• Title/Summary/Keyword: adhesion of particulate soil

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Adhesion of Soil to Polyester Fabric According to Polarity of Oily Soil in Oily/Particulate Mixed Soil System (지용성/고형오구의 혼합오염 계에서 지용성오구의 극성에 따른 Polyester직물에의 오구부착)

  • Kang, In-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.34 no.7
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    • pp.1175-1183
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    • 2010
  • This study investigates the effect of polarity of oily soil on adhesion of oily and particulate soil to PET fabric in oily/particulate mixed soil systems. The potential energy of interaction between two particles was examined as a fundamental environment of adhesion of soil to fabrics. The ${\zeta}$-potential of ${\alpha}-Fe_2O_3$ particles was measured by a microelectrophoresis method, and the potential energy of interaction between two particles was calculated by using the Verwey-Overbeek theory. The ${\zeta}$-potential of particle and the potential energy of interaction between two particles was slightly influenced by the polarity and type of oily soil, but increased with the increased anionic surfactant concentration and amount of oily soil. The adhesion of oily soil to fabric increased with the additional amount of polarity of oily soil and decreased surfactant concentration that was relatively high at a temperature of $60^{\circ}C$ surfactants solution. The adhesion of ${\alpha}-Fe_2O_3$ particle to PET fabric decreased with an increased amount and polarity of oily soil and increased surfactant concentration Although some similarity exists, the general trend of the adhesion to fabric by particulate soil differ from oily soil.

Detergency of Particulate Soil of PET Fabric Finished with Hydrophilic and Hydrophobic Chemicals (친수 및 소수처리 PET직물의 고형오구의 세척성)

  • Kang, In-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.36 no.11
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    • pp.1237-1245
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    • 2012
  • The effect of hydrophilicity and hydrophobicity of PET fabric on the detergency of particulate soil were investigated as functions of the concentration of hydrophilic and hydrophobic chemicals, surfactant concentration, ionic strength, adhesion and removal time, and pH. The detergency of the particulate soil was determined by the adhesion of particles to and their removal from fabric, the PET fabric and ${\alpha}-Fe_2O_3$ were used as textile materials and for the model of particulate soil, respectively. The hydrophilic and hydrophobic finish for PET fabric was treated with a polyester, silicone and fluorine organic compound of resin respectively. The adhesion of particulate soil to fabric treated with hydrophobic chemicals were slightly higher but its removal from fabric treated with hydrophobic chemicals was largely higher than fabric treated with a hydrophilic chemical regardless of solution conditions such as the concentration of hydrophilic and hydrophobic chemicals, surfactant concentration, ionic strength, adhesion and removal time, and pH. Therefore, hydrophobic treatment for fabric had a more positive effect than the hydrophilic treatment on the detergency of particulate soil.

Detergency of Particulate Soil in Anion/Nonionic Surfactant Mixed Solution (음이온/비이온 혼합 계면활성제 용액에서의 고형오구의 세척성)

  • Kang, In-Sook
    • Fashion & Textile Research Journal
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    • v.13 no.5
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    • pp.790-796
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    • 2011
  • This study was designed to investigate the influence of ratio of anionic/nonionic surfactant mixture on detergency of particulate soil under various solutions. The detergency of the particulate soil was determined by adhesion of particle to fabric and its removal from fabric separately. The PET fabric and ${\alpha}-Fe_2O_3$were used as materials of textile and model of particulate soil, respectively. The detergency was investigated as a function of surfactants concentration, ionic strength, kinds of electrolyte and mole numbers of oxyethylene ether of nonionic surfactant in different ratio of anionic/nonionic surfactant mixture. Although some deviations exist, the adhesion of particle to fabric generally increased with decreasing its removal from fabric. The detergency of particulate soil on PET fabric was relatively higher in anionic/nonionic surfactant mixed solution than in each single surfactant solution, but the influence of ratio of anionic/nonionic surfactant mixture on detergency of particulate soil was low. Generally the detergency of particulate soil on fabric was at its maximum at 0.1% surfactant concentration, $1{\times}10^{-3}$ ionic strength, $Na_5P_3O_{10}$ electrolytes and 10 mole numbers of oxyethylene ether of nonionic surfactant, regardless of ratio of anionic/nonionic surfactant mixture.

Effect of Electrolyte on the Adhesion of Particulate Soil to Fabric in the Surfactant Solution-Adhesion of -$\alpha$-$Fe_2O_3$Particles to PET Fabric- (계면활성제 용액네에서 고형오구의 직물에서의 부착에 영향을 주는 전해질 효과-$\alpha$-$Fe_2O_3$입자의 PET 섬유직물에의 부착-)

  • 강인숙;김병주
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.8
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    • pp.1465-1474
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    • 2001
  • The dispersion stability of particles and the adsorption of surfactant were examined as a fundamental environment to adhesion of particulate soil to fabric. The adsorption of surfactant on the PEF fabrics decreased with the addition of electrolytes and decreased with increasing the ionic strengths showed similar tendency to PET fabric. And the dispersion force of $\alpha$-Fe$_2$O$_3$particles decreased with the addition of electrolyte. The adhesion of particulate soil to fabric, increased with decreasing the adsorption of surfactant the correlation between the two was high at low ionic strength. The correlation between the adsorption of surfactants on $\alpha$-Fe$_2$O$_3$ particles and the adhesion of particles to fabric was smaller as shown in the correlation between the adsorption of surfactants on fiber substrate and the adhesion of particles on fabric. However, the correlation between the adhesion of particles to fabric and the stability of particle dispersion was relatively more significant.

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Influence of Interaction of Surface Charges of PET Fiber and $\alpha$-Fe2O3 Particle on Detergency of Particulate Soil (PET섬유와 $\alpha-Fe_2O_3$ 입자의 표면전하간 상호작용이 고형오구의 세척성에 미치는 영향)

  • 강인숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.8
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    • pp.1132-1140
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    • 1998
  • The adhesion and removal of $\alpha$-Fe2O3 particles on the from PET fabric in NPE solution with different ionic strength were discussed in terms of interaction of surface charge of particle and substrate. The adhesion of $\alpha$-Fe2O3 particles to PET fabric and its removal from PET fabric were carried out by using water bath shaker and Terg-O-Tometer under various solution conditions. The ζ potential of PET fiber and $\alpha$-Fe2O3 particles in the detergent solution were measured by steaming potential and microelectrophoresis methods, respectively. The adhesion and removal amount of $\alpha$-Fe2O3 particles on the from PET fabric increased with increasing time of adhesion and removal, and the rates of adhesion and removal were high at the initial stage of adhesion and removal, and then the rates decreased with passing time. The adhesion and removal amount of $\alpha$-Fe2O3 particles on and from PET fabric increased with increasing pH of solution regardless ionic strength. The tendencies and degree of adhesion and removal were very similar regardless interaction of surface charge of particle and fiber. Therefore, in the presence of a surfactant and electrolyte, the influence of interaction of surface charge of particle and substrate on the detergency of particulate soil was small.

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The Effect of Particle Size on the Detergency of Particulate Soil (고형오구 입자크기가 고형오구의 세척성에 미치는 영향)

  • Mun, Mi-Hwa;Kang, In-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.34 no.4
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    • pp.653-662
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    • 2010
  • This study investigates the effect of particle size on the detergency of particulate soil using an $\alpha-Fe_2O_3$ particle as the model. Monodispersed spherical $\alpha-Fe_2O_3$ particles were prepared by the hydrothermal aging of an acidic $FeCl_3$ and HCl solution. The $\xi$-potential of PET fiber was measured by the streaming potential method. The potential energy of interaction between the particle and fiber was calculated using the heterocoagulation theory for a sphere-plate model. The $\xi$-potential of PET fiber and potential energy of interaction between particles and fiber increased with a decreasing particle size in a DBS solution. However, in the nonionic surfactant solution, the $\xi$-potential signs of PET fiber and $\alpha-Fe_2O_3$ particles were (-) and (+), respectively; there was no repulsive power between the particles and substrate. The adhesion of particles to the fabric increased with increasing particle size in the anionic surfactant solution and their removal from the fabric increased with a decreasing particle size. The adhesion of particles to the fabric and their removal from the fabric was biphasic with a maximum and minimum at 0.1% concentration of the surfactant solution. In the nonionic surfactant solution the adhesion of particles to fabric and their removal from the fabric were greater than the ones in the anionic surfactant DBS solution.