• Title/Summary/Keyword: acidic pH

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A Study on Organic Sludge Application and Duration Estimate for Treating Natural Purification of Acidic Mine Drainage (폐탄광폐수의 자연정화처리를 위한 유기성슬러지 적용 및 지속시간예측에 관한 연구)

  • Kim, Eun-Ho;Kim, Hyeong-Seok;Sung, Nak-Chang
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.3
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    • pp.475-484
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    • 2000
  • The purpose of this study was to develop model for estimating biodegrability of organic sludge (sewage and papermill) in various environmental conditions. to assume degradable degree with operating time of SRB reactor. and evaluate duratior of organic sludge as carbon source. Average TCOD was 28.7~63.2mg/L in effluent. organic sludge did not much supply carbon source for experimental period. But in point of durability. it seemed that organic sludge was efficient because it was not consumed by degradation of much organic matter within short period. With increasing $SO_4{^{2-}}$ reduction rate. Pb and Fe was removed 77~82% and 33~59%. respectively. Because Al was precipitated as a hydroxide. its removal rate wa,. about $54{\pm}2%$ in R-l~R-3 maintaining low pH but about 78% in R-4 maintaining high pH. Because Mn was large in solubility. it showed to be much lower than other heavy metals. Considering supportable capacity or durability of orgainc matter for initial SRB mixing ratio of sewage/papermill 0.5 was regarded as appropriate substituting material and at this time. it estimated that carbon source continued about 3.08 year but safety factor must apply to be thought over. because various factors had an effect on degradation of organic sludge.

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Quality Changes of Peeled Potato and Sweet Potato Stored in Various Immersed Liquids (다양한 침지액 보관에 따른 박피 감자와 고구마의 품질변화)

  • Park, Kee-Jai;Jeong, Jin-Woong;Kim, Dong-Soo;Jeong, Seong-Weon
    • Food Science and Preservation
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    • v.14 no.1
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    • pp.8-17
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    • 2007
  • The efficacy of strong acidic electrolyzed water (SAEW) at pH 2.53, with ORP of 1,088 mV and HClO concentration of 91.25 ppm, and low alkaline electrolyzed water (LAEW) at pH 8.756, with ORP of 534 mV and HClO concentration of 105.70 ppm, as storing liquids for peeled potato and sweet potato was evaluated in this study. During storage at $5^{\circ}C$, total phenolic contents and PPO activities of peeled potato and sweet potato stored in SAEW and LAEW were lower than those of control samples stored in tap racer (TW) with 0.85% (w/v) NaCl and 0.5% (w/v) sodium metabisulfite (SMS). Increment in color differences and decreases in hardness of peeled potato and sweet potato stored in SAEW and LAEW were lower than those of controls. Also, SAEW and LAEW inhibited growth of microorganisms for at least 3-6 days of storage. The sensory characteristics of peeled potato and sweet potato stored in LAEW were best during the first half of the storage period, compared to samples preserved by other methods.

Recycling of Acidic Etching Waste Solution Containing Heavy Metals by Nanofiltration (II) : Dead-end Nanofiltration of PCB Etching Waste Solution Containing Copper Ion (나노여과에 의한 중금속 함유 산성 폐에칭액의 재생(II) : 구리이온을 함유한 PCB 폐에칭액의 Dead-end 나노여과)

  • Nam, Sang-Won;Jang, Kyung-Sun;Youm, Kyung-Ho
    • Membrane Journal
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    • v.23 no.1
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    • pp.92-99
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    • 2013
  • In this study the nanofiltration (NF) membrane treatment of a sulfuric acid waste solutions containing copper ion ($Cu^{+2}$) discharging from the etching processes of the printed circuit board (PCB) manufacturing industry has been studied for the recycling of acid etching solution. SelRO MPS-34 4040 NF membrane from Koch company was tested to obtain the basic NF data for recycling of etching solution and separation efficiency (total rejection) of copper ion. NF experiments were carried out with a dead-end membrane filtration laboratory system. The pure water flux was increased with the increasing storage time in sulfuric acid solution and lowering pH of acid solution because of the enhancement of NF membrane damage by sulfuric acid. The permeate flux of acid solution was decreased with the increasing copper ion concentration. Total rejection of copper ion was decreased with the increasing storage time in sulfuric acid solution and copper ion concentration, and lowering the pH of acid solution. The total rejection of copper ion was decreased from initial 37% to 15% minimum value.

Basic Properties of Stones used for Cooking Utensils and Their Leaching Characteristics for Heavy Metal Elements (조리용구용 석재의 기초 특성과 중금속 원소의 용출 특성)

  • 진호일;김신자;김복란;민경원
    • Economic and Environmental Geology
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    • v.35 no.4
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    • pp.347-353
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    • 2002
  • Dominant rock types of stones used presently for cooking utensils in Korea are pyroxenite, breccia and biotite diorite. Pyroxenite and biotite diorite relatively abundant in mafic minerals have higher specific gravities of 3.0 than breccia of 2.5. Breccia shows the highest absorption (2.9%) among three stones used as cooking utensils and pH value of three stone types shows the alkaline range of 9.7 to 9.9. Among the studied stones used for cooking utensils, biotite diorite is the most durable against abrasion and has the highest strength and therefore, it is expected to be used effectively for the longest time except for other specific causes. Heavy metals such as Cu, Pb, Co, Cr and Ni were leached lower than their detection limit (0.1 ppm) regardless of reaction time and initial pH value of solution. But the leached contents of Fe are various with rock types and leaching conditions and those by acidic solution are generally 1.8 to 31 times higher than those by neutral solution. Breccia and biotite diorite show the highest leached content of Fe in cases of neutral and acidic solutions, respectively. Standard criteria of leached heavy metals and macrominerals should be studied thoroughly to utilize stones for cooking utensils of high quality which are harmless to the human body. Also it is required to examine mon detailed abiochemical properties of various stone types used for cooking utensils.

Quality Changes in Peeled Lotus Roots Immersed in Electrolyzed Water Prior to Wrap- and Vacuum-Packaging (전기분해수 침지처리 박피연근의 랩 및 진공포장 저장 중의 품질변화)

  • Park, Kee-Jai;Jeong, Jin-Woong;Lim, Jeong-Ho;Kim, Bum-Kun;Jeong, Seong-Won
    • Food Science and Preservation
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    • v.15 no.5
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    • pp.622-629
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    • 2008
  • This study investigated changes in quality characteristics of wrap- and vacuum-packaged peeled lotus roots treated with strong acidic electrolyzed acid water (SAEW pH 2.58, ORP 1,128 mV, HClO 105.0 ppm) or low alkaline electrolyzed water (LAEW pH 8.56, ORP 660 mV, HClO 73.8 ppm) as immersion liquids prior to packaging and storage at 5C. Immersion of peeled lotus roots in SAEW and LAEW reduced initial microbial load by about 1 log compared to treatment with tap water (TW). Hardness differences on storage were observed. However, reduction in PPO activity by electrolyzed water was not reproducible. Changes in Hunter's color value and the color difference value ($\Delta$) of peeled lotus roots immersed in 0.5% (w/v) sodium metabisulfite (SMS) and electrolyzed water were smaller than those of roots treated with TW prior to storage. Sensory characteristics measured during storage were best-preserved in lotus roots previously immersed in 0.5% (w/v) SMS or electrolyzed water, compared to TW. Immersionin electrolyzed water and vacuum packaging preserves the quality of peeled lotus roots in terms of microbial, visual, and sensory aspects, at levels comparable to those offered by storage after treatment with 0.5% (w/v) SMS.

As(III) Oxidation and Phenol Adsorption by the Activated Carbon Impregnated with Mn Oxide (망간산화물이 첨착된 활성탄에 의한 페놀흡착 및 비소(III) 산화)

  • Yu, Mok-Ryun;Yang, Jae-Kyu;Chang, Yoon-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.4
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    • pp.423-429
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    • 2008
  • Application of manganese-impregnated activated carbon(Mn-AC) in the treatment of synthetic wastewater containing both organic and inorganic contaminants was investigated. Phenol and As(III) was used as representative organic and inorganic contaminants, respectively. When the stability of Mn-AC at acidic condition was evaluated with variation of solution pH ranging from 2 to 4, Mn-AC was unstable below pH 3, while negligible dissolution of Mn was observed above pH 4. This stability test suggests a plausible applicability of Mn-AC in the treatment of wastewater above pH 4. Compared to AC-alone, the adsorption rates of phenol as well as adsorbed amounts of phenol by Mn-AC were slightly decreased due to the decrease of the surface area by impregnation. The maximum adsorbed amount of phenol by Mn-AC was corresponds to 75% of that by AC-alone from the adsorption isotherm study. The oxidation efficiency of As(III) by Mn-AC was greater than that by AC-alone at lower pHs while reverse trend was observed as pH increased above 7. From this work, it was found that Mn-AC could be used in the simultaneous treatment of both phenol and As(III).

Chemical Analysis of Transplanted Aquatic Mosses and Aquatic Environment during a Fish Kill on the Chungnang River, Seoul, Korea

  • Lee, Joohyoung;Green, Perry-Johnson;Lee, Eun-Ju
    • Animal cells and systems
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    • v.6 no.3
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    • pp.215-219
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    • 2002
  • In mid-April, 2000, hundreds of thousands of fish floated dead on the Chungnang River, one of the small branches of the Han River in Seoul. We examined the causes of the accident in detail, through analysis of monitorinq data from the Han River Monitoring Project, which employed the transplanted aquatic moss, Fontinalis antipyretica. This allowed investigation of another possible cause of the fish kill: release of trace metals into the river from industrial sources during the rainfall event. In addition, we aimed to verify the usefulness of aquatic mosses as bioindicators of the event. Water samples collected 48 h after the fish kill exhibited low pH and high Total-N and Total-p, indicating that acidic compounds rich in nitrogen and phosphorus might be a major contaminant. BOD and COD were also very high. On the whole, the conditions of the river water were degraded at that time. Distinct trends were not observed in the chlorophyll phaeophy-tinization quotient and photosynthesis rate of transplanted mosses. How-ever mosses sampled soon after the accident exhibited the lowest values for those variables (P < 0.01), suggesting that stress factors in the river were diluted out over time. Heavy metals with characteristics of industrial effluents (Cr, Pb, Zn, Fe, Cu, and Cd) increased (p < 0.01), indicating that they were unlikely to be major causes of the accident.

Effects of Temperature on Flocculation Kinetics Using Fe(III) Coagulant in Water Treatment (정수처리시 Fe(III) 응집제를 사용한 응집동력학에 대한 온도의 영향)

  • 강임석
    • Journal of Environmental Science International
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    • v.4 no.2
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    • pp.181-194
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    • 1995
  • Flocculation kinetics using ferric nitrate as a coagulant to coagulate kaolin clay in water was examined as a tool to investigate the effect of low temperature under tightly controlled treatment conditions. Both the particle size distribution data obtained from Automatic Image Analysis (AIA) system and the on-line measurement of the degree of turbidity fluctuation in a flowing suspension by Photometric Dispersion Analyzer (PDA) were used to measure flocculation kinetics. Results show that cold water temperature had a pronounced detrimental effect on flocculation kinetics. For improving flocculation kinetics at low water temperature, maintaining constant pOH to adjust water chemistry for temperature changes was found to be partially effective only in the more acidic pH range studied.

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Reducing Microbial Populations on Refrigerated Pork Hams Treated with Acetic Acid (초산으로 처리한 냉장 돼지고기 햄의 미생물 증식억제)

  • 이재일;신은하;김창렬;김광현
    • The Korean Journal of Food And Nutrition
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    • v.9 no.4
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    • pp.484-489
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    • 1996
  • The influence of acetic acid (AA) dips on aerobic plate counts (APC), gram-negative bacterial counts (GNC), pH, and sensory tests of pork hams was studied during storage at 4$^{\circ}C$. Pork hams were treated by dipping in 0.5~3.0%(v/v) AA for 0~3 min. Treatments of 1.0~3.0% AA for 3 min completely (P<0.05) inhibited the GNC for 12 days of storage. Treatments of 3.0% AA for 3 min completely (P<0.05) inhibited the APC for 12 days of storage. Treatments with 1.0~3.0% AA for 0~3 min prolonged the microbiological shelf-life to 12 days of storage. Sensory evaluations of pork hams treated with acetic acid were liked less than the fresh controls due to acidic odor and whitness.

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Isolation of Cellulolytic Microorganisms and their Physiological Characteristics (섬유소분해균의 분리 및 그의 생리학적 특성)

  • 홍순우;하영칠;민경희;이영하
    • Korean Journal of Microbiology
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    • v.14 no.1
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    • pp.17-24
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    • 1976
  • Celluloytic microorgnasims were isolated form the various sources and four of them were identified as Trichoderma roningi, Aspergillus niger, Penicillium chrysogenum, and Streptomyces sp. The induction of extracellular5 cellulase of these species in the liquid culture media containing carboxymethylcellulose (CMC) or Avicel as inducer showed that CMC was a better effective inducer for the production of CMCase(Cx cellulase component) as well as Avicelase(C$_{1}$ cellulase component) than Avicel. It is believed that certain hydrolysis products of cellulose(CMC) could serve as an inducer for an enzyme synthesis. In T. roningi, Asp. niger, and Strptomyces sp., the optimum temperature of CNCase on CMC-culture medium was 50.deg. but temperature around 40.deg.C was found to be optimum for the activities of CMCase prepared from P.ehrysogenum. The optimum temperature for Avicelase activitiles on Avicel-culture media of T. roningi and P. chrysogenum was $40{\circ}C$ whereas temperature $50{\circ}C$ was found to be optimum for Avicelase from A.niger and Streptomyces sp. The optimal activities of these CNCase and Avicelase prepared from. T. ronigi, Pen.chrysogenum and Streptomyces sp. were found similarly to be at pH's around 5.4 and 6.0 while pH 4.8 was optimum for the activities of CMCase and Avicelase from A.niger, indicating that A.niger in acidic media would yield an enzyme of high activity.

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