• Title/Summary/Keyword: acidic pH

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Swelling Patterns and relevant Hydraulic Conductivities of Na-Bentonite under Various Acidic and Alkali conditions (산과 알칼리 조건하에서 Na-벤토나이트의 팽창경향과 상대적 수리전도도)

  • Chung, Doug-Young;Yang, Jae E.;Oh, Taek-G.;Lee, Kyo-S.
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.1
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    • pp.71-76
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    • 2007
  • We investigated the effects of solution pH on swelling characteristics and relevant hydraulic conductivity of different particle sizes of Na-bentonite which have significantly high swelling capacity. The results showed that the time taken to reach the maximum swelling indexes for all pH levels ranged from 84 hours and 156 hours for pH 6.5 or above by NaOH and pH 3.5 by HCl, respectively. The maximum swelling index slightly increased with increasing particle size, while the maximum swelling indexes were less or approximately half of that of the indigenous Na-bentonite. The changes in swelling indexes before and after solution treatment were distinctive in acidic condition, especially in pH 3.5 by HCl while there were not much differences in alkali condition. For hydraulic conductivities of fully swelled Na-bentonite in a given solution pH, elution did not occur under pressure below 1 bar. But elution started as the pressure was raised to 1.5 bars or above after 500 seconds. The stabilized hydraulic conductivities observed from 1.5, 3.0, and 5.0 bars ranged from $7{\times}10^{-3}cm\;day^{-1}$ to $6{\times}10^{-3}cm\;day^{-1}$, indicating that the hydraulic conductivities were slightly higher in acidic condition than that of normal condition.

The Effects of Turbidity and pH on the Removal of Cryptosporidium and Giardia by Coagulation Process (원수 탁도와 pH 변화가 혼화응집침전 과정에서 원생동물과 탁질 제거에 미치는 영향)

  • Chung, Hyen-Mi;Park, Sang-Jung
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.1
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    • pp.71-78
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    • 2006
  • The removal of protozoa in the coagulation process was evaluated under the different pH and turbidity using the jar test after the addition of polyaluminium chloride (PAC) as a coagulant. Two well-known protozoa of Cryptosporidium parvum and Giardia lamblia were tested at the same time with turbidity, the critical water quality parameter of the water treatment process. Both protozoa were removed about 1log (and up to 2log) at the optimum injection of PAC. The source water turbidity and pH affected the removal of protozoa and turbidity. At neutral and alkaline pH, 1.3-1.7log removal of protozoa for low turbid water with 5NTU, and 1.6-2.3log removal for high turbid water with 30NTU were achieved. However, at acidic pH, maximum 0.8-1.0log and 1.1-1.2log were removed for low and high turbid water, respectively, at the optimum PAC injection of 15mg/L. The relation of protozoa and turbidity removals were expressed as the 1st order equation (significantly positive relation) in the most of the tested conditions. In addition, the relation of protozoan removals with residual turbidity were also expressed the 1st order equation (significantly negative relation), although the significance of the equations were reduced at acidic pH. Therefore, residual turbidity could be a good index of efficient protozoan removal in the coagulation process, probably except at the low pH condition.

Effect of Extraction Temperature and pH on the Chemical Properties of Crude Porphyran Extracted from Porphyra yezoensis (추출온도 및 pH가 김에서 추출한 Crude Porphyran의 화학특성에 미치는 영향)

  • PARK Jin-Hee;KOO Jae-Geun;DO Sung-Ryong;YANG Cha-Bum;WOO Sang-Kyu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.1
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    • pp.127-131
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    • 1998
  • The effect of extraction temperature ($60\~100^{\circ}C$) and pH ($2.0\~13.5$) on the yield and chemical compositions of crude porphyran from Porphyra Yezoensis was investigated. The yield and chemical compositions of crude porphyran were greatly affected by extraction pH and temperature. Yield was highest between pH $3\~4$ at all temperature ranges. Crude porphyran extracted in acidic conditions showed more sulfate and less protein content than extracted in neutral conditions, but molecular weights was decreased. Crude porphyran extracted in alkaline conditions showed low sulfate and high protein content. For high yield and low molecular weight, acidic condition, particulary pH $3\~4$, was effective. But in order to avoid molecular weight degradation, neutral conditions were effective.

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Enzymatic Bleaching of Kraft-pulp with Horseradish Peroxidase and Radical Mediator (Horseradish Peroxidase와 라디칼 전달체를 이용한 Kraft 펄프의 표백)

  • 류근갑;권오열
    • KSBB Journal
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    • v.16 no.2
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    • pp.179-182
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    • 2001
  • The use of 2,2-azinobis(3-ethylbenzthiazoline-6-sulfonic acid)(ABTS) as a radical mediator enhanced the bleaching efficiency of kraft pulp by horseradish peroxidase(HRP) and $H_2O_2$. High concentrations of up to 20 mM $H_2O_2$. were used. The bleaching of the kraft pulp increased as the amount of HRP and ABTS concentration were inceased up to 0.3 mg/90 mL and 2 mM, respectively. The bleaching of the kraft pulp was closely related with the HRPs activity and its adsorption onto the pulp. The activity of HRP and bleaching of kraft pulp were maximum at pH 7 and were reduced either in a acidic or alkaline solutions. The adsorption of HRP onto pulp was low in solutions of pH 6-8 and high in an acidic(pH5) and an alkaline solutions(pH 9). The adsorption of the enzyme was greater for alkali-lignin than for crystalline cellulose, the two major components of pulp.

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The Characteristics of Electrokinetic Remediation for Unsaturated Soil (불포화토의 동전기정화 특성에 관한 실험적 연구)

  • 김병일;김익현;한상재;김수삼
    • Proceedings of the Korean Geotechical Society Conference
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    • 2003.03a
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    • pp.641-646
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    • 2003
  • In this study, a series of electrokinetic(EK) remediation experiments are carried out under the different degree of saturation for contaminated soil with lead. for constant electrical potential, the final current of all the sample represents the similarity to steady-state value of 5∼7mA. Under conditions of all the degree of saturation the anode reservoir becomes acidic(pH as low as 3) while the cathode reservoir is basic(pH as high as 12). But pH changes in the sample is a little and decontamination efficiency is the low.

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The Degradation of Indomethacin in Aqueous Solution (수용액에 있어서의 Indomethacin 분해)

  • 전인구;이민화;우종학
    • YAKHAK HOEJI
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    • v.20 no.1
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    • pp.76-82
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    • 1976
  • The base-catalyzed hydrolysis of indomethacin over a range of pH 8,2 to 10.0 was investigated, according to the first order kinetic equation. The energy of activation for the reaction was calculated 20, 18 kcal/mole from the Arrhenius plot. And the optimal pH of indomethacin in aqueous solution was estimated as pH 4.93 by the extrapolation of the log k-pH profiles in strong acidic and alkaline regions. And the influences of alkaline earth metals, heavy metals and some other compounds on the degradation of indomethacin were observed with no effect.

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Increase of Yeast Survival under Oxidative Stress by the Expression of the Laccase Gene from Coprinellus congregatus

  • Kim, Dong-Sik;Kwak, Eun-Jung;Choi, Hyoung-T.
    • Journal of Microbiology
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    • v.44 no.6
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    • pp.617-621
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    • 2006
  • Coprinellus congregatus secreted a laccase isozyme when the culture was transferred to an acidic liquid medium (pH 4.1). The laccase cDNA gene (clac2) was used as a probe for cloning of the genomic laccase gene (lac2) including the promoter (Plac2). The open reading frame (ORF) of lac2 had 526 deduced amino acids and four conserved copper binding domains as other fungal laccases. Recombinant plasmid (pRSlac2p-cDNA) of lac2 cDNA with its own promoter was transformed in Saccharomyces cerevisiae. Expression of the transformed lac2 gene was induced by oxidative stress ($H_2O_2$) in yeast and the survival rate of the transformed yeast strain was greatly increased when compared with that of the control strain transformed with pRS316 yeast vector.

Esophageal pH and Combined Impedance-pH Monitoring in Children

  • Shin, Myung Seok
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.17 no.1
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    • pp.13-22
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    • 2014
  • Esophageal pH monitoring is considered the gold standard for the diagnosis of gastroesophageal reflux disease because of the normal ranges across the pediatric age range. However, this method can only detect acid reflux. Multichannel intraluminal impedance-pH (MII-pH) monitoring has recently been used for the detection of bolus reflux in infants and children. This method allows for the detection of liquid, gas or mixed reflux in addition to acid, weakly acidic or weakly alkaline reflux. MII-pH monitoring can record the direction of flow and the height of reflux, which are useful parameters to identify an association between symptoms and reflux. However, the technique is limited by its high cost and the lack of normative data of MII-pH in the pediatric population. Despite certain limitations, MII-pH monitoring will become more common and gradually replace pH monitoring in the future, because pH monitoring is part of MII-pH.

Saprolegnia ferax에 의한$\beta$-amylase의 생산 및 특성

  • Bai, Suk;Cho, Nam-Chul;Chun, Soon-Bai
    • Microbiology and Biotechnology Letters
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    • v.25 no.2
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    • pp.109-114
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    • 1997
  • The Oomycete Saprolegnia ferax produces an extracellular $\beta$-amylase, Maximum enzyme yield was attained after 7 days of growth in YNB starch medium (pH 6.5) at 25$\circ$C. The amylase was pu- rified 24-fold by ultrafitration, HPLC DEAE column and HPLC gel filtration. The purfied enzyme was a monomeric glycoprotein with a molecular weight of about 44,000 dalton. The pH and temperature optima were 6.5 and 50$\circ$C, respectively. The enzyme was fairly stable up to 50$\circ$C and at acidic pH region (pH 4.0-7.0). The apparent Km and Vmax values of the enzyme against soluble starch were 0.77 mg/ml and 2,174 $\mu$moles/mg protein, respectively. Amino acid analysis indicated that the enzyme was enriched in alanine, glycine, leucine and acidic amino acid. Starch hydrolysis with the enzyme released maltose but not glucose, whereas maltotriose, Schardinger dextrin ($\alpha$-cyclodextrin) and pullulan were not hydrolysed by the enzyme. The enzyme was inhibited by Schardinger dextrin, p-chloromercuribenzoate(PCMB), CU$^{2+}$' and Hg$^{2+}$. Inhibition of the enzyme by PCMB could be reversed by the addition of cysteine and mercaptoethanol.

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Influences of Extraction pH on the Functionality of Soybean Protein Isolate (추출 pH가 분리대두단백질의 기능성에 미치는 영향)

  • Bae, Song-Hwan;Rhee, Chul
    • Korean Journal of Food Science and Technology
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    • v.30 no.3
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    • pp.557-561
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    • 1998
  • This study was conducted to investigate the functionality of soybean protein isolates extracted in acidic range (pH 2.0 and 3.0), neutral range (pH 7.0) and alkaline range (pH 10.0 and 12.0). The protein content of soybean protein isolates extracted at pH 3.0 was maximum (93.31%), but that of pH 7.0 was minimum (73.93%). The extraction yield of soybean protein isolates extracted at pH 3.0 was minimum (0.36%), but that of pH 12.0 was maximum (47.54%). The functionality (solubility, water absorption, oil absorption, foam capacity, foam stability, emulsion capacity and gelation) of soybean protein isolates was significantly influenced by pH of extraction medium. The soybean protein isolates extracted at pH 2.0 and 3.0 were more soluble at acidic ranges and those of pH 3.0 and 7.0 were more soluble at neutral ranges, but those of pH 2.0, 3.0, 7.0, 10.0 and 12.0 were more soluble at alkaline ranges than other ranges. The soybean protein isolates extracted at pH 2.0 and pH 12.0 gave greater water absorption, oil absorption and foam capacity than those extracted at pH 3.0, pH 7.0 and pH 10.0. And the emulsion capacity of soybean protein isolates was increased by the increase of extraction pH.

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