• 제목/요약/키워드: acid strength

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Ophthalmic Application of Hydrogel Polymer Containing Carbon Nanomaterials

  • Seok, Jae-Wuk;Geum, Yong-Pil;Shin, Dong-Seok;Sung, A-Young
    • Journal of Integrative Natural Science
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    • v.12 no.4
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    • pp.116-121
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    • 2019
  • This experiment is to evaluate the physical properties of the hydrogel lens with the addition of carbon-based nanomaterials, Graphene oxide and Carbon nanotube, and to confirm the improvement of strength. Hyaluronic acid, a hydrophilic substance, was used as an additive by using HEMA (2-hydroxyethyl methacrylate) and ethylene glycol dimethacrylate (EGDMA) as a base monomers. Graphene oxide and two types of Carbon nanotubes(Amide functionalized and Carboxilic acid functionalized) were added 0.1%, 0.3%, 0.5%, respectively, and the physical properties were analyzed by measuring water content, refractive index, breaking strength and SEM image. In the case of the sample added with each carbon nano material, the water content tended to increase for all three materials. The breaking strength tended to increase in Graphene oxide and Carbon nanotube; Carboxilic acid functionalized, but in the case of Carbon nanotube; amide fuctionalized, the breaking strength tended to decrease. However, Carbon nanotube; amide fuctionalized had the highest breaking strength among the three nano materials. Thus, the addition of certain carbon nanomaterials seems to be appropriate for improving the strength of hydrogel lenses.

Studies on Adhesion and Mechanical Properties of Casting Polyurethane Elastomer with Acid Groups (Acid Group이 도입된 Casting 폴리우레탄 탄성체의 접착 및 기계적 물성에 관한 연구)

  • Mok, Dong Youb;Shin, Hyun Deung;Kim, Dong Ho;Kim, Gu Ni;Moon, Hyung Suk;Kim, In-Soo
    • Journal of Adhesion and Interface
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    • v.14 no.2
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    • pp.68-74
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    • 2013
  • We synthesized polyurethane elastomer containing acid groups. We measured the adhesion, grip, tensile strength and mechanical properties. Casting polyurethane elastomers were prepared with the contents of acid. The adhesive strength and the wet slip were increased. Also, the tensile strength and abrasion properties were increased. We measured the properties with different acid contents. Increasing the acid content, the mechanical properties were increased. But the mechanical properties were decreased above 0.20 wt% of acid content. The wet slip was increased and the contact angle was decreased as the acid content increased.

A Study on the Recycled Fine Aggregate and Properties of Mortar by the Acid Treatment (산처리에 의한 순환잔골재의 품질과 모르타르의 특성에 관한 연구)

  • Kim Ha-Suk;Sun Joung-Soo;Kawg Eun-Gu;Han Ki-Suk;Lee Do-Heune;Kim Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.81-84
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    • 2006
  • This study is intended for how to utilize the recycled fine aggregate which is produced by concrete wastes. It analyzes the quality of the fine aggregate which is reproduced through the acid treatment process, and comprehends the characteristics of mortar using the recycled fine aggregate to review whether it can be put to practical use for concrete. The conclusion of the study are as follows 1. The recycled fine aggregate through the acid treat shows the low rate of absorption and high density. 2. Compared to the mortar made from acid liquid precipitated recycled fine aggregate, using nature water precipitated one reduces the flow. 3. The compressive strength of mortar using recycled fine aggregate tends to be reduced according to the kind of precipitated water. Based on the above results, the recycled fine aggregate through the acid treatment process satisfies the quality standards of the first-grade recycled fine aggregate of KS F 2573 (recycled fine aggregate for concrete) but it is concluded that the recycled fine aggregate through the acid treatment process can not used as fine aggregate used concrete because it has destructive characteristics when the mortar is produced

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Development of Ultra-Lightweight High Strength Trench Using Lightweight Polymer Concrete

  • Sung, Chan-Yong;Kim, Young-Ik
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.7
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    • pp.20-26
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    • 2003
  • The ultra-lightweight high strength polymer concrete could be used for the drain structures under severe condition. In this study, materials used were unsaturated polyester resin, heavy calcium carbonate, artificial lightweight coarse aggregate and perlite. In the test results, the unit weight of the ultra-lightweight high strength polymer concrete was 946 kg f/$\textrm{m}^3$ and the compressive strength was appeared in 34.5 MPa. The compressive strength, splitting tensile strength, flexural strength, acid resistance and weather resistance were shown in excellently than that of the normal cement concrete. The draining trench had 1m length, 0.24 m width, 0.02 m thickness and 0.07 m height. The developed trench could be effectively used at the draining structures.

A STUDY ON THE SHEAR BOND STRENGTH OF THE COMPOSITE RESIN TO GLASS IONOMER CEMENT ACCORDING TO SURFACE TREATMENT METHODS OF GLASS IONOMER CEMENT (글라스 아이오노머 시멘트의 표면처리방법에 따른 복합레진과의 전단결합강도에 관한 연구)

  • No, Bong-Hwan;Hwang, Ho-Keel;Cho, Young-Gon
    • Restorative Dentistry and Endodontics
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    • v.20 no.1
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    • pp.362-371
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    • 1995
  • The purpose of this study was to evaluate the shear bond strength between composite resin and glass ionomer cement according to surface treatment methods of glass ionomer cement. Sixty round acrylic cylinders were fabricated. And then, a round undercut cavity(8 mm diameter, 2.5mm depth) was prepared in the center of the every acrylic cylinder. After all cavities were restored by using light-cured glass ionomer cement. A total of sixty acrylic cylinders restored with glass ionomer cement were divided into 4 groups according to surface treatment methods of glass ionomer cement. The surface treatment of each group were as follows : control group : no treatment Group 1 : acid etching Group 2 : sandblasting Group 3 : air-podwer abrasive polishing The composite resin was bonded to glass ionomer cement of each specimens. And the shear bond strength was tested with a universal testing machine at a cross-head speed of 1mm/min and 500kg in full scale. The results were as follows : 1. The sandblasting group(group 2) had the highest shear bond strength with $272.50{\pm}24.96\;kg/cm_2$ and the acid etching group(group 1) had the lowest shear bond strength with $192.89{\pm}29.32kg/cm_2$. 2. The no treated group(control group) had higher shear bond strength than acid etching group(group 1) (p<0.05). 3. The sandblasting group(group 2), air-powder abrasive polishing group(group 3) and no treated group(control group) had higher shear bond strength than the acid etching group(group 1) (p<0.05). 4. The sandblasting group(group 2) and air-powder abrasive polishing group(group 3) had higher shear bond strength than the no treatment group(control group), but there was not significant(p>0.05).

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Effect of Acrylic Acid Contents and Inorganic Fillers on Physical Properties of Acrylic Pressure Sensitive Adhesive Tape by UV Curing (아크릴산 함량 및 무기물 충전제가 UV 경화형 아크릴 점착테이프의 물성에 미치는 영향)

  • Kim, Dong-Bok
    • Polymer(Korea)
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    • v.37 no.2
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    • pp.184-195
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    • 2013
  • Acrylic pressure sensitive adhesive (PSA) tapes were used for the automotive, the electrical and the electronic industries and the display module junction. In this study, the manufacture of high-strength structural tape used 2-ethylhexyl acrylate (2-EHA) and acrylic acid (AAC), and UV irradiation for photo-polymerization, and the semi-structural properties of acrylic PSA tape with the AAC content and inorganic filler $SiO_2$ content were investigated. The initial adhesion strength was lowered by the rigidity of molecule chains due to the use of AAC, and the adhesion strength increased with increasing wetting time. The wetability, contact angle, and SEM images of PSA tapes with various contents of AAC were determined. Without filler, the peel strength and dynamic shear strength of PSA tape showed inverse correlation but the peel strength and dynamic shear strength increased with increasing filler content. From these correlations the PSA tapes could be optimized for the applications requiring high performance.

Effect of Acid Fog on Rust Formation and Fatigue Strength of Weathering Steel (산성안개가 내후성강재의 녹형성 및 피로강도에 미치는 영향)

  • Kim, Min-Gun;Ku, Eun-hoi
    • Journal of Industrial Technology
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    • v.22 no.B
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    • pp.13-20
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    • 2002
  • The purpose of this study is to investigate the effect of acid fog on the rust formation behavior of weathering steel (SMA50) which is used in uncoated bridges. Weathering steel didn't form the passive film under the environment of acid fog(pH5,6), whereas the environment of distilled water formed the protective oxide film. Therefore, the construction of weathering steel under the environment extremely exposed to SOx and NOx which are the main compositions of acid fog is not adequate. Fatigue limits of weathering steel under acid fog environment are remarkably decreased as compared with environment of distilled water. The corrosive constituents in acid fog has piled up the corrosion products on specimen surface and generated the corrosion pits. Because of the high stress concentration arising at this corrosion pit, relatively low fatigue limits were obtained for acid fog specimens.

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THE EFFECT OF $CO_2$ LASER IRRADIATION ON ENAMEL SURFACE AND THE BOND STRENGTH OF SEALANT MATERIAL (탄산가스 레이저 조사가 법랑질 표면구조와 치면열구 전색재의 결합강도에 미치는 효과)

  • Yun, Dong-Sik;Kim, Yong-Kee;Kim, Jong-Soo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.25 no.4
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    • pp.761-771
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    • 1998
  • In this study, attempt has been made to evaluate the effect of $CO_2$ laser irradiation on enamel surface structure and the bond strength of sealant material. Conventional acid etching was used as a control technic for comparison. The results obtained from this experiment were as follows; 1. The highest mean shear bond strength value was observed in samples of Group I (acid-etching) with the statistical significance(p<.05) between all the other groups. 2. The shear bond strength in Group IV was the lowest among laser etching groups. but there were no significant difference between them(p>.05). 3. Scanning electron microscopic observation showed that the rough and irregular surface was created by $CO_2$ laser treatment with the formation of numerous pores, micro-cracks, and small bubble-like inclusion. Increasing the energy density induced localized surface melt with a thin smooth glaze-like appearance. 4. In acid-etched control specimen cohesive failure predominated, whereas adhesive failure was the main mode in laser-treated group. Based upon the above-mentioned results, it can be assumed that the $CO_2$ laser is not an adequate substitute for the acid-etch technique in enamel preconditioning. More studies are required to explore the effective condition of laser irradiation which could attain the better bond strength of restorative materials.

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Effect of zirconia surface treatment using nitric acid-hydrofluoric acid on the shear bond strengths of resin cements

  • Cho, Jin Hyung;Kim, Sun Jai;Shim, June Sung;Lee, Keun-Woo
    • The Journal of Advanced Prosthodontics
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    • v.9 no.2
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    • pp.77-84
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    • 2017
  • PURPOSE. The aim of this study was to compare the surface roughness of zirconia when using Zircos E etching system (ZSAT), applying a nitric acid-hydrofluoric acid compound as a pretreatment agent, and also to compare the shear bonding strength according to different resin cements. MATERIALS AND METHODS. ZSAT, air abrasion, and tribochemical silicacoating were applied on prepared 120 zirconia specimens (10 mm in diameter, 7 mm in height) using CAD/CAM. Each 12 specimens with 4 different resin cements (Panavia F 2.0, Rely X Unicem, Superbond C&B, and Hot bond) were applied to test interfacial bond strength. The statistical analysis was performed using SAS 9.1 (SAS Institute Inc., Cary, NC, USA). The results are as follows: after application of the ZSAT on the zirconia specimens, surface roughness value after 2-hour etching was higher than those after 1- and 3-hour etching on SEM images. RESULTS. For Superbond C&B and Rely X Unicem, the specimens treated with ZSAT showed higher shear bond strength values than those treated with air abrasion and tribochemical silicacoating system. Regarding the failure mode of interface over cement and zirconia surface, Rely X Unicem and Hot bond showed cohesive failures and Panavia F 2.0 and Superbond C&B showed mixed failures. CONCLUSION. Zircos E etching system in zirconia restoration could increase its shear bond strength. However, its long term success rate and clinical application should be further evaluated.

AN EXPERIMENTAL STUDY ON THE TENSILE STRENGTH OF COMPOSITE RESIN TO ETCHED DENTIN SURFACE (상아질면(象牙質面)에 대(對)한 복합(複合)resin 인장강도(引張強度)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Pak, Sun-Jae;Choi, Ho-Young;Park, Sang-Jin
    • Restorative Dentistry and Endodontics
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    • v.8 no.1
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    • pp.107-113
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    • 1982
  • The purpose of this study was to observe the tensile strength of composite resins to etched dentin surface with the various methods of placing bonding agent before composite resin or placing composite resin alone. Recently extracted 60 maxillary incisors were chosen. These were divided into 6 groups: Group I : Immediate Silar adaptation to the etched dentin surface with 37% phosphoric acid for 60 seconds without bonding agent. Group II : Immediate Silar adaptation to the etched dentin surface with 37% phosphoric acid for 60 seconds with bonding agent. Group III : Silar adaptation to the etched dentin surface with 37% phosphoric acid for 60 seconds after 5 minutes of bonding agent. Group IV : Immediate Enamelite adaptation to the etched dentin surfaces with 50% phosphoric acid for 120 seconds without bonding agent. Group V : Immediate Enamelite adaptation to the etched dentin surface with 50% phosphoric acid for 120 second s with bonding again. Group VI : Enamelite adaptation to the etched dentin surface with 50% phosphoric acid for 120 seconds after 5 minutes of bonding agent. All specimens were immersed in water at $37^{\circ}C$ for 24 hours before testing. The results were as follows: 1. The tensile strength of powder/liquid composite resin system was higher than that of pastel paste composite resin system. 2. The tensile strength of the composite resin group II, III, V, & VI with bonding agent was higher than that of the composite resin group I & IV without bonding agent. 3. The tensile strength of the composite resin group III & VI after 5 minutes added to bonding agent was higher than that of the composite resin group II & V immediately added to bonding agent.

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