• Title/Summary/Keyword: active surface

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Design of a Plasmonic Switch Using Ultrathin Chalcogenide Phase-change Material

  • Lee, Seung-Yeol
    • Current Optics and Photonics
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    • v.1 no.3
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    • pp.239-246
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    • 2017
  • A compact plasmonic switching scheme, based on the phase change of a thin-film chalcogenide material ($Ge_2Sb_2Te_5$), is proposed and numerically investigated at optical-communication wavelengths. Surface plasmon polariton modal analysis is conducted for various thicknesses of dielectric and phase-change material layers, and the optimized condition is induced by finding the region of interest that shows a high extinction ratio of surface plasmon polariton modes before and after the phase transition. Full electromagnetic simulations show that multiple reflections inside the active region may conditionally increase the overall efficiency of the on/off ratio at a specific length of the active region. However, it is shown that the optimized geometrical condition, which shows generally large on/off ratio for any length of active region, can be distinguished by observing the multiple-reflection characteristic inside the active region. The proposed scheme shows an on/off switching ratio greater than 30 dB for a length of a few micrometers, which can be potentially applied to integrated active plasmonic systems.

Preparation and Surface-Active Properties of Vinyl Acetate Cotelomers (I) (비닐아세테이트 코텔로머의 제조 및 계면활성(I))

  • Lee, Eon-Pil;Kang, Se-Mi;Hwang, Dae-Youn;Jung, Young-Jin;Choi, Hae-Wook;Choi, Young-Ho;Lee, Jae-Ho
    • Fashion & Textile Research Journal
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    • v.14 no.4
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    • pp.677-683
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    • 2012
  • 1-octanethiol and vinyl acetate telomers ($R_8S$-nVAc) were synthesized and hydrolyzed with sodium hydroxide subsequently, 1.2-epoxyhexane was then introduced to the telomers. In addition, we prepared cotelomers of multi-alkylated nonionic surfactants with a molecular structure of xRnMA-yVA (x; hydrophobic group, y; hydrophilic group, MA; methacrylic ester, VA; vinyl alcohol, R; and alkyl group) and cross-linked with sodium tetraborate decahydrate. Their active surface properties were investigated by several techniques such as surface tension, foaming property, and emulsification power measurements. The surface tension of $R_8S$-8.8VA decreased without the introduction of 1.2-Epoxy hexane, and the degree of emulsification and foaming abilities of $R_8S$-8.8VA increased without the introduction of 1.2-Epoxy hexane. However, the differences were insignificant. The epoxy groups were attached to a $R_8S$-8.8VA cotelomer with a limited variation of the active surface properties. The surface tension of $1.1R_6MA$-8.8VA decreased after cross-linking subsequently, the degree of emulsification and foaming abilities of $1.1R_6MA$-8.8VA increased after cross-linking. However, there was no clear difference between them. The B-O bonds were attached to a $1.1R_6MA$-8.8VA cotelomer with a limited variation of the active surface properties.

Active Earth Pressure behind Rigid Retaining Wall Rotating about the Base (저점을 중심으로 회전하는 강성옹벽에 작용하는 주동토압)

  • 백규호
    • Journal of the Korean Geotechnical Society
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    • v.20 no.8
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    • pp.193-203
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    • 2004
  • Arching effects in backfill materials generate a nonlinear active earth pressure distribution on a rigid retaining wall with rough face, and arching effects on the shape of the nonlinear earth pressure distribution depends on the mode of wall movement. Therefore, the practical shape of failure surface and arching effect in the backfill changed with the mode of wall movement must be considered to calculate accurate magnitude and distribution of active earth pressure on the rigid wall. In this study, a new formulation for calculating the active earth pressure on a rough rigid retaining wall rotating about the base is proposed by considering the shape of nonlinear failure surface and arching effects in the backfill. In order to avoid mathematical complexities in the calculation of active earth pressure, the imaginary failure surface composed of four linear surfaces is used instead of the nonlinear failure surface as failure surface of backfills. The comparisons between predictions from the proposed equations and existing model test results show that the proposed equations produce satisfactory predictions.

Distribution of Fault-related Landforms and Lineaments Along the Ulsan Fault Zone (울산단층대 주변의 단층 지형 및 선구조 분포)

  • Lee, Gwang-Ryul;Park, Chung-Sun;Shin, Jae-Ryul
    • Journal of The Geomorphological Association of Korea
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    • v.25 no.3
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    • pp.89-103
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    • 2018
  • This study presents results of analysis on fault-related landforms and the Quaternary fluvial landforms, which are important evidences for active faulting by identifying surface deformation, around the Ulsan Fault Zone. In addition, this study suggests lineament map and inferred active fault-line map based on analyzing linearity and continuity of these landforms and by compiling location information of existing active faults. We convince that quantitative tectonic-geomorphological analysis are an effective method for active faults tracking, in particular, considering the conditions of relatively low seismicity and surface ruptured-events in the Korean Peninsula compared to plate boundary active areas. However, research on active fault in South Korea is just an infant stage since the 1990s and requires accumulation of research achievements on development and application of various fault analysis techniques, analysing and standardizing linear structures.

A Study on the Current-Voltage Characteristics of Self-Assembled Organic Molecules by using STM

  • Kim Seung-Un;Shin Hoon-Kyu;Kwon Young-Soo
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.3
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    • pp.115-118
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    • 2005
  • Currently, molecular devices are reported utilizing active self-assembled monolayers (SAMs) containing the nitro group as the active component, which has active redox centers [1]. SAMs are ordered molecular structures formed by the adsorption of an active surfactant on a solid surface. The molecules will be spontaneously oriented toward the substrate surface and form an energetically favorable ordered layer. During this process, the surface-active head group of the molecule chemically reacts with and chemisorbs onto the substrate In this paper, the electrical properties of the 4'4- di(ethynylphenyl)-2'-nitro-1-benzenethiolate was confirmed. This material is well known as a conducting molecule having possible application to molecular level negative differential resistance (NDR) device. To deposit the self-assembly monolayers onto the gold electrode, the prefabricated Au(1 l l) substrates were immersed into 0.5[mM/l] self-assembly molecule in THF solution. Then, the electrical properties and surface morphologies of 4' 4-di(ethynylphenyl)-2' -nitro-1-benzenethiolate were measured by using the ultra-high vacuum scanning tunneling microscopy (UHV-STM).

Influence of Interface Active substances(Ionic and Amphoteric) on Chemical property and Streaming Electrification of Transformer Oil (이온성 및 양성 계면 활성제가 변압기유의 화학적 특성 및 유동대전에 미치는 영향)

  • 김용운;이덕출
    • Electrical & Electronic Materials
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    • v.10 no.7
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    • pp.719-726
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    • 1997
  • This research was conducted to analyze the change of surface tension, viscosity, streaming current and conductivity of transformer oil when it were injected with the interface active substances.(anionic:S-111, cationic:S-121, amphoteric:S-131) The changes properties of the surface tension and viscosity of the oil which were injected with the interface active substances were divided into the changes area and the minimum reduction area. The surface tension and viscosity of the oil which were injected with three different kinds of interface active substances showed remarkable change at the point where the concentration of the substance in anionic, in cationic and in amphoteric were 100[ppm], 10[ppm] and 1[ppm] respectively. The streaming current and conductivity of the same sample oil were also changed at the same densities of the surface tension and viscosity. For this factor, it was possibile for us to interpret the mechanism of the streaming current and conductivity. Therefore the interface active substances of the three kinds were injected into the oil within the limit of optimal volume, prevention effects of electrification were showed more excellence than unmixed insulating oil.

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Enhancement of Common-path Fourier-domain Optical Coherence Tomography using Active Surface Tracking Algorithm (표면 추적 알고리즘을 적용한 공통경로 FD-OCT의 성능개선)

  • Kim, Min-Ho;Kim, Keo-Sik;Song, Chul-Gyu
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.4
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    • pp.639-642
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    • 2012
  • Optical coherence tomography(OCT) can provide real-time and non-invasive subsurface imaging with ultra-high resolution of micrometer scale. However, conventional OCT systems generally have a limited imaging depth range within a depth of only 1-2 mm. To overcome the limitation, we have proposed an active surface tracking algorithm used in common-path Fourier-domain OCT system in order to extend the imaging depth range. The surface tracking algorithm based on the threshold and Savitzky-Golay filter of A-scan data was applied to real-time tracking. The algorithm has controlled a moving stage according to the sample's surface variance in real time. An OCT image obtained by the algorithm clearly show an extended imaging depth range. Consequently, the proposed algorithm demonstrated the potential for improving the conventional OCT systems with limitary depth range.

Electrocatalytic activity of carbon-supported near-surface alloys (NSAs) for electrode reaction of fuel cell (연료전지 전극 반응을 위한 카본 담지 표면 합금의 전기촉매 활성)

  • Park, In-Su;Sung, Yung-Eun
    • New & Renewable Energy
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    • v.2 no.4 s.8
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    • pp.64-69
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    • 2006
  • There is a worldwide interest in the development and commercialization of polymer electrolyte membrane fuel cells [PEMFCs] for vehicular and stationary applications. One of the major objectives is the reduction of loaded electrode materials, which is comprise of the Pt-based noble metals. In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the supporting of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled active materials were formed on the surface of carbon-supported Au nanoparticles. The structural and electrochemical analyses indicate that the active materials were deposited on the surface of Au nanoparticles selectively and that an alloying process occurred during the successive reducing process. The carbon-supported & surface-alloys showed the higher electrocatalytic activity than those of the particle-alloys and commercial one [Johnson-Matthey] for the reaction of methanol and formic acid oxidation. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

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Electrocatalytic activity of Carbon-supported near-surface alloys (NSAs) for Electode reaction of Fuel cell (연료전지 전극 반응을 위한 카본 담지 표면 합금의 전기촉매 활성)

  • Park, In-Su;Lee, Kug-Seung;Choi, Baeck-Beom;Sung, Yung-Eun
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.316-319
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    • 2006
  • There is a worldwide interest in the development and commercialization of Polymer Electrolyte Membrane Fuel Cells (PEMFCs) for vehicular and stationary applications. One of the major objectives is the reduction of loaded electrode materials, which is comprise of the Pt-based noble metals. In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the deposition of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled active materials were formed on the surface of carbon-supported Au nanoparticles. The structural and electrochemical analyses indicate that the active materials were deposited on the surface of Au nanoparticles selectively and that an at toying process occurred during the successive reducing process The carbon-supported & surface-alloys showed the higher electrocatalytic activity than those of the particle-alloys and commercial one (Johnson-Matthey) for the reaction of methanol and formic acid oxidation. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

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Multichannel Analysis of Surface Waves (MASW) Active and Passive Methods

  • Park, Choon-Byong
    • 한국지구물리탐사학회:학술대회논문집
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    • 2006.06a
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    • pp.17-22
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    • 2006
  • Shear modulus is directly linked to material's stiffness and is one of the most critical engineering parameters. Seismically, shear-wave velocity (Vs) is its best indicator. Although methods like refraction, down-hole, and cross-hole shear-wave surveys can be used, they are generally known to be tougher than any other seismic methods in field operation, data analysis, and overall cost. On the other hand, surface waves, commonly known as ground roll, are always generated in all seismic surveys with the strongest energy, and their propagation velocities are mainly determined by Vs of the medium. Furthermore, sampling depth of a particular frequency component of surface waves is in direct proportion to its wavelength and this property makes the surface wave velocity frequency dependent, i.e., dispersive. The multichannel analysis of surface waves (MASW) method tries to utilize this dispersion property of surface waves for the purpose of Vs profiling in 1-D (depth) or 2-D (depth and surface location) format. The active MASW method generates surface waves actively by using an impact source like sledgehammer, whereas the passive method utilizes those generated passively by cultural (e.g., traffic) or natural (e.g., thunder and tidal motion) activities. Investigation depth is usually shallower than 30 m with the active method, whereas it can reach a few hundred meters with the passive method. Overall procedures with both methods are briefly described.

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