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A Study on Property Change of Acrylic Rubber by Selected Monomers and Crosslinking Agent (선택된 단량체와 가교제에 의한 아크릴고무의 물성 변화에 관한 연구)

  • Kim, Jun-Ho;Cho, Ur-Ryong
    • Elastomers and Composites
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    • v.47 no.1
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    • pp.75-81
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    • 2012
  • Acrylic rubber was synthesized using ethyl acrylate. butyl acrylate, methoxyethyl acrylate as main monomers and glycidyl methacrylate as cure site monomer by emulsion polymerization. Rubber compound was made by adding 2,2-bis[4-(4-aminophenoxy)phenyl]propane as crosslinking agent. Increase of ethyl acrylate content in the main monomer ratio resulted in enhancement of heat resistance due to decrease of glass transition temperature in acrylic rubber. And also oil resistance was increased with increasing content of ethyl acrylate because ethyl acrylate has the highest ester concentration in the three main monomers. With content of 2,2-bis[4-(4-aminophenoxy)phenyl]propane, both tensile strength and elongation were increased until 2 phr, but in higher content than that, they decreased owing to reduction of viscosity and elongation by increase of crosslinking density.

A Narrowband Detection Performance for Small Objects on Seabed by the Active Synthetic Aperture Sonar (능동 합성개구면소나에 의한 해저 소형물체 협대역 탐지 성능 고찰)

  • Kim, Boo-Il
    • Journal of the Korea Society for Simulation
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    • v.23 no.4
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    • pp.41-49
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    • 2014
  • Detection and processing techniques for small objects on seabed by the active synthetic aperture sonar can be increased the detection performance because it can be used by short sensor array in small unmanned underwater systems that are spatially constrained. But the limited conditions on constant speed and straight movement of the platform cause a large error in the number of external environmental factors and exact phase synthesis process. In this study, analyzed the applicability of active synthetic aperture processing that is mounted on such a system, and compared detection resolution change in accordance with the phase difference mismatch caused by the along track disturbance. Various simulations were performed as a coherently focus processing model by adding along track disturbance mismatched parameter on the configuring simulator. As the result, detection performance of active synthetic processing for small objects on seabed was found a number of changes by the phase difference mismatch errors according to track disturbances and S/N ratio variations.

The Research about Successful Apparel Products in Internet Shopping-mall -Focusing on F/W products- (의류 상품에 인터넷 쇼핑몰 성공 제품에 관한 조사 연구 -F/W 상품을 중심으로-)

  • Kim Seon-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.9_10 s.146
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    • pp.1349-1358
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    • 2005
  • Generally apparel products were recognized as an incongruent product type which direct search was needed for. But nowadays apparel products were ranked as a second product type next to electronics in sale amount of internet shopping mall. Therefore more detailed study on which attributes of fashion products are more successful and suitable in internet shopping mall is necessary. This study was executed to analyze common attributes of successful apparel in internet shopping mall on the basis of real sale data, and then to help internet apparel marketer plan marketing strategies more efficiently. Common attributes of successful apparel products in internet shopping-mall in terms of product, price and promotion attributes were identified. 240 products which were loaded in bestseller section of internet shopping-mall for 8 weeks from November to December, 2004 were analyzed. The results are as follows. First, products ratio for women ($76.7\%$) were higher than for men($18.3\%$). And the amount of each apparel product types purchased by consumers were ranked in the order of leather/fur coat, woven coat, inner wear, jacket, T-shirts, pants, training wear, suit, knit wear etc. and basic style dominated in $74.2\%$. General brands ($69.2\%$) that had price competitiveness were preferred to famous designer brand, national brand and PB brand. Preferred level of price was ten thousand to fifty thousand won. For promotion skill, in order of just one product, product adding promotion product and package set were preferred. Regular price, less than $50\%$ off and more than $50\%$ off price showed no difference in preference. Product planning strategy for internet apparel marketer was followed on the basis of these results.

Effects of the Structure of Weight Loss Accelerating Agents on the Weight Loss in Alkaline Hydrolysis of PET Fibers (감량촉진제의 구조에 따른 PET섬유의 감량가공효과)

  • Chun, Dong-Woo;Kim, Seung-Jin;Keun, Jang-Hyoun;Park, Hong-Soo
    • Applied Chemistry for Engineering
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    • v.5 no.1
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    • pp.63-73
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    • 1994
  • Weight loss accelerating agents, TDACW and TTAMW were prepared by adding water to n-tetradecyldimethylbenzylammonium chloride(TDAC) and n-tetradecyltrimethylammonium methyl sulfate(TTAM) synthesized in our lab. On weight loss finishing of PET fiber with NaOH and TDACW or TTAMW, TDACW showed much more weight loss than TTAMW. Optimum concentration was about $8g/{\ell}$, treatment time 60~90min and treatment bath ratio 1:40~1:50. Density and crystallinity increased with weight loss and tensile strength decreased with weight loss. From the reaction mechanism of weight loss accelerating agent and PET fiber, weight loss accelerating agent was proved to function as a catalyst and the surface structures of PET fibers treated with weight loss accelerating agent were characterized with SEM.

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Research on Characteristics of Multifunctional Soil Binder Based on Polyacrylamide (폴리아크릴아마이드를 기반으로 하는 다기능성 토양안정제의 특성에 관한 연구)

  • Kim, Jin Kyung;Kim, Dae Ho;Joo, Sang Hyun;Lee, Myung Cheon
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.155-161
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    • 2018
  • For the efficient recovering of collapsed sloped soil, using a soil binder that can support the soil strongly and help the growth of plants is very important. The soil binder should also have functions of recovering the soil ecologically as well as be environmental friendly materials. In this research, optimum values of the water content and permeability and direct shear strength were searched by adding the water absorbent and coagulant into the soil binder. The polyacrylamide (PAM) with various anionic strength, super absorbent polymer (SAP) and cellulose ether (CE) were used as a soil binder, water absorbent and coagulant, respectively. Effects of the soil binder on the characteristics of soil were observed by changing the mixing ratio of PAM, SAP and CE. Experimental results showed that the soil binder increased the direct shear strength tens of times and the water content around two times, whereas decreased the water permeability. Also, the addition of CE to increase the coagulation of SAP increased more of the direct shear strength and water content.

Reactive ion etching of InP using $Cl_2/CH_4/H_2$ discharges ($Cl_2/CH_4/H_2$ 혼합기체를 이용한 InP 소재의 반응성 이온 에칭에 관한 연구)

  • 최익수;이병택;김동근;박종삼
    • Journal of the Korean Vacuum Society
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    • v.6 no.3
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    • pp.282-286
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    • 1997
  • Reactive ion etching (RIE) characteristics of InP in the $Cl_2$/ CH_4/H_2$ discharges was investigated, as a function of the rf power, substrate temperature and gas composition. It was observed that the etch rate increased as the rf power, sample temperature and/or $Cl_2$ gas concentration increased. Etch rate of about 0.9$\mu\textrm{m}$/min was obtained at the optimum condition of 150W rf power, $180^{\circ}C$ substrate temperature and $10Cl_2$ /$5CH_4/85H_2$ gas ratio. Polymer formation was completely suppressed by adding $Cl_2$ to the $CH_4$ /$H_2$ discharges.

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Quality Characteristics of Vinegar Added with Different Levels of Black Garlic (흑마늘의 첨가량을 달리한 식초의 품질특성)

  • Sim, Hye Jin;Seo, Weon Taek;Choi, Myoung Hyo;Kim, Kyoung Hwa;Shin, Jung Hye;Kang, Min Jung
    • Korean journal of food and cookery science
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    • v.32 no.1
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    • pp.16-26
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    • 2016
  • In this study, we aimed to develop functional vinegar with different levels of black garlic through two stages of fermentation. Black garlic vinegars were prepared from black garlic and water (w/w) mixed with 1:2 (BG3), 1:5 (BG6), 1:9 (BG9) and 1:11 (BG12), and adding the sugar by adjusting the soluble solids content to $14^{\circ}Brix$. The alcohol content of black garlic vinegar was 5.2-5.5% after 7 days of alcohol fermentation at $25^{\circ}C$. Acetic acid fermented was at $30^{\circ}C$ for 25 days and samples were taken at 3, 6, 9, 12, 15, 20 and 25 days. The pH of black garlic vinegar was not significantly different among the samples, but acidity was increased during fermentation. Total polyphenol contents showed irregular changes with the fermentation periods and were higher by black garlic content. At 25 days fermentation, total polyphenol contents were 18.96-56.56 mg/100 mL. Acetic acid content of black garlic vinegars was higher than other organic acids. S-allyl cysteine (SAC) contents of BG3 and BG6 were 13.03-14.54 and 1.69-2.20 mg/L, respectively. However SAC was not detected in BG9 and BG12. In 25 days fermented black garlic vinegar, the major mineral was K with a content ratio of 61-68% of total minerals. The DPPH and ABTS radical scavenging activity of 25 days fermented black garlic vinegar were stronger at higher black garlic content.

A Study of Numerical Analysis on Mixed Combustion Characteristics in a Gasoline Direct Injection Engine with Premixed Hydrogen (수소 예혼합 가솔린 직접분사 엔진의 혼소특성에 관한 수치해석 연구)

  • Bae, Jaeok;Choi, Minsu;Suh, Hyunuk;Jeon, Chunghwan
    • Journal of Hydrogen and New Energy
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    • v.24 no.6
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    • pp.524-534
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    • 2013
  • Gasoline direct injection(GDI) engine has a high thermal efficiency, but it has a problem to increase carbon emissions such as soot and $CO_x$. In this study, the objective is to analyze numerically a problem for adding the hydrogen during the intake stroke so as to reduce the injected amount of gasoline in GDI engines. For selection of the base model, the cylinder pressure of simulation is matched to experimental data. The numerical analysis are carried out by a CFD model with the hydrogen addition of 2%, 3% and 4% on the volume basis. In the case of 3% hydrogen addition, the injected gasoline amount is only changed to match the maximum pressure of simulation to that of the base model for additional study. It is found that the combustion temperature and pressure increase with the hydrogen addition. And NO emission also increases because of the higher combustion temperature. $CO_x$ emissions, however, are reduced due to the decrease of injected gasoline amount. Also, as the injected gasoline amount is reduced for the same hydrogen addition ratio, the gross indicated work is no significant, But NO and $CO_x$ emissions are considerably decreased. On the order hand, $CO_x$ emissions of two cases are more decreased and their gross indicated works are higher obtained than those of the base model.

Generic optimization, energy analysis, and seismic response study for MSCSS with rubber bearings

  • Fan, Buqiao;Zhang, Xun'an;Abdulhadi, Mustapha;Wang, Zhihao
    • Earthquakes and Structures
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    • v.19 no.5
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    • pp.347-359
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    • 2020
  • The Mega-Sub Controlled Structure System (MSCSS), an innovative vibration passive control system for building structures, is improved by adding lead rubber bearings (LRBs) on top of the substructure. For the new system, a genetic algorithm is used to optimize the dynamic parameters and distributions of dampers and LRBs. The program uses various seismic performance indicators as optimization objectives, and corresponding results are compared. It is found that the optimization procedure for maximizing the energy dissipation ratio yields the best solutions, and optimized models have consistent seismic performances under different earthquakes. Seismic performances of optimized MSCSS models with and without LRBs, as well as the traditional Mega-Sub Structure model, are evaluated and compared under El Centro wave, Taft wave and 20 other artificial waves. In both elastic and plastic analysis, the model with LRBs shows significantly smaller story drift and horizontal acceleration than those of the other two models, and fewer plastic hinges are developed during severe earthquakes. Energy analysis also shows that LRBs installed in proper locations increase the deformation and energy dissipation of dampers, thereby significantly reduce the kinetic, potential, and hysteretic energy in the structure. However, LRBs do not have to be mounted on all the additional columns. It is also demonstrated that LRBs at unfavorable locations can decrease the energy dissipation for dampers. After LRBs are installed, the optimal damping coefficient and the optimal damping exponent of dampers are reduced to produce the best damping effect.

Effect of Enrobing and Adding Antioxidants on the Quality of Pork Patties

  • Biswas, A.K.;Keshri, R.C.;Kumar, Sunil
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.9
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    • pp.1374-1383
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    • 2003
  • The effect of applying edible coating and addition of antioxidants (butylated hydroxyanisole (BHA) plus butylated hydroxytoluene (BHT) in a 1:1 ratio) on pork patties were investigated prior to achieve desired physico-chemical, microbiological and sensory qualities. For this, five treatments were conducted as (i) control (neither coated nor antioxidants treated); (ii) coated without antioxidants treated; (iii) coated and antioxidants added in the batter mix only (100 ppm); (iv) coated and antioxidants added in meat mix (100 ppm) only; and (v) coated and antioxidants added both in the batter mix (50 ppm) and the meat mix (50 ppm). Addition of antioxidants both in the batter mix and the meat mix significantly (p<0.05) reduced the microbial loads and thiobarbituric acid (TBA) values. The TBA values significantly (p<0.05) increased up to day 14 and then progressively increased with the advancement of each interval of storage days up to 28 days. Total plate count significantly (p<0.05) increased with the increase in storage days.Coliform and Staphylococcus aureus were absent throughout the storage days in all samples. Staphylococcus aureus however, were present in the control group at day 14 and in enrobed (coated) patties (without antioxidants treated) at 28th day. Addition of antioxidants to batter mix and meat mix did not substantially enhance bacteriostatic activity. Application of coatings and antioxidants retarded the loss of firmness, flavor, changes in appearance and color, and also other sensory attributes. Control patties were better with respect to microbial quality and TBA values but had poorer sensory quality than coated patties.