• Title/Summary/Keyword: adhesion ratio

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Adhesion and Interface Chemical Reactions of Cu/CuO/Polyimide System (Cu/CuO/Polyimide 시스템의 접착 및 계면화학 반응)

  • Lee, K.W.;Chae, H.C.;Choi, C.M.;Kim, M.H.
    • Korean Journal of Materials Research
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    • v.17 no.2
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    • pp.61-67
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    • 2007
  • The magnetron reactive sputtering was adopted to deposit CuO buffer layers on the polyimide surfaces for increasing the adhesion strength between Cu thin films and polyimide, varying $O_2$ gas flow rate from 1 to 5 sccm. The CuO oxide was formed through all the $O_2$ gas flow rates of 1 to 5 sccm, showing the highest value at the 3 sccm $O_2$ gas flow rate. The XPS analysis revealed that the $Cu_2O$ oxide was also formed with a significant ratio during the reactive sputtering. The adhesion strength is mainly dependent on the amount of CuO in the buffer layers, which can react with C-O-C or C-N bonds on the polyimide surfaces. The adhesion strength of the multi-layered Cu/buffer layer/polyimide specimen decreased linearly as the heating temperature increased to $300^{\circ}C$, even though there showd no significant change in the chemical state at the polyimide interface. This result is attributed to the decrease in surface roughness of deposited copper oxide on the polyimide, when it is heated.

Strength Properties of CLC According to Additional Ratio of Polymer (폴리머 첨가율에 따른 CLC의 강도 특성)

  • Lee, Jeong-Taek;Lee, Chang- Woo;Hwang, Woo-Jun;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.83-84
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    • 2022
  • Zero-energy construction is being emphasized due to environmental pollution. However, in the case of external insulation using organic insulation with good insulation performance, there are many studies on inorganic insulation as it shows limitations on fire stability. In addition, as the demand for stone for exterior walls increases, Cellular Light -weight Concrete(CLC) with polymer is used to supplement fire stability and insulation performance, and the construction of stone is complemented by combining organic insulation, inorganic insulation, and stone. In this study, the compressive strength and adhesion in tension of CLC are studied. As a result of the experiment, the compressive strength of 28 days according to the polymer addition rate did not change. The adhesion in tension according to the polymer addition rate tends to increase as the addition rate increases. The target adhesion in tension is 0.8 MPa, but the maximum value of the experiment did not reach the target value, and further research was needed to combine to maintain the density and improve the adhesion in tension.

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Development of Polymer-Modified Cementitious Self-Leveling Materials for Thin Coat

  • Kim, Wan-Ki;Do, Jeong-Yun;Soh, Yang-Seob
    • KCI Concrete Journal
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    • v.13 no.2
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    • pp.58-66
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    • 2001
  • Recently, polymer-modified mortar has been studied for proposed use on industrial floors as top coat with thin thickness, typically 5~15mm. The purpose of this study is to evaluate basic properties of self-leveling materials using polymer dispersions as kinds of SBR, PAE, St/BA with thin coat (under 3mm). Superplasticizer and thickener have been included in the mixes to reduce bleeding and drying shrinkage as well as to facilitate the workability required. The self-leveling materials using four types of polymer dispersion are prepared with polymer-cement ratio which respectively range from 50% and 75%, and tested for basic characteristics such as unit weight, air content, flow, consistency change and adhesion in tension. From the test results, the self-leveling materials using PAE emulsion at curing age of 28days are almost equal to those of conventional floor using urethane and epoxy resin. The adhesion in tension of self-leveling mortars using SBR latex and PAE emulsion at curing age of 3days is over 17 kgf/cm$^2$(1.67MPa). Consistency change is strongly dependent on the type of polymer dispersion. It is concluded that the self-leveling materials using polymer dispersions can be used in the same manner as conventional floor using thermosetting resin in practical applications, in the selection of polymer dispersions.

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Studies on the Utilization of Chestnut Bur(2) - Utilization of Chestnut Bur Powder as Glue Extender for Plywood Adhesion - (밤송이 이용(利用)에 관(關)한 연구(硏究)(2) - 밤송이 분말(粉末)의 합판접착용(合板接着用) 증량제(增量劑)로의 이용(利用) -)

  • Kong, Young-To;Kim, Jae-Kwang;Ahn, Byung-Hwan;Jo, Jae-Myeong;Kang, Young-Mu
    • Journal of the Korean Wood Science and Technology
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    • v.15 no.4
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    • pp.64-68
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    • 1987
  • To develope the utilities of the chestnut bur, which is wasted after harvesting chestnut in farmhouses, the feasibilities of adhesion(urea resin) extenders of the powder for plywood were examined. These experiments were implemented on experimental scale at Forestry Research Institute(Seoul) and on a plywood mill scale at Eugon Industrial Co LTD(Inchon) for more reliable data. In this paper, it was proved that the chestnut bur powder caused to rise the glue viscosity but the chaff powder to down reversely. The most effective mixing ratio were wheat flour 5kg, chaff powder: 5kg and chestnut bur powder. 5kg per 100kg of urea resin. At this condition, the viscosity were most appropriate (1,320 2,230 cps) for glue spreading operations, and the dry shear strengthes were most adequate(10.7-13.2kg/$cm^2$), wood failure ratio 82-88%). The chestnut bur powder, can be utilized for plywood adhesion extenders without any change of present process lines in plywwod mills.

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Preparation and Properties of UV Curable Urethane Acrylates for Ink Binder (Ink Binder용 UV 경화형 조성물의 제조 및 특성)

  • Park, Hyun-Ju;Han, Chang-Duk;Oh, Sang-Taek
    • Journal of Adhesion and Interface
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    • v.14 no.4
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    • pp.167-174
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    • 2013
  • In this study, Ultraviolet (UV) curable urethane acrylates for ink binder was prepared by reaction of IPDI, polyether polyol and HEA. The UV curing behavior of compositions with HEA/PETA ratio on UV irradiation time was investigated by FT-IR spectrophotometer, probe tack tester and Photo-DSC. Conversion % and gel content were increased with increasing UV irradiation time, but probe tack was decreased. Storage modulus, tensile strength and decomposition temperature were increased as PETA content increased. In case of HEA/PETA ratio was 30/70, adhesion property of UV-cured composition on PMMA sheet was excellent.

A Study on the Adhesion Properties of Polymer-Cement Composites for Repairing Cracks in RC Structures (RC 구조물의 균열 보수용 폴리머 시멘트 복합체의 접착특성에 관한 연구)

  • Jo, Young-Kug;Hong, Dae-Won;Kwon, Woo-Chan;Kim, Wan-Ki
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.1
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    • pp.23-34
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    • 2022
  • The purpose of this study is to evaluate the adhesion properties of polymer cement composites for crack repair of an RC structure. Polymer cement composites are manufactured from cement, three types of polymers and silica fume, and the mixture is designed by adjusting the water cement ratio and AE reducing agent so that the viscosity target of the polymer cement composites is 700mPa·s or less. According to the test results, the Type-A adhesion in tension of the polymer cement composite exceeded the adhesion standard of 1.0MPa of the polymer finishing material, and furthermore, depending on the type of polymer, the adhesion in tension was highest for SAE, followed in descending order by EVA, and SBR. In addition, the adhesion in tension of Type-B is up to 1/4.5 lower than that of Type-A, but the incorporation of silica fume shows a significant improvement in terms of adhesion in tension. Based on this study, the basic mixing design of the polymer cement composites required for viscosity and adhesive performance required for crack repair of the RC structure was completed. It could be proposed as an optimal mixing design under conditions for intermixing polymer type EVA, SAE, and P/C 80%-100%.

Effects on Density and Dominant rate of Periphyton by Variation of Dissolved Silicon Concentration (용존규소농도의 변화가 하천 부착조류의 밀도와 우점율에 미치는 영향에 관한 연구)

  • Jeon, Kyoung-ho
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.6
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    • pp.703-709
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    • 2009
  • In this study, an artificial-waterway experiment was conducted, using an attachment plate, on which algae from Nanakita river was placed, to examine the influence exerted by the variation of the dissolved-silicon concentration on the river periphyton. As a result, the variation of the dissolved-silicon concentration was found to exert an influence on the density of the adhesion diatom, and the mole ratio limits of the silica were about $Si/P{\fallingdotseq}182$ and $Si/N{\fallingdotseq}16.4$ or less. Moreover, the mole ratio that is necessary for proliferation was found to be larger than the value of the oceanic algae. Senedesmus sp. and Ankistrodesmus sp., which used silica in adhesion chlorophyta, received the influence of the silicon concentration strongly, and the twowere found to be superior in the environment, making silica a restriction factor.

The Optimization of the Selective CVD Tungsten Process using Statistical Methodology (통계적 기법을 이용한 선택적 CVD 텅스텐 공정 최적화 연구)

  • 황성보;최경근;박흥락;고철기
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.12
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    • pp.69-76
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    • 1993
  • The statistical methodology using RSM (response surface method) was used too ptimize the deposition conditions of selective CVD tungsten process for improving the deposition rate and the adhesion property. Temperature, flow rate of SiH$_4$ and WF$_6$ and H$_2$ and Ar carrier gases were chosen for the deposition variables and process characteristics due to carrier gas were intensively investigated. It was observed that temperature was the main factor influencingthe deposition rate in the case of H$_2$ carrier gas while the reactant ratio, $SiH_{4}/WF_{6}$, had the principal effect on the deposition rate in the case of Ar carrier gas. The increased deposition rate and the good adhesion to Si were obtained under Ar carrier gas compared to H$_2$ carrier gas. The optimum conditions for deposition rate and antipeeling property were found to be the temperature range of 300~32$0^{\circ}C$ and the reactant ratio, $SiH_{4}/WF_{6}$, of 0.5~0.6.

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An Experiment Study on the Safety and Bond Strength of Exterior Tile (외장타일의 접착강도 및 안전성에 관한 실험적 연구)

  • 김동준
    • Journal of the Korean Society of Safety
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    • v.4 no.1
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    • pp.91-98
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    • 1989
  • Today, the conception of building architecture is changing the conception that it is a kind of product and the operator of construction try to produce excellent building through developing efficiency and materials of building component. This study improves the problematic point of the extenor tile setting, through making on experiment on the method of it and purposes doing to do the exterior tile setting of good quality as it selects out of the most conformable the method. The experimental materials choose the tile of 60$\times$108mm size which are using frequently in the exterior tile setting and mortar is made from sand of Han river and potland cement, which apply the volume mixing of the ratio 1:3. The water cement ratio (W/C)is made up 62% The methods of tile setting utilise the method of the tile setting and laying the method of the tile improved setting and laying, the method ol the pressing adhesion, the method of the improved pressing adhesion and the method of setting adherent (the method of VIBRATOR).

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Preparation of Nanocapsules Containing Phase Change Materials by Miniemulsion Polymerization

  • Oh, Keun Jin;Kim, Dae-Su;Lee, Jae Heung;Choi, Kil-Yeong;Lee, Changjin
    • Journal of Adhesion and Interface
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    • v.4 no.1
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    • pp.35-42
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    • 2003
  • Polystyrene nanocapsules containing octadecane as a core material were prepared by miniemulsion polymerization. The morphology and size of the nanocapsules were measured with varying the surfactant concentration, content of initiator, core/shell ratio and content of comonomer. The morphologies of the prepared nanoparticles were examined by a scanning electron microscope, a transmission electron microscope and the core material was confirmed by a differential scanning calorimeter. The particles below 70 nm in diameter were formed at a high surfactant concentration. The size of the nanoparticles was not significantly affected by the initiator content. With increasing the core/shell ratio and polar comonomer content, the particle size and its distribution were increased.

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