• Title/Summary/Keyword: acidity analysis

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Application of Clustering Methods for Interpretation of Petroleum Spectra from Negative-Mode ESI FT-ICR MS

  • Yeo, In-Joon;Lee, Jae-Won;Kim, Sung-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3151-3155
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    • 2010
  • This study was performed to develop analytical methods to better understand the properties and reactivity of petroleum, which is a highly complex organic mixture, using high-resolution mass spectrometry and statistical analysis. Ten crude oil samples were analyzed using negative-mode electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). Clustering methods, including principle component analysis (PCA), hierarchical clustering analysis (HCA), and k-means clustering, were used to comparatively interpret the spectra. All the methods were consistent and showed that oxygen and sulfur-containing heteroatom species played important roles in clustering samples or peaks. The oxygen-containing samples had higher acidity than the other samples, and the clustering results were linked to properties of the crude oils. This study demonstrated that clustering methods provide a simple and effective way to interpret complex petroleomic data.

The Effect on the Forest Plant Community by the Air Pollution around Daesan and Kunsan Industrial Complex Areas (대산.군산공단지역의 대기오염이 삼림식물군집에 미치는 영향)

  • Lee, Kyung-Jae;Cho, Woo;Han, Bong-Ho
    • Korean Journal of Environment and Ecology
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    • v.9 no.1
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    • pp.1-14
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    • 1995
  • To investigate the damage on the forest plant community by the air pollution around Daesan, Kunsan industrial complex, five sites(Daesan) and three sites(Kunsan) were set up and surveyed(Area : 500$m^2$/site). In the analysis of community structure, the dominant species in the canopy and understory layer were Pinus densiflora, P. thunbergiana. ones in the shrub layer appeared Rhododendron mucronulatum and Quercus spp. in the Daesan industrial complex. Species diversity of the plant community in Daesan industrial complex showed very severe difference between plots. Soil acidity measured 4.67~5.12. It was not found that plant community in Daesan industrial complex appeared serious damage by the air pollutant. In the analysis of community structure the dominant species in the canopy and understory layer were P. densiflora, P. thunbergiana in Kunsan industrial complex. Species diversity of the plant community in Kunsan industrial complex was prove to low as nearer from the pollutant. Soil acidity measured 4.32~4.76 and it was very strong acidity. It was found that plant community as nearer from the pollutant appeared visible damage entirely by the air pollutant in Kunsan industrial complex.

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Effects of Red Peppers on the Its Pungency and Color during Kimchi Fermentation (고춧가루가 발효중 김치의 매운맛과 색도에 미치는 영향)

  • 구경형;박재복;박완수
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.6
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    • pp.1034-1042
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    • 2004
  • This study was carried out to investigate preparation of reconstructed red peppers, effects of pungency and redness of red peppers on the Kimchi quality using central composite design and response surfaces methodology. Capsaicinoids and ASTA (American Spice Trading Association) value put in X$_1$, X$_2$ of independent variable. The result of response surface regression analysis of reconstructed red peppers, correlation coefficient ($R^2$) of overall pungency intensity, persistence and degree of redness was 0.935, 0.935 and 0.821, respectively. After it was made Kimchi samples with reconstructed red peppers, it was examined pH, titratable acidity and lactic acid bacteria of its during fermentation. In the initial fermentation period of Kimchi, it showed pH of 5.46∼5.78, titratable acidity of 0.27∼0.31%, salt content of 2.26∼2.48% and lactic acid bacteria of 4.05${\times}$10$^{5}$ ∼6.23${\times}$10$^{5}$ , respectively. And it showed traditional fermentation pattern in the pH, titratable acidity and microbes of the middle (appropriate fermentation) and last (excessive) fermentation period. While capsaicinoids content in the Kimchi decreased a little according to extend fermentation period, ASTA value showed low correlation reconstructed red pepper and fermentation period. Also, it was analyzed correlation coefficient ($R^2$) of independent variables (capsaicinoids, X$_1$; ASTA value, X$_2$) between sensory attribute in the Kimchi during fermentation. The result of regression analysis, $R^2$ in the overall pungency intensity, persistence and degree of redness showed 0.515, 0.675, 0.784, respectively.

Acidity in Precipitation and Solar North-South Asymmetry

  • Moon, Ga-Hee;Ha, Kyoung-Yoon;Kang, Seong-Hoon;Lee, Byoung-Ho;Kim, Ki-Beom;Kim, Jung-Hee;Chang, Heon-Young
    • Journal of Astronomy and Space Sciences
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    • v.31 no.4
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    • pp.325-333
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    • 2014
  • We are motivated by both the accumulating evidence for the connection of solar variability to the chemistry of nitrogen oxide in the atmosphere and recent finding that the Galactic cosmic-ray (GCR) influx is associated with the solar north-south asymmetry. We have analyzed the measured pH in precipitation over the 109 stations distributed in the United States. We have found that data of pH in precipitation as a whole appear to be marginally anti-correlated with the solar asymmetry. That is, rain seems to become less acidic when the southern hemisphere of the Sun is more active. The acidity of rain is also found to be correlated with the atmospheric temperature, while not to be correlated with solar activity itself. We have carried on the analysis with two subsamples in which stations located in the east and in the west. We find that the pH data derived from the eastern stations which are possibly polluted by sulfur oxides and nitrogen oxides are not correlated with the solar asymmetry, but with the temperature. On the contrary, the pH data obtained from the western stations are found to be marginally anti-correlated with the solar asymmetry. In addition, the pH data obtained from the western stations are found to be correlated with the solar UV radiation. We conclude by briefly pointing out that a role of the solar asymmetry in the process of acidification of rain is to be further examined particularly when the level of pollution by sulfur oxides and nitrogen oxides is low.

Calcium Lactate Affects Shelf-life and Firmness of Kimchi

  • Kim, Soon-Dong;Kim, Mee-Hyang;Kim, Mee-Jung
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.04a
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    • pp.136-136
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    • 2003
  • Calcium lactate has been known extending shelf-life of several lactic acid fermented foods through buffer action with lactic acid and binding of calcium and pectic polysaccharides in the tissue. But, the effects in kimchi during storage and distribution has not been observed. Calcium lactate is tasteless, nontoxic compounds commonly used in a number of food products. Recent observations have indicated the potential usefulness of calcium lactate as food additive which has anticariogenic-, antimicrobial-, anticalculus, anti- carcinogenic effects and enhancement of bone mineral density. In this work we determined the effects of calcium lactate(CaL)-treatment(0, 1, 2 and 3% against salted Chinese cabbage) on the pH, acidity, microbial counts, content of alcohol insoluble substance and calcium texture, color, scanning electron microscopic observation of kimchi tissue and sensory test during storage. pH of CaL treated kimchi were higher(3.78∼3.92) than that of control products(3.58). Total microbe(TM) of CaL treated kimchis were lower but ratio of lactic acid bacteria against TM was higher than those of control products, respectively. Calcium content of treated products were 3-5 times higher than control products. The hardness and crispy taste of treated products were remarkably higher than those of control products evaluated by SEM observation AIS analysis, sensory and textural analysis. Moreover, evaluation on the pH, acidity and sensory test showed the shelf-life of treated kimchi(CaL 2%) to be 25-30 days, which was 13-15 days longer than that of control products.

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Studies on Pollution Characteristics and Sources of Precipitation in Jeiu Island

  • Kang, Chang-Hee;Kim, Won-Hyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E4
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    • pp.191-201
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    • 2002
  • The pH, electric conductivity. and the major ionic components were analyzed for the precipitation samples collected at 1100 Site of Mt. Halla and Jeju city. The quality of analytical data was verified by the comparison of ion balances, conductivities and acid fractions, all of which correlation coefficients were over 0.952. The ionic strengths lower than 10$^{-4}$ M were found in 57 and 28% at 1100 Site and Jeju city respectively. The precipitation in Jeju city was influenced more by the oceanic effect than those in 1100 Site. The acidification of precipitation was caused mostly by S $O_4$$^{2-}$and N $O_3$$^{[-10]}$ in both areas, and the organic acids have contributed to the acidity with only 7~8%. The neutralization factors by N $H_3$ were about 44 and 47% at the 1100 site and the Jeju city, respectively, whereas those by CaC $O_3$were 21 and 24%, and the free acidity were about 38 and 28% at two sites. From the investigation of seawater and soil enrichment factors, the S $O_4$$^{2-}$, N $O_3$$^{[-10]}$ and N $E_4$$^{+}$ were immigrated by other sources rather than from the seawater or soil origins. but not in the case of $Mg^{2+}$, C $l^{[-10]}$ , N $a^{+}$, and $K^{+}$. Factor analysis has shown that the precipitation at the 1100 site had been influenced mostly by anthropogenic sources, followed by soil and sea-water sources. On the other hand, the precipitation at the Jeju city was mainly influenced by oceanic sources, followed by anthropogenic and soil sources.urces.

Applications of Discrete Wavelet Analysis for Predicting Internal Quality of Cherry Tomatoes using VIS/NIR Spectroscopy

  • Kim, Ghiseok;Kim, Dae-Yong;Kim, Geon Hee;Cho, Byoung-Kwan
    • Journal of Biosystems Engineering
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    • v.38 no.1
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    • pp.48-54
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    • 2013
  • Purpose: This study evaluated the feasibility of using a discrete wavelet transform (DWT) method as a preprocessing tool for visible/near-infrared spectroscopy (VIS/NIRS) with a spectroscopic transmittance dataset for predicting the internal quality of cherry tomatoes. Methods: VIS/NIRS was used to acquire transmittance spectrum data, to which a DWT was applied to generate new variables in the wavelet domain, which replaced the original spectral signal for subsequent partial least squares (PLS) regression analysis and prediction modeling. The DWT concept and its importance are described with emphasis on the properties that make the DWT a suitable transform for analyzing spectroscopic data. Results: The $R^2$ values and root mean squared errors (RMSEs) of calibration and prediction models for the firmness, sugar content, and titratable acidity of cherry tomatoes obtained by applying the DWT to a PLS regression with a set of spectra showed more enhanced results than those of each model obtained from raw data and mean normalization preprocessing through PLS regression. Conclusions: The developed DWT-incorporated PLS models using the db5 wavelet base and selected approximation coefficients indicate their feasibility as good preprocessing tools by improving the prediction of firmness and titratable acidity for cherry tomatoes with respect to $R^2$ values and RMSEs.

A Study on Physical Risk and Chemical Risk Analaysis of Seasoned Laver (조미 김의 물리적 위해요소와 화학적 위해요소 분석에 관한 연구)

  • Hwang, Yong-Il;Kim, Jin-Gon;Kwon, Sang-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.6
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    • pp.620-626
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    • 2017
  • This study conducted chemical and physical hazard analysis on the acidity, peroxide value, color removal, and limit criteria of metal detector of roasted laver. The Hunter color L- and a-value of roasted laver was higher than the control, and the b-value was higher at $400^{\circ}C$. The limit criteria establish by metal detector was determined to a sensitivity of 60 because it detected 100% in a sensitivity of 60 to Fe and Sus. The acidity and peroxide values increased with increasing temperature. These results confirmed that roasted laver is safe when roasted to $300^{\circ}C$ for 5 seconds.

Statistical Analysis of Ion Components in Rainwater (濕性大氣成分에 對한 統計的解析)

  • 李敏熙;韓義正;元良洙;辛燦基
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.1
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    • pp.41-54
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    • 1986
  • Methods used for averaging PH's of rainwater and site representation have been studied, Statistical analysis was attempted regarding effects of ionic components on PH's utilizing 847 data altogether obtained in two years, 1984 and 1985. The outcome of the study may be assumarized as follows: 1. Methods for Averaging PH Volume weighted method is considered to be acceptable providing that precipitation is measured at the same time when the samples are taken. Without precipitation data a simple averaging method should be the next choice. 2. Site Representation A statistical method used for optimizing a monitoring newtork was applied using the data collected. Because of a limited number of data, no discernible conclusion can be reached suggesting that the method can serve as a good guide when the data base becomes more reliable. 3. A good correlation appears to exist betwen conductivities and ionic components in rainwater. It would, therefore, be possible to certain extend to estimate ionic concentrations from conductivity measurements by correlation equations. 4. The acidity of rainwater is effected by $SO_4^{2-}, NO_3^-, Cl^- and NH_4^+ with SO_4^{2-}$ being the most significant as demonstrated by standardized regression analysis.

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The Study on the Quality of Pre-Processed Vegetables in School and Institutional Food-Service (단체급식에서 사용되는 전처리 농산물의 품질 특성 분석)

  • Lee, Seung-Joo;Lee, Seung-Mi
    • Korean Journal of Food Science and Technology
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    • v.38 no.5
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    • pp.628-634
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    • 2006
  • This study was performed to investigate the quality of pre-processed vegetables used in school and institutional food-services. Pre-processed food materials (carrot, potato, and cabbage) frequently used in food-service were collected from 14 various processing company sources. The sensory and physico-chemical qualities of the pre-processed food materials were determined using sensory and instrumental analysis. For the physico-chemical analysis of the food materials, pH, total acidity, hardness, Hunter colorimeter value, reducing sugar and vitamin C content were determined. For the sensory quality evaluation, 15 panelist were trained and consensus was reached on the quality standards of the preprocessed materials (carrot, potato, and cabbage). Finally, appearance, color, texture, off-odor/taste, and overall quality were determined. In the physico-chemical analysis, there were no significant differences among samples collected from various processing companies. In sensory quality evaluations, the color quality of pre-processed potato was lower than that of other materials. From the coefficient correlations and partial least squares regression analysis between sensory and instrumental data, pH, total acidity, colorimeter values, and hardness were considered important components in assessing the quality of pre-processed vegetables.