• Applied Chemistry for Engineering
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• v.5 no.4
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• pp.743-747
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• 1994

The catalytic effects of carboxylic acid and dibutyltin dilaurate(DBTL) on the curing rate of acrylic polyol with isocyanate prepolymer were investigated. In this work reaction of a biuret type aliphatic isocyanate with acrylic polyol follows the second order reaction in the thin film state. Carboxylic acid of acrylic polyol has a strong catalytic effect on the isocyanate groups and influences greatly on curing rate, also DBTL is more effective catalysis on acrylic polyol without carboxylic acid than with carboxylic acid.

• Journal of the Korean Chemical Society
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• v.65 no.2
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• pp.88-92
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• 2021

In art painting creation, painting material is an important carrier. Acrylic as a young material has very wide applications in modern art. This study mainly analyzed the properties of acrylic material. Firstly, the emergence and development of acrylic were introduced, and then its material characteristics were analyzed. Finally, the performance embodiment of acrylic paintings was compared with oil paintings and watercolor paintings. It was found that acrylic paintings not only had some advantages of oil and watercolor paintings but also had own style characteristics; acrylic paintings also have advantages in durability and flexibility; acrylic paintings could present the characteristics that oil and watercolor paintings did not have while realizing the techniques of them. Acrylic paintings have a broad development space in art creation, which is worth further attention and promotion.

• Elastomers and Composites
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• v.48 no.4
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• pp.276-281
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• 2013

Polyester type polyurethane foam modified with acrylic polyol was prepared by quasi prepolymer method. Thermal and dynamic mechanical properties of polyurethane foam were analysed by thermal gravimetric analysis(TGA) and dynamic mechanical analysis(DMA). Also, glass transition temperature was measured by differential scanning calorimeter(DSC). As acrylic polyol contents were increased, thermal stability measured by TGA was slightly decreased. Storage modulus was increased and tan delta was decreased with increasing of acrylic polyol contents.

• Journal of the Korean Applied Science and Technology
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• v.28 no.3
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• pp.359-366
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• 2011

In this study we experimented that how polyurethane effect to acrylic-polyurethane resin in Full-Grain leather coatings. First of all, we consummated waterborne acrylic emulsion and waterborne polyurethane resin, Than we prepared F.G leathers which were coated by acrylic resin and acrylic-polyurethane resins. According to measured data for solvent resistance, acrylic resin and acrylic-polyurethane resins had good property. Sample a(WAC) had most low strength($2.10kg_f/mm^2$) and sample d(WAC 93 : WPU 7) had most high strength($3.41kg_f/mm^2$). Also we knew that most good property of abrasion is d(47.4 mg). In elongation case, a(WAC) had most good result(645 %) in this experiment.

• Elastomers and Composites
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• v.48 no.3
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• pp.241-248
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• 2013

Polyester type polyurethane foam has low hydrolysis resistance. It was overcome with addition of acrylic polyol by quasi prepolymer method. Tensile strength and hardness of polyurethane foam contained acrylic polyol was increased with increasing of acrylic polyol contents. But split tear strength and tear strength was slightly changed. Hydrolysis resistance of polyurethane foam was measured by loss % of tensile strength. It was improved with increasing of acrylic polyol contents from 25.5g to 102g.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.160-161
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• 2021

To prepare polyurethane coatings for top coatings of automobiles, acrylic resins containing 75% of solids were synthesized by a radical polymerization. The viscosity of the acrylic resins was increased with increasing OH values. Crosslinked acrylic-urethane clear coatings were obtained by curing reaction between the synthesized acrylic resins and hexamethylene diisocyanate(HDI) trimer(Desmodur N-3600). The physical properties from the following studies were carried out : viscosity(Zahn cup #2), adhesion, pensil hardness, and 60° specular gloss. Various properties of the acrylic-urethane clear coatings as top coatings of mobile coat were evaluated on the coating specimens. Adhesion property to a substrate, 60° specular gloss, and pencil hardness of prepared paint showed quite good properties.

• Journal of Food Hygiene and Safety
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• v.8 no.2
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• pp.105-117
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• 1993

The objective of this investigation was to characterize the subacute toxic potency of orally administered poly(sodium acrylic acid-acrylic acid), super absorbent polymer. Four groups of rats were maintained on diets containing 0, 1.25, 2.5 or 5% of poly(sodium acrylic acid-acrylic acid). The mean dosages of poly(sodium acrylic acid-acrylic acid) were estimated to be 1025 mg/kg/day, 2009 mg/kg/day and 4728 mg/kg/day in the male groups. The estimated average dosages of poly(sodium acrylic acid-acrylic acid) in the female groups were 1011 mg/kg/day, 2088 mg /kg/day and 4576 mg/kg/day, respectively. Few test compound-related toxic effects were observed in body weight gain, clinical signs, hematological parameters and serum biochemical values. Urinalyses, gross necropsy and histopathology revealed no evidence of specific toxicity. Food and water consumption tended to increase in the animals fed the diet of 2.5% and 5%. Our data indicate that no-observed effect level of poly(sodium acrylic acid-acrylic acid) was estimated to be 1.25% in the diet (mean dosage: 1025 mg/kg/day in male rats, 1011 mg/kg/day in female rats).

• Journal of Adhesion and Interface
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• v.23 no.3
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• pp.80-86
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• 2022

In this study, water-based acrylic tackifier with different contents of 1-dodecanethiol(n-DM), a chain transfer agent(CTA), were synthesized to improve the performance and adhesive properties of water-based acrylic pressure sensitive adhesive(PSA). In order to investigate the change in physical properties according to the amount of water-based acrylic tackifier added, 10/20/30 phr of water-based acrylic tackifier was added to the water-borne acrylic emulsion to measure the physical properties. The molecular weight and glass transition temperature(T_g) of the synthesized water-based acrylic tackifier tended to decrease as the content of n-DM increased. When a water-based acrylic tackifier was added to the water-borne acrylic emulsion, the peel strength and heat-resistance were increased. Also, when the water-based acrylic tackifiers were added at 10 phr or 20 phr, the best value was shown.

• Journal of the Korea Fashion and Costume Design Association
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• v.8 no.3
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• pp.17-25
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• 2006

We performed the objective sensibility evaluation on knitted fabrics by the following procedures: setting acrylic fabrics with knitted fabrics as basis, knitted five kinds of blended spun yarns and four kinds of twisted filament yams made by different twisting methods(the amount and direction of twist) then, measuring mechanical properties in the use Kawabata Evaluation System, obtaining hand values and total hand values. The results are as follows: First, A(F)/W acrylic/wool spun knits obtain high scores in bending, compressing, shear properties, MMD, and thickness among five kinds of acrylic-blended knit fabrics. A(S)/W acrylic/wool blended knit represented prominent values at compressing properties and thickness and so wool-blended yams demonstrated superior characters comparing other blended yarns. To contrast, acrylic/rayon blended knits showed low scores in bending properties, shear properties and thickness, so that it affects to total hand values. On the one hand, among the four kinds of acrylic filament knitted fabrics, they do not exhibit any notable dynamic differences such as tensile properties of knitted fabrics by the twist number and direction of filament yarns, bending, shear, compressing properties, weight and thickness except surface properties. Second, fabrics showed the most high score at FUKURAMI (fullness and softness) among the hand values. A(S)/W acrylic/wool blended knits obtaining the lowest values at SAHRI (crispness) outrank at total hand values, so that it was the predominant knitted fabric in objective sensibility evaluation. In total hand values, five kinds of acrylic blended knits got a higher score than four kinds of acrylic filament knits, and the amount and direction of twist did not influence on total hand values among the four kinds of acrylic filaments.

• Journal of the Korea Fashion and Costume Design Association
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• v.9 no.1
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• pp.35-50
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• 2007

We performed the subjective sensibility evaluation on knitted fabrics by the following procedures: setting acrylic fabrics used for S/S among fabrics as basis, five kinds of blended spun yarns and four kinds of twisted filament yarns made by different twisting methods then, we did questionnaire survey targeting sixty females in the expert groups. Utilizing SPSS 12.0, correlation, ANOVA, Duncan, and Multidimensional Standard way were analyzed. The results are as following. First, the result of evaluating on preferred knits followed by the analysis of the sense factor, in the 'drape sense', the acrylic/rayon blended knit was preferred as the most flexible, pliable, and elastic knit; in weight/bulk factor, the acrylic filament knit the most twisted was preferred as the least bulk, thin, cool and transparent knit; in 'surface depression sense' factor, A(F)W acrylic/wool blended knit was preferred as the most haggard, straight, dry knit. Second, the result of evaluating on preferred knits followed by the analysis of the sensibility factor, in the 'neatness' the acrylic filament hit was preferred as the most clean, neat and delightful knit; in the 'comfortableness', the acrylic/wool blended knit was preferred as the most natural, stable, and comfortable knit. Third, according to the result of evaluating on preferred knits as the spring and summer, generally the acrylic filament twisted yarn knits were more preferred than the acrylic blended yarns. However the preference on the kinds of the acrylic twisted filament yarn showed that there is a little difference on the acrylic blended yarn knit.