• Title/Summary/Keyword: active surface

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AN INVERSION METHOD FOR DERIVING PHYSICAL PROPERTIES OF A SUBSURFACE MAGNETIC FIELD FROM SURFACE MAGNETIC FIELD EVOLUTION I. APPLICATION TO SIMULATED DATA

  • Magara, Tetsuya
    • Journal of The Korean Astronomical Society
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    • v.50 no.6
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    • pp.179-184
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    • 2017
  • We present a new method for solving an inverse problem of flux emergence which transports subsurface magnetic flux from an inaccessible interior to the surface where magnetic structures may be observed to form, such as solar active regions. To make a quantitative evaluation of magnetic structures having various characteristics, we derive physical properties of subsurface magnetic field that characterize those structures formed through flux emergence. The derivation is performed by inversion from an evolutionary relation between two observables obtained at the surface, emerged magnetic flux and injected magnetic helicity, the former of which provides scale information while the latter represents the configuration of magnetic field.

Actively controlled sound field of upper sections attached to noise harriers (방음벽 상단 소음의 회절에 관한 능동제어)

  • Koh, Hyo-In;Moser, Michael
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2004.11a
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    • pp.482-485
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    • 2004
  • On the basis of theoretical studies on the effect of the cylinders attached to semi-infinite screens, the tangential sound power-transport parallel to the surface of the attached cylinder is minimized by means of a secondary sound field, which is generated from a part of the attached cylinder. The numerical study shows the possibility of deflecting the incident sound by minimizing the acoustic surface impedance of the upper sections. The acoustical shadow region was more pronounced in both near- and far-field compared to the passive case with rigid surface, i.e. without active control. For a relatively wide frequency range it was possible to enhance shielding effects only with few secondary sources and error microphones. In this paper effects of some control parameters on the actively controlled sound field near the top edge of noise barriers are studied. Results of numerical study and model measurements are shown and discussed.

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A Synthesis and Surface-Active Characteristics of Oligomer Type Anionic Surfactants with Fluorescent Structure (형광구조를 갖는 올리고머형 음이온성 계면활성제의 합성 및 계면성)

  • Park, Seon-Young;Kim, Sang-Chun;Jeong, Hwan-Kyeng;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.2
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    • pp.86-96
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    • 2002
  • Oligomer type anionic surfactants(RmM-Na or RmD-Na} were synthesized from $C_{8}{\sim}C_{16}$ long chain alkylvinylether and maleic anhydride (or maleic diethylether). And also their fluorescent anionic surfactants (RmF- Na) were obtained from alkali neutralization which opens the lactone ring of the condensing materials produced by maleic anhydride alkylvinylether copolymer and 3-aminophenol. The measurement results for the surface active properties of water soluble oligomer type anionic surfactants with fluorescent structure (RmF-Na) exhibited a remarkable surface tension lowing property, foam breaking property, and a ernulsing power.

Hygroscopic Characteristic of Gypsum Boards Using Porous Materials (다공성 원료를 사용한 석고보드의 흡습 특성)

  • Jeong, Eui-Jong;Lee, Jong-Kyu;Cheong, Deock-Soo;Chu, Yong-Sik;Song, Hun
    • Korean Journal of Materials Research
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    • v.19 no.10
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    • pp.538-543
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    • 2009
  • Active clays, Diatomite, bentonite and zeolite were used as porous materials for fabricating hygroscopic gypsum boards. Pohang active clay and Cheolwon diatomite showed excellent characteristics of moisture adsorption and desorption. These characteristics were caused by higher surface area and pore volume of porous materials. Moisture adsorption content of gypsum board with 10% active clay(P1) was 62.0 g/m$^2$, and moisture desorption content was 50.2 g/m$^2$. Moisture adsorption content of gypsum board with 10% diatomite(P) was 59.5 g/m$^2$, and moisture desorption content was 49.0 g/m$^2$. Moisture adsorption contents of gypsum boards with porous materials were higher than that moisture desorption contents of gypsum board without porous materials. Correlation coefficient between surface area and moisture adsorption content of gypsum boards was 0.98. Also, correlation coefficient between surface area and moisture desorption content of gypsum boards was 0.97. Moisture adsorption and desorption contents were influenced by surface area and pore volume of the gypsum boards, and surface area had a larger effect on moisture adsorption and desorption.

Effects of HA and TiN Coating on the Electrochemical Characteristics of Ti-6Al-4 V Alloys for Bone Plates

  • Oh, Jae-Wook;Choe, Han-Cheol;Ko, Yeong-Mu
    • Journal of the Korean institute of surface engineering
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    • v.37 no.5
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    • pp.249-252
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    • 2004
  • Effects of HA and TiN coating on the electrochemical characteristics of Ti-6AI-4V alloys for bone plates were investigated using various test methods. Ti-6AI-4V alloys were fabricated by using a vacuum induction furnace and bone plates were made by laser cutting and polishing. HA was made of extracted tooth sintered and then tooth ash was used as HA coating target. The TiN and HA film coating on the surface were carried on using electron-beam physical vapor deposition (EB-PVD) method. The corrosion behaviors of the samples were examined through potentiodynamic method in 0.9% NaCI solutions at $36.5\pm$$1^{\circ}C$ and corrosion surface was observed using SEM and XPS. The surface roughness of TiN coated bone plates was lower than that of tooth ash coated plates. The structure of TiN coated layer showed the columnar structure and tooth ash coated layer showed equiaxed and anisotrophic structure. The corrosion potential of the TiN coated specimen is comparatively high. The active current density of TiN and tooth ash coated alloy showed the range of about $1.0xl0^{-5}$ $A\textrm{cm}^2$, whereas that of the non-coated alloy was$ 1.0xl0^{-4}$ $A\textrm{cm}^2$. The active current densities of HA and TiN coated bone plates were smaller than that of non-coated bone plates in 0.9% NaCl solution. The pitting potential of TiN and HA coated alloy is more drastically increased than that of the non-coated alloy. The pit number and pit size of TiN and HA coated alloy decreased in compared with those of non-coated alloy. For the coated samples, corrosion resistance increased in the order of TiN coated, tooth ash coated, and non-coated alloy.

Bioconjugation of Poly(poly(ethylene glycol) methacrylate)-Coated Iron Oxide Magnetic Nanoparticles for Magnetic Capture of Target Proteins

  • Kang, Sung-Min;Choi, In-Sung S.;Lee, Kyung-Bok;Kim, Yong-Seong
    • Macromolecular Research
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    • v.17 no.4
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    • pp.259-264
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    • 2009
  • Chemical modification of magnetic nanoparticles(MNPs) with functional polymers has recently gained a great deal of attention because of the potential application of MNPs to in vivo and in vitro biotechnology. The potential use of MNPs as capturing agents and sensitive biosensors has been intensively investigated because MNPs exhibit good separation-capability and binding-specificity for biomolecules after suitable surface functionalization processes. In this work, we demonstrate an efficient method for the surface modification of MNPs, by combining surface-initiated polymerization and the subsequent conjugation of the biologically active molecules. The polymeric shells of non-biofouling poly(poly(ethylene glycol) methacrylate)(pPEGMA) were introduced onto the surface of MNPs by surface-initiated, atom transfer radical polymerization(SI-ATRP). With biotin as a model of biologically active compounds, the polymeric shells underwent successful post-functionalization via activation of the polymeric shells and bioconjugation of biotin. The resulting MNP hybrids showed a biospecific binding property for streptavidin and could be separated by magnet capture.

Role of Charges of the Surface-grafted Polymer Chains for Aqueous Lubrication at a Nonpolar Interface

  • Ron, Troels;Madsen, Jan Busk;Nikorgeorgos, Nikolaos;Lee, Seunghwan
    • Tribology and Lubricants
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    • v.30 no.5
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    • pp.247-255
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    • 2014
  • Charged polymer chains, i.e., polyelectrolytes, are known to show superior aqueous lubricating properties compared to those of neutral polymer chains, especially in brush conformation. This is primarily because of the incorporation of a large amount of counterions within the polymer layers and the consequently increased osmotic pressure. However, this effect is active only when the polymer chains remain immobilized even under tribostress, which is not realistic for high-contact pressure tribological applications, especially when they are irreversibly immobilized on tribopair surfaces. In contrast, with free polymers, which can be included as surface-active additives in the base lubricant (water), long-term lubricating performance based on "self-healing" properties is readily expected. In order to assess whether the superior aqueous lubricating properties of polyelectrolyte chains are valid for free polymers too, this study reviews recent studies on the tribological properties of many charged biopolymer and synthetic copolymers at a nonpolar, hydrophobic interface. In contrast to the irreversibly immobilized polyelectrolyte chains, free polyelectrolyte chains show inferior aqueous lubricating properties compared to their neutral counterparts owing to charge accumulation and the consequently impeded surface adsorption on the nonpolar surface. Nevertheless, bovine submaxillary mucin (BSM), a representative biopolymer, shows a sufficiently effective surface adsorption and aqueous lubricating capabilities even at neutral pH without losing the polyanionic characteristics.

Suspension Stability of Pigments in Aqueous Solution of Anionic Oligo-Type Surfactants(part 3);Synthesis of Anionic Oligo Surfactant having Fluorescent Intensity and Their Properties (올리고머형 음이온성계면활성제 수용액에서 안료의 분산안정성(제 3보);형광성이 큰 올리고머 계면활성제의 합성 및 그의 계면성)

  • Lee, H.W.;Lee, J.H.;Ju, M.J.;Nam, K.D.
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.1
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    • pp.109-115
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    • 1997
  • Fluorescent anionic oligo surfactants were synthesized by the condensing products of long chain alkylvinylether-maleic anhydride cooligomers and resorcinol including dye structures. Their various surface activities and dispersing action were studied on the aqueous solution. These oligo surfactants exhibited a remarkable surface tension lowering property, lower foaming and a large dispersing action for the particles of ${\alpha}-copper$ phthalocyanine blue. Further it was ascertained that the binding of oligo surfactant onto the pigment surface caused the deviation towards lower wavelengths at the maximum fluorescent intensity as compared with aqueous oligo surfactant solutions, These surface active properties of the oligo surfactants may be attributed to rigid and hydrophobic structure of dye groups, besides surface-active groups of alkylether groups and carboxylic group of the anionic oligo surfactants.

Biosensing interfaces based on the dendrimer-underlying layer on gold

  • Yun, Hyeon-Cheol;Kim, Hak-Seong
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.52-55
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    • 2000
  • Structually organized mono- and multilayers were developed on gold for the catalytic and affinity biosensing using hyper-branched dendrimers. For the catalytic biosensing interface, a new approach to construct a multilayered enzyme film on the electrode surface was developed. The film was prepared by layer-by-layer depositions of dendrimers and periodate-oxidized glucose oxidase. The voltammograms obtained from the GOx/dendrimer multilayered electrodes revealed that bioelectrocatalytic response is directly correlated to the number of deposited bilayers. From the analysis of voltammetric and ellipsometric signals, the coverage of active enzyme per layer during the layering steps was estimated, demonstrating the spatially-ordered multilayer formation. As an extension of the study, dendrimers having various degrees of ferrocenyl modification were prepared and used. The resulting electrodes were electrochemically characterized, and the density of ferrocenyl groups, active enzyme coverage, and sensitivity were estimated. For the affinity-sensing surrface, a biosensor system based on avidin-biotin interaction was developed. As the building block of affinity monolayer, G4 dendrimer having partial ferrocenyl-tethered surface groups was prepared and used. And the biotinylated and electroactive dendritic monolayer was used for the affinity-sensing surface interacting with avidin. Electrochemical characterization of the resulting biosensor was conducted using free enzyme in electrolyte in terms of degree of surface coverage with avidin and subsequent surface shielding.

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Analysis of Sinkhole Formation over Abandoned Mine using Active-Passive-Active Finite Elements (폐광지역에서의 싱크홀 발생 규명을 위한 Active-Passive-Active 유한요소 기법 연구)

  • Deb Debasis;Shin Hee-Soon;Choi Sung O.
    • Tunnel and Underground Space
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    • v.14 no.6 s.53
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    • pp.411-422
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    • 2004
  • Sinkhole subsidence occurs over abandoned mine workings and can be detrimental to human lives, damage to properties and other surface structures. In this study, simulation of sinkhole development process is performed using special finite element procedure. Especially, creation of mine voids due to roof falls and generation of goaf from broken rocks are simulated using active-passive-active finite elements. An active or solid element can be made passive or void once the tensile failure criterion is satisfied in the specified sinkhole formation zone. Upon completion of sinkhole development process, these passive elements in again be made active to simulate goal region. Several finite element models are analyzed to evaluate the relationships between sinkhole formation with width of gallery. depth of mine, roof condition and bulking factor of roof rocks. This study demonstrates that the concept of passive elements in numerical analysis can be used effectively for analyzing sinkhole formation or roof fall phenomenon in general.