOI   ScienceOn
40 Chong, A. S. M.; Zhao, X. S. J. Phys. Chem. B 2003, 107, 12650.   DOI   ScienceOn
41 Zhang, M.; Shi, L.; Yuan, S.; Zhao, Y.; Fang, J. J. Colloid Interface Sci. 2009, 330, 113.   DOI   ScienceOn
42 He, J.; Xu, Y.; Ma, H.; Evans, D. G.; Wang, Z.; Duan, X. Micropor. Mesopor. Mater. 2006, 94, 29.   DOI   ScienceOn
43 Moller, K.; Bein, T.; Fischer, R. X. Chem. Mater. 1999, 11, 665.   DOI   ScienceOn
44 Victor, S. P.; Sharma, C. P. Colloids and Surfaces B: Biointerfaces 2013, 108, 219.   DOI   ScienceOn
45 Milner, S. T. Science 1991, 251, 905.   DOI   ScienceOn
46 Tang, Q. L.; Xu, Y.; Wu, D.; Sun, Y. H. J. Solid State Chem. 2006,179, 1513.   DOI   ScienceOn
47 Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordinates Compounds; Wiley: New York, 1978.