• Title/Summary/Keyword: acryl

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Preparation of Pressure Sensitive Adhesive Using Reactive Polyurethane Resin and the Effect of Interfacial Crosslinking on the Adhesion Property (반응성 폴리우레탄 레진을 이용한 Pressure Sensitive Adhesive 제조 및 계면 가교 반응이 점착 물성에 미치는 영향)

  • Shin, Jin Sup;Kim, Ji Heon;Cheong, In Woo;Kim, Jung Hyun
    • Applied Chemistry for Engineering
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    • v.16 no.1
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    • pp.81-85
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    • 2005
  • Pressure sensitive adhesive (PSA) was prepared by semi-batch emulsion polymerization of acryl monomers in the presence of reactive and non-reactive carboxylated polyurethane resin (PUR). Effects of the PUR type, its content, and crosslinker feeding method on the adhesive properties of the PSA was investigated. In this experiment, the PSA prepared with the reactive PUR showed better adhesive property then the PSA with the non-reactive PUR. Especially, peel strength of the PSA, where acetoacetoxy ethyl methacrylate and 1,6-hexane diamine as crosslinkers were introduced, was dramatically enhanced in severe humidity condition due to the interfacial crosslinking.

A Study on the Phase Behavior and Stability of the Polar Oil Emulsion System (Polar Oil계 Emulsion의 상거동과 안정성에 관한 연구)

  • Park, Eun-Hee;Chung, Hung-Ho;Kim, Jong-Gyu;Kim, Hyung-Il;Rho, Jae-Seong
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.510-516
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    • 1997
  • O/W emulsions were prepared by adding water to the solution containing amphiphilic resin and the mixed emulsifier of cetyl alcohol polyoxyethylene(20) sorbitan monooleate. Phase behavoir of these emulsions was studied at various HLB(Hydrophilic Lipophilic Balance) values and temperatures. The polar oil emulsion containing the amphiphilic resin showed improved phase stability at various temperatures. Model compounds which contain one of the functional groups in the amphiphilic resin were used in the polar oil phase in order to study the effect of interaction between the functional group and the emulsifier on the phase stability of emulsion. These model compound emulsions showed the phase stability order of poly(acrylic acid)

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Development of Automatic Measurement and Control Method based on Single Chip Microcomputer for Tackjoo Fermentation (Single Chip Microcomputer를 이용한 탁주발효(濁酒醱酵)의 자동계측(自動計測)과 제어방법(制御方法)의 개발(開發))

  • Kim, Kyung-Man;Chun, Jae-Kun
    • Korean Journal of Food Science and Technology
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    • v.25 no.4
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    • pp.391-394
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    • 1993
  • For the automation of Tackjoo fermentation, a sensor measurable gas production during brewing and a controller were built. The performance tests were carried out at 10 litter Tackjoo fermentor, The sensor was consisted of a transparent acryl cell for bubble formation and photo-interrupter for the detection of bubbles of 0.018ml size. The fermentation controller was fabricated with a single chip microcomputer (MC68705R3) and provided with both the monitoring module of temperature measurement and the valve controling device for the cooling water circulation in coil type heat exchanger. The operation programs were developed and systemized in ROM. With this computer system, the gas production amount and rate were acquired during the Tackjoo fermentation. The fermentation curve based on the gas production rate showed a good agreement with that of alcohol concentration. The maximum rate of gas production was found after 24 hr at $30^{\circ}C$. The correlation equation between the gas production and alcohol concentration was established and used as the control algorithm of the fermentation.

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The Reduced Model Test for the Determination of Ventilation Velocity to Prevent Backflow in Uni-directional Road Tunnel during a Fire Disaster (일방향 도로터널내 화재 발생시 역류를 막는 환기속도결정에 관한 축소모형실험)

  • 유영일;이희근
    • Tunnel and Underground Space
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    • v.8 no.2
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    • pp.107-117
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    • 1998
  • In the case of a fire disaster in a uni-directional road tunnel, it is important to determine the critical ventilation velocity to prevent the backflow travelling toward the tunnel exit where vehicles are stopped. The critical ventilation velocity is horizontal velocity to prevent hot smoke from moving toward the tunnel exit. According to Froude modelling, the model tunnel whcih was 300mm in diameter and 21 m in length was made of acryl tubes. Inner section of acryl tubes was clothed with polycarbonate. 1/20 scaled model vehicles were installed to simulate the situation that vehicles are stopped in the tunnel exit. Methanol in a pool type burner was burned in the middle of tunnel to simulate a fire hazard. In this study, the basis of determining the critical ventilation velocity is the ventilation flow rate that is able to maintain the allowable CO concentration in the tunnel section. We assumed that the allowable CO concentration was backflow dispersion index. Futhermore, We intended to find out CO distribution and temperature distribution according as we changed ventilation velocity. The results of this study were that no backflow happened when ventilation velocity was 0.52 m/s in the case of 5.75 kW. If we adapt these results of a fire disaster releasing 10MW heat capacity in real tunnel which is 400m in length, no backflow happens when ventilation velocity is 2.31m/s. After we figured out dimensionless heat release rate and dimensionless ventilation velocity of model test and those of real test to verify experimental correctness, we tried to find out correlation between experimental results of model tunnel and those of real tunnel.

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Endovaginal and Endorectal Surface Coils for in-ViVo Human MR Imaging and Spectroscopy (자궁경부암 진단용 MR 질내표면코일과 전립선암 진단용 MR 경직장표면코일의 제작 : 인체에서의 MR 영상과 MR 분광)

  • 문치웅;조경식
    • Journal of Biomedical Engineering Research
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    • v.16 no.4
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    • pp.481-491
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    • 1995
  • Endovaginal and endorectal receiver only surface coils were designed for MR imaging (MRI) and $^1H$ MR spectroscopy (MRS) for the uterine cervix and the prostate. The shape of endovaginal coil wire was rectangular with round corner. Size of the coil wire was empirically determined for 7cm and 4cm along the long and short axis, respectively. The coil wire loop was supported by acryl handle and bent about $150^{\circ}$ at one side of the loop considering the average angle of the cervix to the vagina. We called this as a "spoon-type endovaginal coil". The wire of the endorectal coil was made of the flexible materials so that the wire loop became long elliptic shape by pushing the acryl handle into the plastic tube for the comfort of patients when the coil was inserted into the cervix. Then, the shape was maintained to be circle by popping out handle. Conventional spin echo (SE) and fast spin echo (FSE) sequences were used as 71 and 72 weighted imaging sequences, respectively. Matrix size was 128~$256{\times}256$. FOVs for surface coil and body coil were 14cm and 24cm, respectively. 3D volume localized in vivo $^1H$ MR spectroscopy of the human cervix and prostate was performed using PRESS or STEAM localization method with the following parameters . TR=3 sec, TE=135 msec for PRESS or 30 msec for STEAM, NEX=2, NS=48, Sl=2048, and SW=2500 Hz. Using home-built endovaginal and endorectal coils, excellent T1- and T2-images were obtained to visualize early cervical and prostate tumors. 3D volume localized in vivo IH MRS was useful to differentiate the cancerous tissue from the normal tissue.

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Reinforcement of provisional restoration with cast metal framework: A case report (주조 금속 구조물을 이용하여 강화한 임시보철물 수복 증례)

  • Kim, Hyun-Young;Moon, Yoon-Hee;Lee, Jong-Hyuk
    • The Journal of Korean Academy of Prosthodontics
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    • v.55 no.1
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    • pp.46-52
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    • 2017
  • Provisional restoration plays an important role in the process of restoration with fixed partial denture by providing protection and restoring function and esthetics of abutment tooth. This is especially true in patients requiring use of provisional prosthesis for a long term. However, such situations may lead to higher possibility of provisional prosthesis fracture, and if expected so, reinforcement of provisional prosthesis should be considered. In this article, a patient requiring prosthetic treatment with increase of vertical dimension of occlusion was introduced. Due to increased vertical dimension of occlusion, the provisional restoration was expected to withstand relatively larger amount of load during a relatively long observation period. In order to minimize possible occurrence of fracture, reinforcement of the provisional restoration was sought by insertion of cast-metal framework and by using bis-acryl resin. The reinforced provisional restoration showed satisfactory results during the observation period of 4 months.

Comparison of fracture strength after thermomechanical aging between provisional crowns made with CAD/CAM and conventional method

  • Reeponmaha, Tanapon;Angwaravong, Onauma;Angwarawong, Thidarat
    • The Journal of Advanced Prosthodontics
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    • v.12 no.4
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    • pp.218-224
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    • 2020
  • PURPOSE. The objectives of this study were to evaluate the fracture strength and fracture patterns of provisional crowns fabricated from different materials and techniques after receiving stress from a simulated oral condition. MATERIALS AND METHODS. A monomethacrylate-based resin (Unifast Trad) and a bis-acryl-based (Protemp 4) resin were used to fabricate provisional crowns using conventional direct technique. A milled monomethacrylate resin (Brylic Solid) and a 3D-printed bis-acrylate resin (Freeprint Temp) were chosen to fabricate provisional crowns using the CAD/CAM process. All cemented provisional crowns (n=10/group) were subjected to thermal cycling (5,000 cycles at 5°-55℃) and cyclic occlusal load (100 N at 4 Hz for 100,000 cycles). Maximum force at fracture was tested using a universal testing machine. RESULTS. Maximum force at fracture (mean ± SD, N) of each group was 657.87 ± 82.84 for Unifast Trad, 1125.94 ± 168.07 for Protemp4, 953.60 ± 58.88 for Brylic Solid, and 1004.19 ± 122.18 for Freeprint Temp. One-way ANOVA with Tamhane post hoc test showed that the fracture strength of Unifast Trad was statistically significantly lower than others (P<.01). No statistically significant difference was noted among other groups. For failure pattern analysis, Unifast Trad and Brylic Solid showed less damage than Protemp 4 and Freeprint Temp groups. CONCLUSION. Provisional crowns fabricated using the CAD/CAM process and the conventionally fabricated bis-acryl resins exhibited significant higher fracture strength compared to conventionally fabricated monomethacrylate resins after the aging regimen. Therefore, CAD/CAM milling and 3D printing of provisional restorations may be good alternatives for long term provisionalization.

Study on Heat-shield Property of Surface-treated Inorganic Oxide Particles (표면처리된 무기산화물 입자의 열차단 특성에 관한 연구)

  • Kim, Dong Ho;Kim, Gu Ni
    • Journal of Adhesion and Interface
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    • v.14 no.1
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    • pp.28-35
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    • 2013
  • In this study, we produced heat-shield coating materials using surface-treated Ga-doped ZnO (GZO) and investigated the dispersity of particle, visible light transmittance, ultraviolet light cut off, infrared light cut-off, heat-shielding property by surface-treating compounds and treatment conditions. In the case of using IPA or acryl binder for heat-shield coating, the dispersity of inorganic oxide particles was poor but in the case of using surface-treated inorganic oxide particles by hybrid compound having urethane (urea) group, acryl group and silica, dispersity of particle, visible light transmittance and haze were improved. We used the measurement kit and sunlamp for measuring heat-shielding property and confirmed that the internal temperature of the measurement kit using heat-shield film was lower more than $4.8^{\circ}C$ in comparison with using PET film for itself.

Synthesis and Properties of Waterborne Polyurethane Acrylate Adhesive (수분산 폴리우레탄 아크릴 접착제의 합성 및 물성 연구)

  • Lee, Seung Hwan;Cheon, Jung Mi;Jeong, Boo Young;Kim, Han-Do;Chun, Jae Hwan
    • Journal of Adhesion and Interface
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    • v.16 no.4
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    • pp.156-161
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    • 2015
  • In this study, waterborne polyurethane acrylate were synthesized with polyester polyol, 4,4-dicyclohexylmethane diisocyanate ($H_{12}MDI$), dimethylol propionic acid (DMPA), acrylate monomer to improve the properties and peel strength. In addition, the properties of the synthesized waterborne polyurethane acylate was evaluated through FT-IR, particle size analysis, UTM, peel strength. As the acrylic acid content increased, particle size increased. In the results of mechanical properties, when the acrylic acid contents increased, tensile strength was increased but elongation was decreased. All peel strength was improved as the acrylic acid contents of WPUA and acrylate ratio of PU/acrylate increased. Optimum peel strength obtained when acrylic acid was 0.5 wt%.

Studies on the Focusing Solar Agricultural Crop Dryer - II. Aluminum-laminated Acryl Film Cylindrical Focusing Solar Food Dryer - (농산물(農産物) 건조용(乾燥用) 곡면(曲面) 집광식(集光式) 태양(太陽) 열(熱) 이용(利用) 장치(裝置)에 관한 연구 - 제(第) 2 보(報) : 알루미늄-아크릴 필름 태양열(太陽熱) 이용(利用) 장치를 사용한 농산물(農産物) 건조(乾燥)에 관한 연구 -)

  • Chun, Jae-Kun;Mok, Chul-Kyoon
    • Korean Journal of Food Science and Technology
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    • v.11 no.4
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    • pp.258-263
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    • 1979
  • A cylindrical focusing solar food dryer made with aluminum-laminated acryl film was demonstrated for the dehydration of agricultural product and its perfomance was analyzed with respect to the solar energy utilization and its scale-up technology. With one square meter reflector and a 74 cm copper pipe absorber, the heat exchange efficiency between air stream and absorber was 1.39 %. The installation of circular segment-baffle increased 33 % of the efficiency. In dehydration of radish-cut with this drier, 58 % of fuel consumption was saved. The relationship between reflector area and heat energy utilization was established for the scale-up purpose.

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