• Title/Summary/Keyword: activated nitrogen

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Effects of sludge and $CO_2$ addition on advanced treatment of swine wastewater by using microalgae (미세조류를 이용한 양돈폐수 고도처리에서 슬러지 및 이산화탄소의 첨가의 영향)

  • Lim, Byung-Ran;Park, Ki-Young;Lee, Ki-Say;Lee, Soo-Koo
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.3
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    • pp.307-312
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    • 2011
  • The potential of algal-bacterial culture was investigated for advanced treatment of animal wastewater. Fed-batch experiments were carried out to examine treatability of nitrogen and phosphorus in different microbial consortium: Chlorella vulgaris, activated sludge, three microalgae strains (Scenedesmus, Microcystis, Chlorella) and Bacillus consortium, and three microalgae strains and sludge consortium. Single culture of C. vugaris showed the better efficiency for nitrogen removal but was not good at organic matter and phosphorus removal compared with activated sludge. Three microalgae and Bacillus consortium was best culture among the culture and consortium for pollutants removal tested in this experiment. Effect of $CO_2$ addition was studied by using three microalgae and Bacillus consortium. $CO_2$ addition enhanced T-P removal efficiency up to 60%. However, removal efficiencies of T-N and ammonia nitrogen reduced on the contrary.

Propellant Shelf-life Extension by Surface-modified Activated Carbon Fiber (활성탄소섬유를 이용한 추진제 저장수명 연장)

  • Yoon, Keun Sig;Lee, Young Seak;Ryu, Seung Kon
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.443-448
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    • 2011
  • The propellant has a short shelf-life because of nitrogen oxides that were released from nitrocellulose decomposition. As-received and surface-modified ACFs were applied to remove the nitrogen oxides with intend to extend the shelf-life of propellant. The specific surface area of modified ACFs was slightly decreased but nitrogen function groups such as pyridine, pyridone and pyrrol were created on the surface of ACFs. As a result, the NO removal capacity of the surface-modified ACF by propellant waste increased about twice than that of the as-received ACF. The shelf-life of propellant was extended about 1.25 times by accompanying surface-modified ACF.

Ammonia Nitrogen Removal by Cation Exchange Resin (양이온 교환수지에 의한 암모니아성 질소 제거)

  • 이동환;이민규
    • Journal of Environmental Science International
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    • v.11 no.3
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    • pp.263-269
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    • 2002
  • This study was conducted to know the removal characteristics of ammonia nitrogen by commercially available cation exchange resins. Eight acidic cation exchange resins were investigated in batch reactors. Among them, the most effective resin for ammonia removal in solution was PK228, which was a strong acidic resin of $Na^{+}$ type. PK228 was compared with activated carbon and natural zeolite. The effects of cation exchange capacity, ammonia concentration, resin amount, temperature and pH on ammonia removal by PK228 were investigated in batch reactor, and the effect of effluent velocity in continuous column reactor. Strong acidic resins of porous type were more effective than week acidic resins or gel type resins for ammonia removal in solution. PK228 was more effective than activated carbon and natural zeolite for ammonia removal in batch reactor. With increasing initial ammonia concentration, the amount of ammonia removed by PK228 increased, but the proportion of removed ammonia to initial ammonia concentration decreased. The effect or temperature on ammonia removal by PK228 was very slight. The ammonia removal to acidic solution was more effective than that at basic solution. With decreasing effluent velocity of solution through column, breakthrough point extended, and ammonia removal capacity increased.d.

Estimation of Sludge Reduction and Nitrogen Removal Possibility using OSA Process (OSA 공정을 이용한 하수슬러지 감량화 및 질소제거 가능성 평가)

  • Joo, Jae-Young;Yoon, Su-Chul;Nam, Duck-Hyun;Park, Chul-Hwi
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.5
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    • pp.497-503
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    • 2008
  • The Oxic-Settling-Anaerobic(OSA) process is a modified activated sludge processes for sludge reduction. It is evaluated that the sludge production in OSA process can decrease to 88% because of biomass decay and kinetic parameter($Y_H$ 0.237mgVSS/mgCOD, $b_H$ $0.195d^{-1}$) in anaerobic reactor, when compared with CAS process. However, it has problems caused by sludge reduction such as increase of nutrient loading. In case that the anoxic condition through the introduction of the intermittent aeration for the enhancement of nitrogen removal ability build up and enough rbCOD is suppled, maximum 88% of nitrogen is removed in the OSA process. If the OSA process optimizing the intermittent aeration cycle is applied to the separate sewage system with high rbCOD fraction, it can be converted to advanced process in terms of the sludge reduction and nitrogen removal, simultaneously.

Estimation of the Reactor Volume Ratio for Nitrogen Removal in Step-Feed Activated Sludge Process (단계 주입 활성슬러지공법에서 질소제거를 위한 반응기 용적비 추정)

  • Lee, Byung-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.2
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    • pp.130-136
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    • 2006
  • Theoretical total nitrogen removal efficiency and reactor volume ratio in oxic-anoxic-oxic system can be found by influent water quality in this study. The influent water quality items for calculation were ammonia, nitrite, nitrate, alkalinity, and COD which can affect nitrification and denitrification reaction. Total nitrogen removal efficiency depends on influent allocation ratio. The total nitrogen removal follows the equation of 1/(1+b). Optimal reactor volume ratio for maximum TN removal efficiency was expressed by those influent water quality and nitrification/denitrification rate constants. It was possible to expect optimal reactor volume ratio by the calculation with the standard deviation of ${\pm}14.2$.

Electrochemical Characteristics of Reforming Activated Carbon with Nitrogenous Functional Group for Electric Double Layer Capacitor (전기이중층 커패시터용 질소성 작용기를 이용한 개질 활성탄의 전기화학적 특성)

  • Yang, Jeong-Jin;Choi, Young-Joo;Kim, Han-Joo;Yuk, Young-Jae;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.16 no.2
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    • pp.65-69
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    • 2013
  • In order to improve capacitance of activated carbon for electric double layer capacitors, peptide bond was induced on the surface of the activated carbon by urea. Urea induced activated carbon has been stabilized through carbonization. Electrochemical characteristics was observed by cyclic voltammetry for specific capacitance, electrochemical impedance spectroscope for measuring resistance and charge-discharge for testing the cyclic ability. In the result, specific capacitance is increased about 22.9% than the activated carbon. And it shows excellent cycle performance and decreasing resistance with the introduction of nitrogen functional groups.

Color Removal from Dyeing Effluent using Activated Carbons Produced from Various Indigenous Biomass

  • Islam, Md. Shahidul;Das, Ajoy Kumar;Kim, In-Kyo;Yeum, Jeong-Hyun
    • Textile Coloration and Finishing
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    • v.22 no.2
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    • pp.94-100
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    • 2010
  • Colored compounds adsorption from the textile dyeing effluents on activated carbons produced from various indigenous vegetable sources by zinc chloride activation is studied. The most important parameters in chemical activation were found to be the chemical ratio of $ZnCl_2$ to feed (3:1), carbonization temperature (460-470 $^{\circ}C$) and time of activation (75 min). The absorbance at 511 nm (red effluent) and 615 nm (blue effluent) are used for estimation of color. It is established that at optimum temperature ($50^{\circ}C$), time of contact (30-40 min) and adsorbent loading (2 g/L), activated carbons developed from rain tree (Samanea saman) saw dust and blackberry (Randia formosa) tree saw dust showed great capability to remove color materials from the effluents. It is observed that adsorption of reactive dyes by all types of activated carbons is more than that of disperse dyes. It is explained that because of its acidic nature the activated carbon can adsorb better reactive dye particles containing large number of nitrogen sites and $-SO_3Na$ group in their structure. The use of activated carbons from the indigenous biomass would be economical, because saw dusts are readily available waste worldwide.