• Title/Summary/Keyword: adhesives type

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Flexural Modulus of Larch Boards Laminated by Adhesives with Reinforcing Material

  • Injeong LEE;Weontae OH
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.1
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    • pp.14-22
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    • 2023
  • Economical use of larix (larch) boards (grade 3) in industries is lower than that of imported hardwood; thus, studies have been conducted toward performance improvement of larix boards. Herein, flexural modulus of larix board samples laminated with wood adhesives polyurethane resins, poly (vinyl acetate) resins, phenol-resorcinol-formaldehyde resins, melamine-formaldehyde resins, and urea-formaldehyde resins was compared with that of the samples bonded with adhesives reinforced with mesh-type basalt fibers. Moreover, the flexural moduli of the laminated samples bonded by mesh-type basalt fibers were compared with those of reinforced samples. The results showed that boards laminated with polyurethane and urea-formaldehyde resin adhesives had higher flexural modulus than those without the lamination. In particular, the increase in the flexural modulus was relatively significant for the 2- and 3-ply board structures laminated with polyurethane adhesives compared to those with reinforcement. The 3-ply board structure without reinforcement had the highest flexural modulus when the urea-formaldehyde resin adhesive was used.

Synthesis and Adhesion Characteristics of Water-Borne Acrylic Pressure Sensitive Adhesives(PSAs) (수계형 아크릴 점착제의 합성 및 점착 특성)

  • Hahm, Hyun-Sik;Kwak, Yun-Chul;Hwang, Jae-Young;Ahn, Sung-Hwan;Kim, Myung-Soo;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.2
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    • pp.191-199
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    • 2005
  • Removable protective adhesives for automobiles were synthesized by an emulsion polymerization of monomers such as n-butyl acrylate (BA), n-butyl methacrylate (BMA), acrylonitrile (AN), acrylic acid (AA) and 2-hydroxyethyl methacrylate (2-HEMA), in which AA and 2-HEMA were functional monomers. Potassium persulfate (KPS) was used as an initiator and sodium lauryl sulfate (SLS) was used as an emulsifier, and polyvinyl alcohol (PVA) was used as a stabilizer. Emulsion polymerization was carried out in a semi-batch type reactor. Tensile strength, extension, peel strength, viscosity and solid content of the synthesized adhesives were tested. The optimum physical properties of the removable protective adhesives for automobiles were obtained with the composition of 0.43 mole BA, 0.57 mole AN, 0.21 mole BMA, 0.03 mole AA, and 0.03 mole 2-HEMA.

A COMPARATIVE STUDY OF THE SHEAR BOND STRENGTH OF DIFERENT CERAMIC BRACKETS AND ADHESIVES (세라믹 브라켓과 교정용 접착제에 따른 전단 결합 강도의 비교 연구)

  • Lee, Joo-Won;Yoo, Dong-Hwan;Kim, Sang-Cheol
    • The korean journal of orthodontics
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    • v.27 no.2
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    • pp.315-326
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    • 1997
  • The purpose of this study was to evaluate the shear bond strength of three kinds of different ceramic brackets with three different bonding adhesives. 5 specimens for each combination were tested for shear bond strength using Instron and for fracture site using SENL And 3 specimens were cross-sectioned for SEM examination of bonding pattern between bracket, resin and enamel surface. The results were as follows 1. The shear bond strength of chemical curing adhesives were higher than that of light curing adhesives. 2. The shear bond strength of Starfire bracket, chemical-bonded type, was lower than that of Transcend bracket, mechanical-bonded type, and Fascination bracket, combined type. 3. Fracture site of each bracket and tooth surface was examined under a light optical stereoscopic microscope, Transcend groups were mainly at the E/R intderface. Fascination groups were mainly at the COMB interface and Starfire groups were mainly at the R/B interface.

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A Study on the Manufacturing and Applicability of Rosin-based Epoxy Adhesives and Filling Material for Conservation of Wood Crafts (목공예품 보존용 송진 기반 에폭시 접착제 및 메움제의 제조와 적용성에 관한 연구)

  • Wi, Koang-Chul;Han, Won-Sik;Oh, Seung-Jun
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.475-482
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    • 2020
  • In this study, we synthesized rosin-based epoxy resin and manufactured two components adhesives and epoxy putty using this epoxy resin. This study manufactured main element of adhesives for enabling it to form epoxide group by letting epichlorohydrin react to maleic anhydride modified rosin, and used room temperature curing type triethylenetetramine for hardener. The ratio between main element and hardener of of manufactured adhesives was 100 : 20, and main element and hardener of filling material were manufactured as clay type by mixing them with filler. Manufactured undiluted adhesives and filling material showed very stable result in the adhesive strength (3.06 MPa) and ultraviolet irradiation, showing outstanding result comparing to existing restoration adhesives. And it is considered a material having reversibility as it was dissolved in organic solvents such as acetone and toluene after being hardened, which showed a result that solved part of possible problems caused by restoration. As a result of use and application of manufactured adhesives and filling material for actual wood crafts, they showed excellent results in workability, stability, removability etc., and this study confirmed that the material can be used for and applied to various fields.

Strength properties of magnesium oxide matrix according to type of phosphate (인산염 종류에 따른 산화마그네슘 경화체의 강도 특성)

  • Lim, Jeong-Jun;Pyeon, Su-Jeong;Kim, Dae-Yeon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.79-80
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    • 2018
  • Recently, the interest in remodeling of new and old buildings is increasing worldwide. As a result, the frequency of use of architectural adhesives has increased. Currently, adhesives used in buildings are made of organic materials in most cases, and epoxy resin adhesives are most widely used. However, epoxy resin adhesives contain formaldehyde and VOCs in the room during construction, which can cause sick house syndrome. In case of building fire, it may cause damage due to carbon monoxide generated from organic materials. It is urgent to study the problem of epoxy fill adhesive made of such organic materials. Therefore, the purpose of this study is to investigate the effect of the adhesion of epoxy resin adhesive, which is a problem of epoxy resin adhesive, which is an existing organic adhesive by using inorganic materials such as magnesia and phosphate, And the inorganic adhesive which does not emit the release amount as an inorganic material.

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Study on the Physical Properties and Characteristics of Adhesives for Woodcraft (목공예용 천연 및 합성 접착제의 특성 연구)

  • Kim, Seong Eun;Lee, Jin Kyung;Lee, Chae Hoon;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.35 no.6
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    • pp.681-688
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    • 2019
  • In this study, the characteristics of natural and synthetic adhesives used in woodcraft were evaluated. The pattern of deterioration of wood and adhesives according to changes in temperature and humidity were compared. For materials, one type of anlmal glue, three kinds of polyvinyl acetate adhesives, one type of epoxy adhesive and one type of zelkova wood were selected. Characteristics of physical and chemical characteristics, weather resistance and drying speed assessment were carried out. The adhesion characteristic evaluation showed that the adhesion strength of anlmal glue and one type of polyvinyl acetate adhesive were 6.54 N/㎟ and 7.01 N/㎟, pH meter of anlmal glue and polyvinyl acetate adhesives was pH 7.03 and pH 3.32-3.59 which were range of available as an adhesive. According to the test results of weather resistance, epoxy adhesives had the highest decreasing value in adhesion strength after deterioration. In the reversible test of the adhesive, it was found to be highly reversible in NaOH, a soluble solvent excluding epoxy, but attention is required when using the wood since it may show discoloration during processing.

The Effects of Functional Monomers on the Synthesis andPhysical Properties of Solution Type Quaternary Polymer Acrylic Pressure-Sensitive Adhesives (관능성 단량체 종류에 따른 4원 용액형 아크릴계 점착제의 합성과 물성에 관한 연구)

  • Kim, Nam-Seok;Kim, Sung-Hoon
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.4
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    • pp.525-532
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    • 2008
  • To prepare a solution type acrylic pressure-sensitive adhesive, quarter polymers were synthesized from butyl acrylate(BA), 2-ethylhexylacrylate(2-EHA) as a base monomer, methyl methacrylate(MMA) as a comonomer, each of methacrylic acid(MAA), acrylic acid(AA) as a functional monomer. Acrylic solution type pressure-sensitive adhesives(PSA's) of isocyanate derivative crosslinking PSA's were prepared by crosslinking of BEMM, BEMA with toluene-2,4-diisocyanate. The structure of adhesive was identified by FT-IR. The viscosity was measured by using Brookfield DV-III and molecular weight was measured by using gel permeation chromatography. The physical properties of polyethylene film coated with BEMMT, BEMAT were measured as a function of the concentration. As the result, BEMMT(0.6, 0.8), BEMAT(0.6) showed peel adhesion of $160{\sim}180\;g_f$/25 mm width and shear adhesion of more than 24 hours, and tackiness of $4/32{\sim}6/32$ which was relevant to commercial usage.

An investigation into the effect of denture adhesives on incisal bite force of complete denture wearers using pressure transducers - a clinical study

  • Kalra, Pawan;Nadiger, Ramesh;Shah, Farhan Khalid
    • The Journal of Advanced Prosthodontics
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    • v.4 no.2
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    • pp.97-102
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    • 2012
  • Study was conducted to determine and assess the effect of different type of denture adhesives on the incisal bite force of complete denture wearers until the dislodgement of upper denture, using pressure transducer. MATERIALS AND METHODS. 30 patients out of 100 were included in the study. Based on the Kapur's method of scoring denture retention and stability, these patients were divided into 3 groups-Group A - Clinically good dentures; Group B - Clinically fair dentures; and Group C - Clinically poor dentures. A custom made occlusal force meter was constructed based on the load cell type of pressure transducers. Different adhesives (powder, paste and adhesive strips) were used in the study. Complete denture wearers were asked to bite on the load cell and the readings of incisal bite force were recorded. The readings of incisal bite force were subjected to statistical analysis using Repeated measures ANOVA followed by post-hoc bonferroni test. RESULTS. The result suggests that denture adhesives improved the incisal bite force of complete denture wearers significantly The incisal bite force (in kg) in Group A without using adhesives, with powder adhesive, with paste adhesive and with adhesive strips was found to be 2.48 (${\pm}0.16$), 3.43 (${\pm}0.11$), 6.01 (${\pm}0.11$), 3.22 (${\pm}0.09$) respectively. The incisal bite force (in kg) in Group B without using adhesives, with powder adhesive, with paste adhesive and with adhesive strips was found to be 1.87 (${\pm}0.18$), 3.35 (${\pm}0.14$), 5.34 (${\pm}0.18$), 3.21 (${\pm}0.12$) respectively. The incisal bite force (in kg) in Group C without using adhesives, with powder adhesive, with paste adhesive and with adhesive strips was found to be 1.00 (${\pm}0.17$), 3.07 (${\pm}0.14$), 4.37 (${\pm}0.26$), 2.99 (${\pm}0.14$) respectively. CONCLUSION. Within the limitations of the study, it was concluded that the use of denture adhesive was found to be significantly effective in improving the incisal bite force of complete dentures until the dislodgement of upper denture. Fittydent paste adhesive was found to be more effective than the powder and strips adhesives. The improvement in incisal bite force was found to be higher in Group C in comparison to that of Group A and Group B.

A Study on Preparation and Characteristics of Natural Adhesives with Lacquer and Animal Glue for Ceramics Conservation (옻과 아교를 이용한 토기 복원용 천연접착제 제조 및 특성 분석)

  • Kim, Eun Kyung;Park, Daewoo;Jang, Sungyoon
    • Journal of Adhesion and Interface
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    • v.14 no.3
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    • pp.128-134
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    • 2013
  • This study investigated the natural adhesives for ceramics conservation that can be used as a substitution for synthetic resins. Samples were prepared by mixing lacquer with animal glue and the structure and adhesion properties of the samples were analyzed. The structure analysis with FT-IR showed that carbonyl (C=O), amine (N-H) and aromatic (C=C) bonds are increased by adding animal glue on lacquer. Comparing to the viscosity and tensile strength of the sample to the Paraloid B-72 and Araldite rapid type, these natural adhesives can be a substitution for the synthetic resins. Through methodical and intensive study, we expect practical uses of this eco-friendly natural adhesives for ceramics conservation.

Properties of Inorganic Adhesives according to Phosphate Type and Borax Ratio (인산염 종류와 붕사 첨가율에 따른 무기접착재의 특성)

  • Song, Ha-Young;Lim, Jeong-Jun;Khil, Bae-Su;Lee, Sang-Soo
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.4
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    • pp.289-297
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    • 2019
  • Epoxy resin adhesives are currently used as adhesives in buildings. Epoxy resin adhesives, which are organic materials, generate harmful substances when producing adhesives, and toxic substances are high in the residential space after installation. In addition, a large amount of carbon monoxide generated from organic materials in the case of a building fire leads to personal injury. This study evaluates the feasibility of inorganic adhesives using pure inorganic materials such as magnesia, phosphate, and borax as inorganic adhesives to replace existing organic adhesives. As a result of the experiment on the selection of adequate phosphate and the characteristics of the addition rate of borax used as a retarder, the potassium phosphate monobasic was obtained as a suitable phosphate and the characteristics according to the borax addition rate were compared with the quality standard of KS F 4923 The hardening shrinkage and heat change rate satisfied the quality standards. The tensile strength was satisfactory when the borax addition rate was 4% or more, but the adhesive strength did not meet the quality standards. Further studies are needed to improve adhesion strength.