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Synthesis and Adhesion Characteristics of Water-Borne Acrylic Pressure Sensitive Adhesives(PSAs)

수계형 아크릴 점착제의 합성 및 점착 특성

  • Hahm, Hyun-Sik (Department of Chemical Engineering, Myongji University) ;
  • Kwak, Yun-Chul (Department of Chemical Engineering, Myongji University) ;
  • Hwang, Jae-Young (Department of Chemical Engineering, Myongji University) ;
  • Ahn, Sung-Hwan (Department of Chemical Engineering, Myongji University) ;
  • Kim, Myung-Soo (Department of Chemical Engineering, Myongji University) ;
  • Park, Hong-Soo (Department of Chemical Engineering, Myongji University)
  • 함현식 (명지대학교 공과대학 화학공학과) ;
  • 곽윤철 (명지대학교 공과대학 화학공학과) ;
  • 황재영 (명지대학교 공과대학 화학공학과) ;
  • 안성환 (명지대학교 공과대학 화학공학과) ;
  • 김명수 (명지대학교 공과대학 화학공학과) ;
  • 박홍수 (명지대학교 공과대학 화학공학과)
  • Published : 2005.06.30

Abstract

Removable protective adhesives for automobiles were synthesized by an emulsion polymerization of monomers such as n-butyl acrylate (BA), n-butyl methacrylate (BMA), acrylonitrile (AN), acrylic acid (AA) and 2-hydroxyethyl methacrylate (2-HEMA), in which AA and 2-HEMA were functional monomers. Potassium persulfate (KPS) was used as an initiator and sodium lauryl sulfate (SLS) was used as an emulsifier, and polyvinyl alcohol (PVA) was used as a stabilizer. Emulsion polymerization was carried out in a semi-batch type reactor. Tensile strength, extension, peel strength, viscosity and solid content of the synthesized adhesives were tested. The optimum physical properties of the removable protective adhesives for automobiles were obtained with the composition of 0.43 mole BA, 0.57 mole AN, 0.21 mole BMA, 0.03 mole AA, and 0.03 mole 2-HEMA.

Keywords

References

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