• Title/Summary/Keyword: additive process

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Microstructure and Mechanical Properties of β-SiAlON Ceramics Fabricated Using Self-Propagating High-Temperature Synthesized β-SiAlON Powder

  • Kim, Min-Sung;Go, Shin-Il;Kim, Jin-Myung;Park, Young-Jo;Kim, Ha-Neul;Ko, Jae-Woong;Yun, Jon-Do
    • Journal of the Korean Ceramic Society
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    • v.54 no.4
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    • pp.292-297
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    • 2017
  • ${\beta}-SiAlON$, based on its high fracture toughness, good strength and low abrasion resistance, has been adopted in several industrial fields such as bearings, turbine blades and non-ferrous metal refractories. In general, ${\beta}-SiAlON$ is fabricated by reactive sintering using expensive $Si_3N_4$ and AlN as starting materials. On the other hand, in this study, a cheaper ${\beta}-SiAlON$ starting powder synthesized by SHS was employed to improve price competitiveness compared to that of the reactive sintering process. ${\beta}-SiAlON$ ceramics with various content of the sintering additive $Y_2O_3$ up to 7 wt% were fabricated by conventional pressureless sintering at $1800^{\circ}C$ for 2 to 8 h under $N_2$ pressure of 0.1 MPa. The specimen with 3 wt% $Y_2O_3$ exhibited the best mechanical properties: hardness of 14 GPa, biaxial strength of 830 MPa, fracture toughness of $5MPa{\cdot}m^{1/2}$ and wear rate of about $3{\times}10^{-6}mm^3/N{\cdot}m$.

Water desalination by membrane distillation using PVDF-HFP hollow fiber membranes

  • Garcia-Payo, M.C.;Essalhi, M.;Khayet, M.;Garcia-Fernandez, L.;Charfi, K.;Arafat, H.
    • Membrane and Water Treatment
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    • v.1 no.3
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    • pp.215-230
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    • 2010
  • Poly(vinylidene fluoride-co-hexafluoropropylene), PVDF-HFP, hollow fiber membranes were prepared by the dry/wet spinning technique using different polyethylene glycol (PEG) concentrations as non-solvent additive in the dope solution. Two different PEG concentrations (3 and 5 wt.%). The morphology and structural characteristics of the hollow fiber membranes were studied by means of optical microscopy, scanning electron microscopy, atomic force microscopy (AFM) and void volume fraction. The experimental permeate flux and the salt (NaCl) rejection factor were determined using direct contact membrane distillation (DCMD) process. An increase of the PEG content in the spinning solution resulted in a faster coagulation of the PVDF-HFP copolymer and a transition of the cross-section internal layer structure from a sponge-type structure to a finger-type structure. Pore size, nodule size and roughness parameters of both the internal and external hollow fiber surfaces were determined by AFM. It was observed that both the pore size and roughness of the internal surface of the hollow fibers enhanced with increasing the PEG concentration, whereas no change was observed at the outer surface. The void volume fraction increased with the increase of the PEG content in the spinning solution resulting in a higher DCMD flux and a smaller salt rejection factor.

Recommendable Methods for Effective Improvement of Management System on Organic Materials based on the Analysis of Unintentional Contamination Investigation and Recognition Survey collected from Organic Farmer and so on (유기농업자재중 비의도적 오염원 조사분석 및 친환경농업인 등 인식조사에 근거한 유기농업자재 관리제도의 효율적 개선방안)

  • Ahn, In;Lee, In-Ae;Sim, Mi-Jin
    • Korean Journal of Organic Agriculture
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    • v.23 no.4
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    • pp.659-682
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    • 2015
  • This study was conducted to suggest ideal management system for organic materials. As the performing method of the study, surveyed results on understanding of related persons (organic farmer 846, organic materials manufacture 70 and Organic materials Auditors 7) with eco-friendly farming were used. And the opinion on unintentional pollution source contained in organic materials was surveyed additionally. The issues pointed out by organic farmers on product of organic materials were high price (60% to total), poor efficacy (16%), disorder on distribution system (13%) and containing chemicals as a pesticide (10%). And notification system for organic materials was accepted in general (positive and so so 76%) while most interviewees preferred (89%) unification of certification system dominantly. As unintentional contamination source, pollution on imported row material was indicated as major reason, and other causes were confirmed as insertion during manufacturing process, agricultural by-products using as product additive et al. Based on these surveyed results, authors suggest bellows as considerable methods for effective improvement of management system on organic material. First, establish new integrated certification system which contains standard of quality certification and notification system on organic material. Second, for evaluation of efficacy, apply relative evaluation system of significance such as Duncan's multiple test instead of existing absolute evaluation system. Third, constitute and operate selection of standard comparison subcommittee in organic Agro-materials committee in RDA.

Effects of Y2O3 Addition on Densification and Thermal Conductivity of AlN Ceramics During Spark Plasma Sintering (Y2O3 첨가가 AlN 세라믹스의 방전 플라즈마 소결 거동 및 열전도도에 미치는 영향)

  • Chae, Jae-Hong;Park, Joo-Seok;Ahn, Jong-Pil;Kim, Kyoung-Hun;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.827-831
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    • 2008
  • Spark plasma sintering (SPS) of AlN ceramics were carried out with ${Y_2}{O_3}$ as sintering additive at a sintering temperature $1,550{\sim}1,700^{\circ}C$. The effect of ${Y_2}{O_3}$ addition on sintering behavior and thermal conductivity of AlN ceramics was studied. ${Y_2}{O_3}$ added AlN showed higher densification rate than pure AlN noticeably, but the formation of yttrium aluminates phases by the solid-state reaction of ${Y_2}{O_3}$ and ${Al_2}{O_3}$ existed on AlN surface could delay the densification during the sintering process. The thermal conductivity of AlN specimens was promoted by the addition of ${Y_2}{O_3}$ up to 3 wt% in spite of the formation of YAG secondary phase in AlN grain boundaries because ${Y_2}{O_3}$ addition could reduced the oxygen contents in AlN lattice which is primary factor of thermal conductivity. However, the thermal conductivity rather decreased over 3 wt% addition because an immoderate formation of YAG phases in grain boundary could decrease thermal conductivity by a phonon scattering surpassing the contribution of ${Y_2}{O_3}$ addition.

Solubillzation and Extraction Of Antioxidant Astaxanthin by Micelle Formation from Phaffia rhodozyma Cell Homogenate (Phaffia rhodozyma 세포파쇄액으로부터 항산화제 Astaxanthin의 미셀 형성을 통한 가용화 및 추출)

  • Kim, Young-Beom;Ryu, Kang;Lim, Gio-Bin;Lee, Eun-Kyu
    • KSBB Journal
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    • v.17 no.2
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    • pp.176-181
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    • 2002
  • Astaxanthin (3,3'-dihydroxy-${\beta}$, ${\beta}$-carotene-4-4'-dione), a natural pigment of pink to red color, is widely distributed in nature particularly in the skin layer of salmonoids and the crust of shrimp, lobster, etc. Recently, it was produced from the yeast culture of Phaffia rhodozyma. Because of its high thermal stability and antioxidant functionality, its applications can be extended into food, cosmetics, and pharmaceutical ingredient beyond the traditional feed additive. Because of its very high lipophilicity, astaxanthin has been extracted traditionally by strong organic solvents such as chloroform, petroleum ether, acetone, etc. In this study, we developed a surfactant-based solubillization system for astaxanthin, and used it to extract astaxanthin from disrupted yeast cells. Among Tween 20, Triton X-100 and SDS, Tween 20 was identified as the most suitable surfactant in terms of extraction capacity and safety. The ethylene oxide group of Tween 20 was identified as the most significant factor to increase the HLB value that determined the extraction capacity. The effects of micelle formation condition, such as the molar ratio of astaxanthin and Tween 20, pH, and ionic strength were also investigated. pH and ionic strength showed no significant effects. The optimal molar ratio between astaxanthin and Tween 20 was 1 : 12. Antioxidant activity of astaxanthin was higher than ${\beta}$-carotene and ${\alpha}$-tocopherol. Astaxanthin in the crude extract from the yeast cell was more resistant to air and/or light degradation than pure astaxanthin, probably because of the presence of other carotenoids and lipids.

Development of a Voluntary Hazard Assessment Model for Small- and Medium-Sized Ship-building Plants (중소규모 조선업 사업장을 위한 자율 위험성 평가 모델의 개발)

  • Lim, Hyeon-Kyo;Lee, Kyung-Tae;Bae, Dong-Chul;Chang, Seong-Rok
    • Journal of the Korean Society of Safety
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    • v.26 no.2
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    • pp.70-76
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    • 2011
  • Industrial accident frequency in small- and medium-sized ship-building plants is much higher than that of large-sized ones so that safety management activities should be different. In that sense, voluntary hazard assessment would be helpful for small- and medium-sized plants. However, conventional hazard assessment items and methods had some problems that discouraged voluntary participation of plants concerned. This study aimed to develop a new model for small- and medium-sized ship-building plants that can promote and encourage voluntary hazard assessment activities. For that purpose, ship-building process was assumed as a sequence of phases, and accident characteristics were compared with them. From that result, relative weights of accident factors including ship-building phases, accident types, occupational category, accident-induced objects, and hazardous items were determined with accident frequency data and with the help of expert groups. Therefore, for web-based integrative computer programming, a plain but accident data-dependent model was developed, with an additive function for related agencies that want to collect assessment results. It is expected that this model would help small- and medium-sized ship-building plants that wanted not only simple checklists but also effective assessment and management guidelines.

A Study on Nonlinear Filter for Removal of Complex Noise (복합잡음 제거를 위한 비선형필터에 관한 연구)

  • Lee, Kyung-Hyo;Ryu, Ji-Goo;Kim, Nam-Ho
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.10a
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    • pp.455-458
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    • 2008
  • Former times Information Technology generally has only depended on text or sound, while nowadays information is being moved through a variety of image media. Cell phone, TV and computer have been major elements of modem society as mediators using image signal. Therefore, image signal processing also has been treated importantly and done actively. The processing has been developed in many fields of digital image processing technologies as image data compression, recognition, restoration, etc. Noises are inevitably generated by using the signals during the processing, and typical types of the noise are Impulse(salt & pepper) and AWGN(Addiction White Gaussian Noise). To reduce the noise, various kinds of filters have been developed, and according to each noise, it is being used different filter each. However, the noise is not generated by one signal but by a complex. In this paper, I suggested an image filter to remove the complex noise, and compared with existing filters' methods for verification.

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Effect of Heat Capacity of Coagulant on Morphology of PVDF-Silica Mixture Through TIPS Process for the Application of Porous Membrane (다공성 분리막으로 응용을 위한 PVDF-실리카 혼합물의 응고액 열용량 변화에 따른 모폴로지 변화)

  • Lee, Jeong Woo;Nam, Sang Yong
    • Membrane Journal
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    • v.27 no.5
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    • pp.458-467
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    • 2017
  • In this study, we prepared PVDF membranes via TIPS for water treatment applications. PVDF was used for its excellent chemical and mechanical properties. The effect of coagulation bath composition, temperature, and heat capacity on the overall membrane morphology was studied and observed using SEM. A mixture of DOP and DBP was used as the diluent, and silica was used as an additive. It was observed that as the heat capacity of the coagulation bath increased, the crystallization rate of PVDF decreased yielding larger pores. Also, as the heat capacity of the coagulation bath decreased, the crystallization rate of PVDF increased yielding smaller pores.

State-of-the-art of Life Cycle Assessment for Biodiesel Production from Plant Biomass (식물성 바이오매스로부터 바이오디젤 생산에 대한 LCA 연구 현황)

  • Seo, Bong-Kuk;Song, Seung-Koo
    • KSBB Journal
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    • v.25 no.1
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    • pp.1-10
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    • 2010
  • Biodiesel is a type of biofuel obtained from bioresources and able to use in diesel vehicles as an alternative/additive to petro diesel. In recent biodiesel research, there are three main issues which include high quality biodiesel, low cost feed stock and a highly efficient biodiesel production process. The sustainable production and use of biodiesel are attracting much attention in the renewable energy field. In this paper, we review some of the literatures related to environmental and economic evaluation for biodiesel production and analysis the issues including life cycle assessment (LCA), global warming potential (GWP), energy consumption, biodiesel production cost, production technologies and feedstock.

Development of Ready-mixed Shotcrete I : Basic Study (레디믹스트 숏크리트 개발 I : 기초 연구)

  • Kim, Dong-Min;Ma, Sang-Joon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.5C
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    • pp.171-185
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    • 2011
  • Ready-mixed shotcrete that mixed with high quality aggregate and can improve construction quality is produced in a dry mortar plant and transported to construction sites. Because of using aggregate that produced in a special plant, Ready-mixed shotcrete has many advantages : good grain-size distribution, minimum stone powder, high quality and standardization material, etc. In this basic study different from the existing study that limited to additive and accelerator, the improvement of aggregate quality was tried to upgrade the shotcrete performance. The investigation about the construction conditions of shotcrete was performed and the result of an opinion poll was analyzed for a good grasp of the problems in domestic shotcrete quality. Pilot Plant Test was also performed to minimize the material segregation in plant manufacturing process. In additions, the field test was performed to find the optimum contents of synthetic fiber, appearing the same flexible toughness with that of steel fiber, and to find the optimum replacement ratio of blast furnace slag.