• Title/Summary/Keyword: activated

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Vapor Phase Mercury Removal by Sulfur Impregnated Activated Carbons and Sulfur Impregnation Protocol

  • Lee, Si-Hyun;Cha, Sun-Young;Park, Yeong-Seong
    • Carbon letters
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    • v.2 no.1
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    • pp.37-43
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    • 2001
  • Mercury has been identified as a potential health and environmental hazardous material. Activated carbon adsorption offers promising potential for the control of mercury emissions, and sulfur impregnated (sulfurized) activated carbons has been shown to be an effective sorbent for the removal of vapor phase $Hg{\circ}$ from sources. In this work, vapor phase mercury adsorption by sulfur impregnated activated carbons were investigated. Sulfur impregnated activated carbons were made by variation of impregnation temperature, and the comparison of adsorption characteristics with commercial virgin and sulfurized carbons were made. Factors affecting the adsorption capacity of virgin and sulfurized activated carbons such as pore characteristics, functional groups and sulfur impregnation conditions were discussed. It was found that the sulfur allotropes plays a critical role in adsorption of mercury vapor by sulfurized activated carbons.

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Removal of boron in seawater by activated carbon adsoprtion (활성탄 흡착에 의한 해수중의 보론 제거)

  • Kim, Han-Seung;Kang, Joon-Seok;Kim, Byung-Ro
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.6
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    • pp.917-922
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    • 2011
  • Adsorption characteristics of boron on activated carbon was investigated in order to evaluate the use of activated carbon for the removal of boron in desalination processes using SWRO. Boron was removed ranging from 54~60% when the concentration of activated carbon was 1,000 mg/L in 6 hours under the initial boron concentration of 5 mg/L. The removal of boron increased by 20~22% with the increase of pH from 5 to 9. Organic matter had adverse effect on the adsorption of boron on activated carbon. Boron removal decreased by 10-12% when EDTA was added at 1 mg/L under 5 mg/L of boron and 200mg/L of activated carbon. In this results, activated carbon would be a good candidate for a pretreatment of desalination processes by SWRO from the view of mitigating the feed boron concentration to RO and meeting the effluent boron concentration without post-treatment after RO.

A Study on the Adsorption of Hg(II) Ion by Activated Carbon(1) (活性炭에 依한 Hg(II) 이온의 吸着에 관한 조사연구(1))

  • Lee, Hyun;Lee, Jong-Hang;Yun, O. Sub
    • Journal of Environmental Health Sciences
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    • v.14 no.2
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    • pp.65-71
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    • 1988
  • In this study, the method of adsorption by activated carbon in the removal of Hg(II) ion in waste water was treated. The influence of kinds of activated carbon and effect of temperature and the influence of coexistent salt on adsorption rates, the influence of pH in the adsorption, equilibrium and adsorption of mercury from activated carbon were investigated. From the adsorption on activated carbon of mercury(II) ion in the presence of cyanide or thiocyanate ion was found that mercury(II) was easily adsorved onto the activated carbon in the form of complex artion such as Hg(CN)$_4^{2-}$, Hg(SCN)$_4^{2-}$ respectively. ZnCl$_2$ activation method had a higher adsorptive ability than steam activation method in adsorption of Hg on activated carbon. Activated carbon adsorbed iodide ion is very effective on adsorption of Hg.

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Physical and Mechanical Properties of Porous Concrete Using Waste Activated Carbon (폐활성탄을 사용한 다공성 콘크리트의 물리.역학적 성질)

  • Youn, Joon-No;Sung, Chan-Yong;Kim, Young-Ik
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.4
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    • pp.21-27
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    • 2009
  • This study was performed to evaluate the physical and mechanical properties of porous concrete using waste activated carbon. Material used were ordinary portland cement, recycled coarse aggregate, waste activated carbon and superplasticizer. The replacement ratios of waste activated carbon were 0,1,2,3,4,5,6,7,8,9, and 10 %. The void ratio was decreased and ultrasonic pulse velocity was increased with increasing the waste activated carbon powder, respectively. The compressive strength and flexural strength of porous concrete using waste activated carbon powder were in the range of 8.21${\sim1}$6.58 MPa and 1.69${\sim1}$3.68 MPa, respectively. The pH degree of porous concrete in 1day and 77days were shown in 12.50${\sim1}$12.63 and 10.21${\sim1}$10.70, respectively. Accordingly, waste activated carbon can be used for porous concrete material.

Characterization and Fabrication of Chemically Activated Carbon Fibers with Various Drying Temperatures using OXI-PAN Fibers

  • Moon, Sook-Young;Lee, Byung-Ha;Lim, Yun-Soo
    • Carbon letters
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    • v.8 no.1
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    • pp.30-36
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    • 2007
  • Oxidized PAN (OXI-PAN) fibers were used for the precursors of activated carbon fiber in study. How drying temperature affected the properties of carbon fibers on activating process of carbon fibers was investigated. The specific surface areas of activated carbon fibers have been determined on a series of chemically activated carbons with KOH and NaOH. The experimental data showed variations in specific surface area, iodine and silver adsorptions by the activated carbon fibers. The amount of iodine adsorption increases with increasing specific surface areas in both activation methods. This was because the ionic radius of iodine was smaller than the interior micropore size of activated carbon fibers. Silver adsorbed well in NaOH activated carbon fibers rather than KOH activated carbon fibers in this study.

A Study on the Standardization of Activated Sludge Use to Biodegraded Linear Alkylbenzene Sulfonate (Linear Alkylbenzene Sulfonate의 생분해에 이용되는 활성오니의 표준화에 관한 연구)

  • Sun, Yle-Shik;Jung, Il-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.9 no.1
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    • pp.31-40
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    • 1992
  • This study is on the biodegradability of the activated sludge, which used to biodegrade Linear Alkylbenzene Sulfonate(LAS), synthetic detergents and sufactants. The activated sludge in waste water treatment plant is used to the test of biodegradation of anionic surfactants and nonionic surfactants, but it have the periodic change of the biological propety to the lapse of the time. For the puropse of controlling and adjusting of the activated sludge in biodegradation test, we collected microorganisms from the sewage plant and the soil, and then, made the activated sludge in semicontinuous aeration chamber. From determined biodegradation data, and the degree of biodegradability to the LAS, we confirmd the standardized synthetic activated sludge which have more stable biodegradability than the sewage activated sludge. In continuous biodegradation test, LAS(dodecene-1) was biodegraded more than 99%, In 7days by the standardized activated sludge.

Physical Property with the Manufacturing Conditions of Activated Carbon for Mercury Adsorption (제조조건에 따른 활성탄의 특성 및 수은 흡착 효율)

  • Min, Hyo-Ki;Ahmad, Tanveer;Park, Min;Lee, Sang-Sup
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.3
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    • pp.302-314
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    • 2015
  • There is an adsorption method using activated carbon as a typical method for removing elemental mercury. Physical characteristics of activated carbon such as specific surface area and volume of pore (micro and meso) have positive effect for mercury adsorption. Activated carbon is carbon-based material with a high specific surface area. This activated carbon can be manufactured through carbonization and activation process. In this process, physical characteristics of specific surface area and pore distribution are changed by controlling operating parameters like temperature, time and reagent of activation. In this study, we evaluated characteristics of activated carbons manufactured from pinewood and coal with the operating parameters. We evaluated mercury adsorption capacities of the activated carbons having excellent physical characteristics and compared those to the commercial activated carbon.

Adsorption capability of activated carbon synthesized from coconut shell

  • Islam, Md Shariful;Ang, Bee Chin;Gharehkhani, Samira;Afifi, Amalina Binti Muhammad
    • Carbon letters
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    • v.20
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    • pp.1-9
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    • 2016
  • Activated carbon was synthesized from coconut shells. The Brunauer, Emmett and Teller surface area of the synthesized activated carbon was found to be 1640 m2/g with a pore volume of 1.032 cm3/g. The average pore diameter of the activated carbon was found to be 2.52 nm. By applying the size-strain plot method to the X-ray diffraction data, the crystallite size and the crystal strain was determined to be 42.46 nm and 0.000489897, respectively, which indicate a perfect crystallite structure. The field emission scanning electron microscopy image showed the presence of well-developed pores on the surface of the activated carbon. The presence of important functional groups was shown by the Fourier transform infrared spectroscopy spectrum. The adsorption of methyl orange onto the activated carbon reached 100% after 12 min. Kinetic analysis indicated that the adsorption of methyl orange solution by the activated carbon followed a pseudo-second-order kinetic mechanism (R2 > 0.995). Therefore, the results show that the produced activated carbon can be used as a proper adsorbent for dye containing effluents.

Effect of Activated Charcoal on Wound Healing in Rabbits (활성탄이 토끼에서 실험적으로 유발된 결손창 치유에 미치는 영향)

  • 조한성;정종태;연성찬
    • Journal of Veterinary Clinics
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    • v.17 no.2
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    • pp.376-380
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    • 2000
  • This study was performed to investigate the effect of activated charcoal on wound healing in an experimentally induced skin wound model. Full-thickness, skin defects ($2 cm{\times}2 cm$) were made in two different areas on the back of eight New Zealand white rabbits. Eight of 16 wounds were treated with gauze-gauze-impregnated activated charocal granules, and another eight wounds were treated with gauze-soaked saline. Wound areas were measured every other day for 2 weeks after the wound-ing. Statistical analysis was performed with the student t-test. The mean percentage of wound con- traction on the 14th day in the activated charcoal-treaded group and in the saline treated group were 93.5% and 81_7%, respectively. The mean value of tensile, strength ell the 21s1 day after wounding was,42.70{\pm}0.8 kg/5cm^2$,/TEX> in the activated charcoal-treated group and $1.75 {\pm} 0.5 kg/5 cm^2$ in the saline treated group. Significantly reduced wound area (p<0.05) and high tensile strength value (P<0.O5) were observed in activated charcoal-treated group compared with those in the saline treated group. In summary activated charcoa1 significantly reduced the wound area an increased tensile strength in the rabbit 7kin wound model. These results suggest that application of activated charcoal in skill wounds will promote wound healing.

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Engineered biochar from pine wood: Characterization and potential application for removal of sulfamethoxazole in water

  • Jang, Hyun Min;Yoo, Seunghyun;Park, Sunkyu;Kan, Eunsung
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.608-617
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    • 2019
  • The adsorption of sulfamethoxazole (SMX) onto a NaOH-activated pine wood-derived biochar was investigated via batch experiments and models. Surprisingly, the maximum adsorption capacity of activated biochar for SMX (397.29 mg/g) was superior than those of pristine biochars from various feedstock, but comparable to those of commercially available activated carbons. Elovich kinetic and Freundlich isotherm models revealed the best fitted ones for the adsorption of SMX onto the activated biochar indicating chemisorptive interaction occurred on surface of the activated biochar. In addition, the intraparticle diffusion limitation was thought to be the major barrier for the adsorption of SMX on the activated biochar. The main mechanisms for the activated biochar would include hydrophobic, π-π interactions and hydrogen bonding. This was consistent with the changes in physicochemical properties of the activated biochar (e.g., increase in sp2 and surface area, but decrease in the ratios of O/C and H/C).