• 한국토양비료학회지
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• 제44권2호
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• pp.316-319
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• 2011

Biopiles which offer the potential for cost-effective treatment of contaminated soils are above-ground, engineered systems that use oxygen to stimulate the growth and reproduction of aerobic bacteria for degradation of the petroleum constituents adsorbed to soil in excavated soils. This technology involves heaping contaminated soils into piles and stimulating aerobic microbial activity within the soils through the aeration and/or addition of minerals, nutrients, and moisture. Inside the biopile, microbially mediated reactions by blowing or extracting air through the pipes can enhance degradation of the organic contaminants. The influence of a aeration system on the biopile performance was investigated. Air pressure made to compare the efficiency of suction in the pipes showed that there were slightly significant difference between the two piles in the total amount of TPH biodegradation. The normalised degradation rate was, however, considerably higher in the aeration system than in the normal system without aeration, suggesting that the vertical venting method may have improved the efficiency of the biological reactions in the pile.

• 한국환경보건학회지
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• 제33권6호
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• pp.493-496
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• 2007

The influences of contact time and ratio of food to microorganism (F/M) on uptake of wastewater organic matter in a short contact process were investigated using three activated sludge batch reactors fed with synthetic wastewater, sewage and livestock wastewater. About 64% of influent soluble chemical oxygen demand (SCOD) in the synthetic wastewater and 61% of SCOD in the sewage and 43% of SCOD in the diluted livestock wastewater were adsorbed into the activated sludge within 30 min. The specific mass of organic matter uptaken in the synthetic wastewater was 55 mg SCOD/g mixed liquor suspended solids (MLSS). In the same manner, 20 and 14 mg SCOD/g MLSS were calculated as the values in the sewage and livestock wastewater, respectively.

• 마이크로전자및패키징학회지
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• 제10권3호
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• pp.83-88
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• 2003

증착온도와 어닐링 조건에 따른 반도체-원자 초격자 구조의 광전자특성이 연구되었다. 나노결정의 Si-O 초격자 구조는 MBE 시스템에 의해 형성되었다. 다층의 Si-O 초격자 다이오드는 매우 안정한 포토루미네슨스 특성과 높은 브레이크다운 전압을 갖는 양호한 절연 특성을 나타내었다. 이러한 결과는 미래의 초고속 및 저전력 CMOS 소자에서 SOI 구조의 대체 방안으로 사용될 수 있을 뿐만 아니라, 실리콘계 광전자 소자 및 양자 전자 소자에도 응용될 수 있을 것이다.

• Bulletin of the Korean Chemical Society
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• 제35권7호
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• pp.1951-1955
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• 2014

Catalytic pyrolysis of Geodae-Uksae 1, a kind of miscanthus found in Korea, was carried out over mesoporous MCM-48 catalysts. For rapid product analysis and catalyst evaluation, pyrolysis-gas chromatography/mass spectrometry was used. X-ray diffraction, nitrogen sorption, pyridine adsorbed Fourier transform infrared, and NH3 temperature programmed desorption were utilized to analyze the properties of the catalysts. Compared to non-catalytic reaction, catalytic upgrading over mesoporous Al-MCM-48 catalysts produced a higher-quality bio-oil with a high stability and low oxygen content. Al-MCM-48 exhibited higher deoxygenation ability than Si-MCM-48 due to its higher acidity.

• Bulletin of the Korean Chemical Society
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• 제19권7호
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• pp.754-760
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• 1998

It was found that the adsorption of a cobalt(III) complex with a macrocyclic ligand, C-meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (hmc), was induced on a glassy carbon electrode by heavily oxidizing the electrode surface. Adsorption properties are discussed. The glassy carbon electrode with the adsorbed complex was employed to see the catalytic activities for the electro-reduction of O2. In the presence of oxygen, reduction of (hmc)Co3+ showed two cathodic waves in cyclic voltammetry. Compared to the edge plane graphite electrode at which two cathodic waves were also observed in a previous study, catalytic reduction of O2 occurred in the potential region of the first wave while it happened in the second wave region with the other electrode. A rotating disk electrode after the same treatment was employed to study the mechanism of the O2 reduction and two-electron reduction of O2 was observed. The difference from the previous results was explained by the different reactivity of the (hmc)CoOOH2+ intermediate, which is produced after the two electron reduction of (hmc)Co3+ in the presence of O2.

• Bulletin of the Korean Chemical Society
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• 제15권5호
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• pp.369-374
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• 1994

Self-assembled (SA) and Langmuir-Blodgett (LB) monolayers of arachidic acid on silver surfaces have been investigated by a reflection-absorption Fourier transform infrared spectroscopy. Arachidic acid was adsorbed on silver as carboxylate with its two oxygen atoms bound symmetrically to the surface. Although both the SA and LB monolayers consisted of fully extended trans zigzag carbon chains, a closer examination indicated that the SA monotayers should possess a more ordered crystalline structure than the LB monolayers. The infrared spectral data dictated that the extent of methyl group exposure at the air-film interface was greater in the SA monolayers than the LB monolayers, in agreement with the contact angle measurement. From a theoretical analysis, the alkyl chains in each monolayers seemed to be tilted away from the surface normal by less than $3.5^{\circ}$, but in opposite directions. Arachidic acid monolayers were concluded to have same structure as stearic acid monolayers.

• Bulletin of the Korean Chemical Society
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• 제11권5호
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• pp.396-399
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• 1990

Fourier transform infrared spectroscopy has been applied to the characterization of titania surface. The bands due to surface OH groups were observed to be more intense in the reduced titania than in the oxidized titania. The IR spectra of CO adsorbed on titania exhibited two C-O stretching bands, namely at 2187 and 2209 cm$^{-1}$. The intensities were stronger in the oxidized titania.The 2187 cm$^{-1}$-peak was attributed to CO coordinated to $Ti^{4+}_{5c}$ (subscriptindicates the coordination number of the coordinatively unsaturated cation by oxygen ions), while the 2209 cm-1-peak due to the $Ti^{4+}_{4c}{\cdots}$CO complex.

• Bulletin of the Korean Chemical Society
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• 제22권12호
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• pp.1323-1327
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• 2001

The catalyst Ni/MgO (Ni : 15 wt%) has been applied to methane reforming reactions, such as steam reforming of methane (SRM), partial oxidation of methane (POM), and oxy-steam reforming of methane (OSRM). It showed high activity and good stability in all the reforming reactions. Especially, it exhibited stable catalytic performance even in stoichiometric SRM (H2O/CH4 = 1). From TPR and H2 pulse chemisorption results, a strong interaction between NiO and MgO results in a high dispersion of Ni crystallite. Pulse reaction results revealed that both CH4 and O2 are activated on the surface of metallic Ni over the catalyst, and then surface carbon species react with adsorbed oxygen to produce CO.

• 한국자기공명학회논문지
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• 제9권1호
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• pp.1-20
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• 2005

Vanadium-incorporated aluminophophate molecular sieve VH-SAPO-11 has been studied by electron spin resonanace (ESR) and electron spin echo modulation (ESEM) spectroscopies to determine the vanadium locatin and interaction with various adsorbate molecules. As-synthsized VH-SAPO-11 contains only vanady1 species with distored octahral coordination. After calcinations in $O_2$ and exposure to moisture, only species A is observed with reduced intensities. Species A is suggested as a VO$(H_2O)_2^{2+$} complex coordinate to three framwork oxygen bonded to aluminum. When calcined, hydrate VH-SAPO-11 is dehydrated at elevated temperature, species A loses it water ligands and transforms to $VO^{2+}$ ions coordinated to three framework oxygens (species B). Species B reduces its intensities significantly after treatment with $O_2$at high temperature, thus suggesting oxidation of $v^{4+}$to $v^{5+}$. When dehydrated VH-SAPO-11 contacts with $D_2O$ at room temperature, the ESR signal of species A is observed. This species assumed as a $VO(O_f)_3(D_2O)_2$, by considering 3 framework oxygens. Adsorption of deuterated methanol on dehydrated VH-SAPO-11 results in another new vanadium species D, which is identified as a $VO(CD_{3}OH)$ complex. When deuterated ethanol is adsorbed on dehydrated VH-SAPO-11, another new vanadium species E identified as a $VO(C_{2}H_{5}OD)^{2+}$, is observed. When deuterated propanol is adsorbed on dehydrated VH-SAPO-11, a new vanadium species F identified as a $VO(C_{3}H_{7}OD)$, is observed. Possible coordination geometries of these various complexes are discussed.

• 한국진공학회지
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• 제20권4호
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• pp.252-257
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• 2011

본 연구 그룹은 6H-SiC (0001)에서 성장시킨 그라핀 층에 흡착된 퓨란(furan)의 고리 형성과 전자적 성질을 원자 힘 현미경(Atomic Force Microscope : AFM), C K-edge에 대한 Near Edge X-ray Absorption Fine Structure (NEXAFS) 스펙트럼, 핵심부 준위 광전자 분광스펙트럼(Core-level Photoemission Spectroscopy : CLPES)을 이용하여 연구했다. 우리는 그라핀위에 흡착된 퓨란 분자들이 화학적 도핑이 가능한 산소기의 홀 전자쌍을 통하여 그라핀의 특성을 조절할 수 있는 화학적 기능화에 이용될 수 있다는 것을 알아냈다. 또한, 퓨란이 자발적으로 세 가지의 다른 결합 구조들 중 하나로 고리를 형성한다는 것과 그라핀 위에 퓨란에 의해 형성된 고리의 전자적 성질들이 AFM, NEXAFS, CLPES를 이용하여 각각 설명될 수 있다는 것을 보여주었다.