• Title/Summary/Keyword: adhesion ratio

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Tensile and Adhesive Properties of Polymer Cement Mortar with EVA Emulsion, Blast-Furnace Slag and Fly Ash as a Repair Material (보수재료로서 EVA 에멀젼과 고로슬래그 미분말 및 플라이애쉬를 혼입한 폴리머 시멘트 모르타르의 인장·접착특성)

  • Jo, Young-Kug
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.11
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    • pp.147-154
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    • 2019
  • The purpose of this study is to evaluate the effect of admixtures as blast-furnace slag(BF) and fly ash(FA) on tensile and adhesive properties of polymer cement mortar(PCM) with EVA emulsion. The test specimens are prepared with five polymer-cement ratio(P/C) and five admixture contents, and tested for tensile strength and adhesion in tension. From the test results, the tensile strength and adhesion in tension could be improved by an appropriate combination of P/C and admixture contents. In particular, the maximum of tensile strength of PCM with P/C 10% and BF content of 10% is 4.70MPa which is about 1.55 times higher than that of plain mortar, and about 1.22 times that of PCM that does not contain any mixture. The ratio of adhesion in tension to tensile strength of PCM with admixtures averaged 55.8%. It is also apparent that admixture contents of 5% or 10% could be proposed for improvement of tensile strength and adhesion in tension of PCM.

A Study on the Improvement of Adhesion in Tension and Flexure of Polymer Cement Mortar Depending on Various Test Methods (시험방법에 따른 폴리머 시멘트 모르타르의 인장 및 휨접착강도 개선에 관한 연구)

  • Jo, Young-Kug
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.1
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    • pp.47-57
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    • 2019
  • The purpose of this study is to evaluate the improvement effect of adhesion in tension and flexure of polymer cement mortars that have widely used as a repair-reinforcement material in construction field according to adding of polymer dispersions depending on different three types test methods. From the test results, the adhesion performance is improved with a raise in polymer-cement ratio irrespective of the type of polymer. The maximums of A type adhesion in tension, B type adhesion in tension and adhesion in flexure show 1.90 times, 2.17 times and 1.83 times, respectively that of plain cement mortar. The relative strength ratios, B type adhesion in tension and adhesion in flexure of polymer cement mortars to tensile and flexural strengths of plain mortar respectively are in ranges of 50.1% to 101.7% and 73.8% to 132.9% compared to 46.9% of plain mortar. It is apparent that polymer cement mortars with EVA and polymer cement ratios of 10% to 15% are recommended considering its adhesion performance and cost as a repair-reinforcement material in construction field.

Studies on Adhesion Properties of Grafted EPDM Containing Carboxylic Acid Group (카르복시산을 포함하는 Grafted EPDM의 접착특성에 관한 연구)

  • Kim, Dongho;Yoon, Yoomi;Chung, Ildoo;Park, Chanyoung;Bae, Jongwoo;Oh, Sangtaek;Kim, Guni
    • Journal of Adhesion and Interface
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    • v.13 no.1
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    • pp.1-8
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    • 2012
  • The effect of the grafting ratio on the mechanical property and adhesion property of the grafted EPDM modified with methacrylic acid (MA) was investigated. The storage modulus of MA-grafted EPDM was maintained higher than that of cross-linked EPDM vulcanizate by sulfur, but it was observed that the storage modulus was decreased at elevated temperature because of the weakened secondary bonding. When the functional group for hydrogen bonding was introduced in EPDM, it had excellent mechanical properties by the aggregate between grafted EPDM molecules and crystallinity of MA. The bonding strength between EPDM and other rubbers was very low because EPDM has nonpolar property and low molecular interaction to others. The bonding strength was increased as increasing grafting ratio and it was excellent enough to break the rubber during the peel test when the grafting ratio was more than 10%.

Adhesion Properties of Urea-Melamine-Formaldehyde (UMF) Resin with Different Molar Ratios in Bonding High and Low Moisture Content Veneers

  • Xu, Guang-Zhu;Eom, Young-Geun;Lim, Dong-Hyuk;Lee, Byoung-Ho;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.2
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    • pp.117-123
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    • 2010
  • The objective of this research was executed to investigate the effect of molar ratio of formaldehyde to urea and melamine (F/(U+M)) of urea-melamine-formaldehyde (UMF) resin on bonding high and low moisture content veneers. For that purpose, UMF resin types with 5 different F/(U+M) molar ratios (1.45, 1.65, 1.85, 2.05, and 2.25) synthesized were used in present study. First, their curing behavior was evaluated by differential scanning calorimetry. Second, their adhesion performance in bonding high and low moisture content veneers was evaluated by probe tack and dry and wet shear strength tests. Curing temperature and reaction enthalpy decreased with the increase of F/(U+M) molar ratio. And the dry and wet shear strengthsof plywood manufactured from low moisture content veneers were higher than thoseof plywood manufactured from high moisture content veneers. Also, the maximum initial tack force on the low moisture content veneer was higher than that on the high moisture content veneer.

Effect of Plasma Etching and $PdCl_2/SnCl_2$ Catalyzation on the Performance of Electroless Plated Copper Layer (플라즈마 에칭 및 $PdCl_2/SnCl_2$ 촉매조건이 무전해 동도금 피막의 성능에 미치는 영향)

  • 오경화;김동준;김성훈
    • Journal of the Korean Society of Clothing and Textiles
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    • v.27 no.7
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    • pp.843-850
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    • 2003
  • Cu/PET film composites were prepared by electroless copper plating method. In order to improve adhesion between electroless plated Cu layer and polyester (PET) film, the effect of pretreatment conditions such as etching method, mixed catalyst composition were investigated. Chemical etching and plasma treatment increased surface roughness in decreasing order of Ar>HCl>O$_2$>NH$_3$. However, adhesion of Cu layer on PET film increased in the following order: $O_2$<Ar<HCl<NH$_3$. It indicated that appropriate surface roughness and introduction of affinitive functional group with Pd were key factors of improving adhesion of Cu layer. PET film was more finely etched by HCI tolution, resulting in an improvement in adhesion between Cu layer and PET film. Plasma treatment with NH$_3$produced nitrogen atoms on PET film, which enhances chemisorption of Pd$^{2+}$ on PET film, resulting in improved adhesion and shielding effectiveness of Cu layer deposited on the Pd catalyzed surface. Surface morphology of Cu plated PET film revealed that Pd/Sn colloidal particles became more evenly distributed in the smaller size by increasing the molar ratio of PdCl$_2$; SnCl$_2$from 1 : 4 to 1 : 16. With increasing the molar ratio of mixed catalyst, adhesion and shielding effectiveness of Cu plated PET film were increased.d.

Adhesion Properties of Polymer Composite Materials for Concrete Repair (콘크리트 보수용 폴리머 복합재료의 접착강도 특성)

  • 지경용;연규석;이윤수
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10a
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    • pp.330-335
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    • 1998
  • This research was conducted to evaluate the adhesion in tension of the polymer mortars for cement concrete repair. Various polymer types, binder ratios, and wet/dry conditions of the surface were considered in this study. Styrene-butadiene rubber (SBR) and ethylen vinyl acetate (EVA) used for polymer cement mortars. Epoxy resin (EP), and unsaturated polyester resin (UP) were used for polymer mertars. Adhesion in tension for the dry condition of the substrate surface was higher than that for the wet condition of the substrate surface under the same binder ratio. Therefore, in repairing concrete, the dry surface condition was effective on adhesion.

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Characterization of the Galvanizing Behavior Depending on Annealing Dew Point and Chemical Composition in Dual-Phase Steels

  • Shin, K.S.;Park, S.H.;Jeon, S.H.;Bae, D.C.;Choi, Y.M.
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.247-253
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    • 2010
  • The characteristics of selective oxidation prior to hot-dip galvanizing with the annealing atmosphere dew point and chemical composition in dual-phase steels and their effect on the inhibition layer formation relevant to coating adhesion have been studied using a combination of electron microscopic and surface analytical techniques. The annealed and also galvanized samples of 3 kinds of Si/Mn ratios with varied amounts of Si addition were prepared by galvanizing simulator. The dew point was controlled at soaking temperature $800^{\circ}C$ in 15%$H_2$ -85%$N_2$ atmosphere. It was shown that good adhesion factors were mainly uniformity of oxide particle distribution of low number density and low Si/Mn ratio prior to hot-dip galvanizing. Their effect was the greatly reduced coating bare spots and the formation of uniform inhibition layer leading to good adhesion of Zn overlay. The mechanism of good adhesion is suggested by two processes: the formation of inhibition layer on the oxide free surface uncovered with no $SiO_2$-containing particles in particular, and the inhibition layer bridging of oxide particles. The growth of inhibition layer was enhanced markedly by the delayed reaction of Fe and Al with the increase of Si/Mn ratio.

Electrical Effects of the Adhesion Layer Using the VDP Process on Dielectric

  • Lee, Dong-Hyun;Pyo, Sang-Woo;Hyung, Gun Woo;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1313-1316
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    • 2005
  • In the present paper, it was investigated that adhesion layer on gate insulator could affect the electrical characteristics for the organic thin film transistors (OTFTs). The polyimide (PI) as organic adhesion layer was fabricated by using the vapor deposition polymerization (VDP) processing . It was found that electrical characteristics improved comparing OTFTs using adhesion layer to another. We researched adhesion layer as a function of thickness. For inverted-staggered top contact structure, field effect mobility, threshold voltage, and on-off current ratio of OTFTs using adhesion layer of PI 15 nm thickness on the gate insulator with a thickness of 0.2 ${\mu}m$ were about 0.5 $cm^2/Vs$, -0.8 V, and $10^6$, respectively.

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Optimization of Biomimetic Two-level Hierarchical Adhesive System (자연모사 2층 구조 응착시스템의 최적화)

  • Kim, Tae-Wan
    • Tribology and Lubricants
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    • v.26 no.2
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    • pp.129-135
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    • 2010
  • Geckos have a unique ability to cling to ceilings and walls utilizing dry adhesion. Their foot pads are covered by a large number of small hairs (setae) that contain many branches per seta with a lower level of spatulae. Their fibrillar structure is the primary source of high adhesion. In this study, we construct the adhesion design database for biomimetic adhesive system. A simple idealized fibrillar structure consisting of single array of beams is modeled. The fibers are assumed as oriented cylindrical cantilever beams with spherical tip. We consider three necessary conditions; buckling, fracture and sticking of fiber structure, which constrain the allowed geometry. The adhesion analysis is performed for the attachment system in contact with rough surfaces with different s values for different main design variables-fiber radius, aspect ratio and material elastic modulus and so on. The developed adhesion design databases are useful for understanding biological systems and for guiding of fabrication of the biomimetic attachment system.

Electrical Characteristics of Bottom-Contact Organic Thin-Film-Transistors Inserting Adhesion Layer Fabricated by Vapor Deposition Polymerization and Ti Adhesion Metal Layer

  • Park, Il-Houng;Hyung, Gun-Woo;Choi, Hak-Bum;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.958-961
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    • 2007
  • The electrical characteristics of organic thin-filmtransistor (OTFTs) can be improved by inserting adhesion layer on gate dielectrics. Adhesion layer was used as polymeric adhesion layer deposited on inorganic gate insulators such as silicon dioxide $(SiO_2)$ and it was formed by vapor deposition polymerization (VDP) instead of spin-coating process. The OTFTs obtained the on/off ratio $of{\sim}10^4$, threshold voltage of 1.8V, subthreshold slop of 2.9 V/decade and field effect mobility about $0.01\;cm^2/Vs$.

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