• 한국응용과학기술학회지
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• 제30권3호
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• pp.551-559
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• 2013

To investigate the adhesion effect of sodium bisulfite content in making blocked isocyanate, wood adhesive PB-1, PB-2, PB-3 and PB-4 containing sodium bisulfite content of 15%, 22.5%, 30% and 37.5% were synthesized respectively. As a result, when the amount of sodium bisulfite increased in adhesives, the tensile strength was found to be proportionally increased. The final adhesive mixtures were manufactured using a two-components system which are prepared by mixing two separate protein and BI solutions due to the precipitate in the adhesives. As PVA was added to adhesives to increase tenacity, the plywood dehiscence phenomenon after cold pressing process was declined. By addition of PVA, the tensile strength was improved up to $6.5{\sim}7kgf/cm^2$ with BI/protein ratio from 1:6 up to 1:8. Phase separation between milk fat and aqueous layer was disappeared after addition of emulsifier, Tween 20. Additon of Tween 20 showed tensile strength up to $5{\sim}6.5 kgf/cm^2$ at NCO/protein ratio of 1:12 ~ 1:14 without phase separation.

• 접착 및 계면
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• 제17권2호
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• pp.56-61
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• 2016

본 연구에서는 아크릴 접착제의 물성에 대한 주 모노머의 영향을 비교하기 위하여 2-ethylhexyl acrylate 대신에 butyl acrylate를 사용하여 acrylic acid와 2-hydroxyethyl methacrylate의 공중합체를 합성하고 2종의 경화제를 이용하여 접착 물성을 연구하였다. 선형의 측쇄사슬을 가진 butyl acrylate계 점착제는 가지형태의 측쇄를 가진 2-ethylhexyl acrylate계 접착제에 비해 낮은 접착특성을 보였다. 경화제의 경우 가교점이 많고 가교반응을 통해 유연한 ether나 ester그룹을 생성하는 epoxy형 경화제에서 우수한 물성을 보였고 관능기인 산의 농도가 높을수록 접착특성이 향상되는 것을 관찰하였다.

• 한국안전학회지
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• 제18권3호
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• pp.81-87
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• 2003

Latex polymers are widely used for adhesive, binder, paint etc. Especially the PVAc(Polyvinyl acetate) latex which manufactured by vinyl acetate and vinyl alcohol as protective colloid is a useful environmentally friendly adhesive. To increase useful property of PVAc latex, this study was carried out for checking thermal characteristics and physical condition of PVAc latex by DSC, FT-IR, Pyrolyzer GC-MS. The activation energies of thermal decomposition for 40, 48, 56, 64% solid content of PVAc latex were found as 28.1-36.0kcal/mol by Kissinger's method and 17.2-22.0kcal/mol by DSC method. Actually, reasonable solid content could be consiered as 56% because of activation energy and adhesive characteristics. According to the effect of protective colloid for 4, 10, 15, 20wt%, the activation energy shows same tendency to both method and in case of l5wt% has been found as the highest activation energy. The mechanism of thermal decomposition was mainly estimated by main chain scission, not by side group on FT-IR analysis. Main component of Pyrolzer GC-MS result were consisted of $CH_3COOH$, $CH_3$, $H_2O$ and light gases(CO, $CO_2$, $CH_4$ etc).

• Korean Chemical Engineering Research
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• 제46권1호
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• pp.76-81
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• 2008

아크릴계 점착제를 합성한 후 이관능성 혹은 육관능성 우레탄-아크릴레이트 올리고머를 혼합하여 자외선 경화형 점착제를 제조하였다. 올리고머 종류 및 함량을 변화시켜 그에 따른 접착력 변화와 재박리 특성을 조사하였다. 자외선 경화전에는 올리고머의 함량의 증가에 따라 박리력이 증가하였으나 자외선 경화 후에는 감소하는 경향을 보였다. 저장 탄성률(G')이 낮을수록 박리력은 증가하지만 점착제 내부의 상용성과 손실계수(tan ${\delta}$) 값에 따라 점착제의 박리정도와 접착력에 영향을 주는 것을 확인할 수 있었다.

• 접착 및 계면
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• 제11권1호
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• pp.26-34
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• 2010

가열에 의해 해체가 가능한 열적특성을 갖는 폴리우레탄 접착제를 합성하였으며 열팽창비드를 혼합하여 해체성 접착제를 제조하였다. Dynamic mechanical thermal analyzer (DMA)를 사용하여 폴리우레탄의 열적특성을 확인하였고 접착강도와 열팽창비드의 함량, 가열 trigger의 종류와 처리조건에 따른 해체특성을 연구하였다. 열풍과 microwave 처리에 의해서 해체성 폴리우레탄 접착제의 부피팽창에 따른 접착된 시편의 해체가 가능하였으며, 열팽창비드의 함량이 증가될수록 접착된 피착재가 더 쉽게 분리되었다. 해체성 접착제에서 접착력과 해체특성 모두를 만족시킬 수 있는 가장 적합한 열팽창비드 사용량은 40%이였으며, 가열 trigger로 열풍을 사용한 경우에는 $160^{\circ}C$, 30 min의 조건에서, 가열 trigger로 microwave를 사용한 경우에는 조사시간 4 min의 조건에서 접착되어 있는 피착재가 완전히 해체되었다.

• Journal of the Korean Wood Science and Technology
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• 제34권3호
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• pp.22-29
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• 2006

친환경 건축자재에 대한 관심이 높아짐에 따라서 가구 및 건축 내외장재로 사용되는 목질복합재료에 대한 친환경적 성능에 대한 요구는 점차 커져가는 추세이다. 목질 복합재료는 일반적으로 그 자체로 사용하기 보다는 표면재를 붙여서 사용하는데 이때 사용되는 요소포름알데히드 접착제를 친환경적인 SIS계 핫벨트 점착제로 대체코자 하는 데 이 연구의 목적이 있다. 본 연구에서는 기질고분자의 diblock 함량, 점착부여수지의 연화점 및 함량 등을 변화시키면서 여러 종류의 핫벨트 점착제를 제조하고 각각의 점착제에 의한 무늬목 부착성능을 평가함으로써 점착형 표면재에 대한 가능성을 제기하였다.

• Journal of the Korean Wood Science and Technology
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• 제48권3호
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• pp.303-314
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• 2020

Gambir is a non-wood forest product with a potential of being used as wood adhesive, due to about 33% catechin in it. Meanwhile, catechins and sucrose have not been studied as adhesives. Therefore, basic characteristics of gambir-sucrose adhesives were investigated. In this research, adhesives were prepared by dissolving gambir and sucrose in distilled water, at different blending ratios of the gambir/sucrose such as 100/0, 75/25, 50/50, and 25/75 wt%. Furthermore, gas chromatography-mass spectrometry (GC-MS) was employed to determine the gambir chemical compositions, and Fourier transform-infrared (FTIR) spectroscopy was carried out to identify chemical bonds. Particleboards with a target density of 0.8 g/㎤ were then manufactured by hot-pressing for 10 min at 200℃. The internal bond (IB) strength of particleboard was subsequently measured. Based on the GC-MS analysis, 31.11% of catechin was identified. In addition, the viscosity, density, solid content, and gelation time of the adhesives, and insoluble matter content (IMC) in boiling water were 7.30~33.24 mPa.s, 1.2~1.3 g/㎤, 25.56~28.44%, 73~420 min, and 29.75~62.10%, respectively. Adding sucrose to the adhesive was observed to raise the IMC from 49.05 to 62.10%, at 180℃ and 200℃. FT-IR analysis showed that the gambir absorption peaks occurred at approximately 1620 cm^-1, assigned to the C=O stretching of 5-hydroxymethylfurfural, which tended to increase with the addition of sucrose. The reaction between gambir and sucrose was observed in the form of the dimethylene ether bridge. The 25/75 wt% gambir-sucrose adhesives and 200℃ hot-pressed temperature resulted in the highest IB strength (0.89 MPa), and met the requirement of JIS A5908-2003 type 18. Consequently, the gambir-sucrose adhesive could be used as a particleboard adhesive.

• 한국염색가공학회지
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• 제30권2호
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• pp.107-116
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• 2018

Simplification of the manufacturing process in shoe making is essential to improve productivity and reduce production costs. To improve the adhesion of EVA foam used as a midsole, EVA/itaconated EPDM(EPDM-g-IA)(80/20wt%) blend was prepared using Torque Rheometer-Plasti-Corder, and 1,6-hexamethylenediamine/crosslinking agent/foaming agent/additive were mixed, followed by amidation reaction and foaming to prepare EVA/EPDM-g-IA foam for shoe midsole. In this study, we investigate the effect of the content of 1,6-hexamethylenediamine(0, 0.5, 1.0, 2.0, 3.0) on the mechanical properties, water-contact angle and adhesion of EVA/itaconated EPDM foam. As the content of 1,6-hexamethylenediamine increased, mechanical properties such as tensile strength, tear strength, tensile elastic modulus, hardness, and water-contact angle were lowered, but elongation at break and compression set(%) were increased. Both normal type and non-UV type adhesive strength increased with increasing diamine content. In particular, it was found that the adhesion strength of the non-UV type adhesion increased sharply with increasing diamine content. As a result, an adherend rupture occurs in a foam sample having a content of 1,6-hexamethylenediamine of 3phr. From this, it can be seen that the EVA/itaconated EPDM foam for shoe midsoles, which can be used for non-UV adhesion without primer and UV treatments, have been developed.

• Composites Research
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• 제31권4호
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• pp.151-155
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• 2018

기계적 조인트와 접착 조인트는 구조물의 일반적인 접합 방법이다. 접착 조인트는 기계적 체결법에 비해 넓은 면적에 하중이 분포되고 우수한 피로 특성을 가진다. 이러한 특성에도 불구하고, 접착 조인트는 환경조건이나 작업자의 숙련도에 대한 접착 건전성이 크게 달라진다. 따라서 접착 조인트의 건전성을 평가 할 수 있는 기술이 필요하다. CNT를 접착제에 분산시켜 접착조인트의 전기적 특성을 측정하는 전기저항법은 결함을 검출하는 매우 유망한 기술이다. 본 논문에서는 초음파 분쇄기와 3-roll-mill을 이용하여 접착제에 CNT를 균일하게 분산시켰으며, 알루미늄-알루미늄 단일 접착 조인트를 제작하여 탄소나노튜브(CNT) 함량에 따른 정적 강도의 변화를 평가하고, 전기저항법을 이용하여 결함탐지능을 평가하였다.

• Journal of the Korean Wood Science and Technology
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• 제52권4호
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• pp.301-318
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• 2024

Contrary to other materials like metals, glass, etc., wood continuously interacts with the environment, increasing and decreasing its moisture content according to the humidity of the air and changing its dimensions by swelling or shrinking. Water diffusion through laminated solid wood is crucial in wood bonding processes. The adhesive layer might block the diffusion if the water vapor diffusion is perpendicular to the bond line. As a result of this blockage, different proportions of deformation appear on the two sides of the bond line, which causes stresses in the bonded assembly. The question arises of how long the bonded structure will keep its integrity due to moisture diffusion blockage, inevitable tensions appearing in the glue line, and how these stresses could be avoided. With cross laminated timber (CLT) solid wood panel production, this question gains new importance. Despite the relevance, only a limited number of publications are available. Comprehensive research would also be necessary considering both the molecular structure and diffusion properties of the adhesive adjusted to the wood species (covering possible substituting wood species, too). Overall, this review serves as a resource for enhancing our understanding of water vapor diffusion through wood adhesive layers and provides insights that have implications for reducing stresses in bonded wood assemblies and the performance of the bonded group over time. Furthermore, identifying knowledge gaps is necessary to establish the basis for investigating the diffusion property of CLT panels.