• 제목/요약/키워드: acid strength

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친환경 유기산 재료를 활용한 지반개량 공법의 현장 적용성 평가 (The Evaluation of the Field Applicability of the Soil Improving Method Using the Environment-friendly Organic Acid Material)

  • 이종휘;홍종욱;;천병식
    • 한국지반공학회논문집
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    • 제28권9호
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    • pp.85-95
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    • 2012
  • 유기산 재료를 이용한 지반 개량은 미생물을 배양하여 지반의 고결화로 인해 친환경적으로 지반의 강도를 증대시키는 방법으로 다양한 토질 성상에 대해 유기산 재료를 혼합 후 미생물 증식으로 강도 증대효과를 규명한 바가 있으나, 현재까지 현장 적용성을 평가한 바가 없다. 본 논문에서는 유기산재료를 이용하여 지반의 미생물 증식으로 인한 지반 고결화에 대해 연구를 실시하였으며, 이를 위해 재령 56일까지 동평판재하시험, 동적콘관입시험, 들밀도시험, SEM-EDS분석을 통해 지반강도의 변화에 대해 규명하였다. 시험 결과, 유기산 재료를 첨가한 지반의 강도와 강성은 증가하는 경향을 나타냈으며, SEM-EDS로부터 탄산칼슘의 증가를 규명할 수 있었다. 향후 유기산 재료를 활용한 친환경적인 지반개량 공법의 지속적인 연구와 관심이 필요하다고 사료된다.

패분을 혼입한 콘크리트의 물리.역학적 특성 및 내산성에 관한 실험적 연구 (Experimental study on the Physical and Mechanical Properties and Acid-Resistance of Concrete with Oyster Shell)

  • 서대석;민정기;정현정;남기성;성찬용
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 1999년도 Proceedings of the 1999 Annual Conference The Korean Society of Agricutural Engineers
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    • pp.319-323
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    • 1999
  • This study is performed to evaluate the physical and mechanical properties and acid-resistance of oyster shell concrete. The result shows that the unit weights of concrete with oyster shell are decreased by 1∼2% than that of the normla cement concrete. The highest strength is achieved by 2.5% oyster shell filled oyster shell concrete, it is increased compressive strength by 4% , tensile strength by 6% and bending strength by7% than that of the normal cement concrete, respectively . The acid-resistanceis increased with increase of the content of oyster shell. It is 1.6 times of the normal cement concrete by 15% oyster shell filled oyster shell concrete. Accordingly, oyster shell concrete will improve the properties of concrete.

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황산의 침해를 받은 슬래그 경화체의 특성 (The Acid-Resistance Properties of Hardened Alkali-Activated Slag Composites)

  • 김원기;소정섭;배동인
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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    • pp.313-317
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    • 2003
  • The study is the results of accelerated tests and the specimens, mortars, are submerged in a 5% sulfuric acid solution. The deterioration of specimens is followed up by investigating the change in weight and compressive strength of the specimens and techniques such as XRD and XRF are used to examine the chemical changes. Sulfuric acid is a very aggressive acid that reacts with the free lime [$Ca(OH)_2$] in the concrete forming gypsum($CaSO_{4}.2H_{2}O$). This reaction is associated with an increase in volume of the concrete, and the corroded surface becomes soft and white. The results showed that the OPC mortar caused an decrease in weight above 18% and strength loss about 57%. On the other hand, AASC(alkali-activated slag composites) did not cause any decrease in weight and in the case of strength caused an decrease below 10%. In addition, this mechanical results was verified to XRD and XRF.

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폐플라스틱/폐섬유소 복합체의 기계적 물성 (Mechanical Properties of Plastic Waste/Cellulose Waste Composites)

  • 홍영근
    • Elastomers and Composites
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    • 제38권1호
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    • pp.19-26
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    • 2003
  • 혼합폐플라스틱과 섬유소로서 폐신문지를 혼합하여 복합체를 구성하고 그 기계적인 물성을 조사하였다. 수지-수지 및 수지-섬유소 사이의 계면접착력을 증대시키고자 섬유소와 친화성을 가진 아비틱산을 소량 첨가하였다. 섬유소의 투입량이 많아질수록 인장강도는 플라스틱자체보다 저하되었으며 아비틱산은 강도에 좋은 영향을 주지 못하였다. 파단신장률 및 충격강도는 섬유소만의 투입량에 따라서는 감소하였으나, 섬유소가 적은 양이고 아비틱산이 적게 포함되어 있을 경우에 놀라운 상승을 나타내었다. 물성의 향상은 아비틱산의 화학적인 양면성에 기인한다고 여겨진다.

고로슬래그를 치환한 보수 모르타르의 내 황산성 평가 (Sulfuric Acid Resistance Evaluation of Repair Mortar Substituted Blast Furnace)

  • 김완수;장종민;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 추계 학술논문 발표대회
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    • pp.25-26
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    • 2019
  • The Reinforced concrete structure is deteriorated in durability due to various deterioration factors such as acid, salt, etc., and thus requires repair and reinforcement. In this study, compressive strength and weight change were measured by substituting blast furnace slag with excellent chemical resistance. As a result, the decrease in compressive strength decreased in proportion to the blast furnace slag substitution rate, and in the case of BFS40, the strength increased after sulfuric acid immersion. The weight change also decreased in proportion to the replacement amount.

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준설토 산세척 시 염산 농도가 중금속의 정화효율 및 존재형태에 미치는 영향 (Effect of Hydrochloric Acid Concentration on Removal Efficiency and Chemical Forms of Heavy Metals During Dredged Sediment Acid Washing)

  • 김기범;최용주
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제25권1호
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    • pp.74-83
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    • 2020
  • In this study, the effect of hydrochloric acid (HCl) concentrations on removal efficiency and chemical forms of heavy metals in dredged sediment during acid washing was investigated. The removal efficiencies of Zn, Cu, Pb, Ni and Cd by acid washing were 18.4-92.4%, 7.2-83.7%, 9.4-75%, 8.1-53.4% and 34.4-70.8%, respectively. Overall, the removal efficiencies of heavy metals were remarkably enhanced with the increase of the acid strength. However, the removal efficiencies for 0.5 and 1.0 M HCl were comparable, and both cases met the Korean soil contamination standard. Based on the sequential extraction results, concentration of the exchangeable fraction (F1), the most labile fraction, increased whereas concentrations of the other fractions decreased with increasing acid strength. Particularly, the carbonate (F2) and Fe/Mn oxides (F3) fractions drastically decreased by using 0.5 M or 1.0 M HCl. The current study results verified that acid washing could effectively reduce heavy metal concentrations and its potential mobility in dredged sediments. However, the study also found that acid washing may cause significant increase in bioavailable fraction of heavy metals, suggesting the need to evaluate the changes in chemical forms of heavy metals by acid washing when determining the acid strength to be applied.

수리된 복합레진 수복물의 전단결합강도 연구 (SHEAR BOND STRENGTH OF REPAIRED COMPOSITE RESIN RESTORATIONS)

  • 최수영;정선와;황윤찬;김선호;윤창;오원만;황인남
    • Restorative Dentistry and Endodontics
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    • 제27권6호
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    • pp.569-576
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    • 2002
  • This study was peformed to evaluate the interfacial shear bond strength of base (direct and indirect) and repair composites with aging and surface treatment methods. Direct composite resin specimens ($Charisma^{\circledR}$, Heraeus Kulzer, Germany) were aged for 5 min, 1 hour, 24 hours, and 1 week in $37^{\circ}C$ distilled water before surface treatment, and then divided into five groups Group 1, grinding; Group 2, grinding and application of bonding agent, Group 3, grinding, etching with 37% phosphoric acid for 30sec, and application of bonding agent, Group 4, grinding, etching with 37% phosphoric acid for 30sec, silane treatment, and application of bonding agent ; Group 5, grinding, etching with 4% hydrofluoric acid for 30sec. silane treatment, and application of bonding agent. Indirect composite resin specimens ($Artglass^{\circledR}$, Heraeus Kulzer, Germany) were aged for 1 week in $37^{\circ}C$ distilled water and divided into seven groups Group 1 - Group 5, equal to Charisma specimens; Group 6, grinding, etching with 37% phosphoric acid for 60sec, silane treatment, and application of bonding agent; Group7, grinding, etching with 4% hydrofluoric acid for 60 sec, silane treatment, and application of bond-ing agent. The repair material($Charisma^{\circledR}$) was then added on the center of the surface (5 mm in diameter. 5 mm in height). The shear bond strength was tested and the data was analyzed using one-way ANOVA and the Student- Newman-Keuls test. The following conclusions were drawn. 1 The shear bond strength of $Charisma^{\circledR}$ specimens aged for 1 hour was significantly higher in Group 2 and Group 5 than in Group 1 (p<0.05), and that of $Charisma^{\circledR}$ specimens aged for 1 week was signifi-cantly higher in Group 3 and Group 5 than in Group 1 (p<0.05). No significant difference was found in the bond strength of specimens aged for 5 min and 24 hours. 2. In Group 2 of the $Charisma^{\circledR}$ specimens, there was significant difference between the bond strength of 24 hours and that of 1 week (p<0.05). 3. In Group 4 of the $Charisma^{\circledR}$ specimens, the shear bond strength of specimens aged for 24 hours was significantly higher than the others(p<0.05) 4. There was no significant difference between the shear bond strength of the $Artglass^{\circledR}$ specimens, 5. Most of the $Charisma^{\circledR}$ specimens showed cohesive fractures. Artglass^{\circledR}$ specimens that were etched with acid (phosphoric or hydrofluoric) for 30 sec showed more cohesive fractures.

중화 액상화 레드머드의 첨가량에 따른 시멘트 페이스트의 특성 (Properties of Cement Paste by the Addition of Liquefied Red Mud)

  • 이희라;강혜주;이영훈;강석표
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 추계 학술논문 발표대회
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    • pp.23-24
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    • 2019
  • In this paper, the compressive strength characteristics of cement paste were compared with the addition of liquefied red mud with the addition of nitric acid in order to improve the strength of the deteriorated cement. The results showed that the compressive strength with between 7 days and 28 days was greater than that of liquefied red mud. The ratio of daily compressive strength of the liquefied red mud is higher than that of the Plain with a 1 percent addition rate, and the ratio of compressive strength is lower than that of the Plain on the 28 days. Therefore, the compressive strength of neutralization liquefied red mud compared to liquidated red mud was relatively high, and the compressive strength of the red mud was shown to be improved to a level almost similar to that of Plain.

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상아질 표면상태에 따른 광중합형 글래스아이오노머 시멘트의 전단결합강도에 관한 연구 (A STUDY ON THE SHEAR BOND STRENGTH OF LIGHT CURED GLASS IONOMER CEMENTS TO CONTAMINATED DENTIN)

  • 김경화;박상진
    • Restorative Dentistry and Endodontics
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    • 제22권2호
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    • pp.609-621
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    • 1997
  • The purpose of this study was to evaluate the shear bond strength of three light-cured glass ionomer cements to blood contaminated bovine dentin. The materials used in this study were Fuji II LC, Dyract and Variglass VLC. The dentin conditioners were 10% polyacrylic acid, 10% maleic acid and 10% phosphoric acid. 180 lower anterior bovine teeth were selected in this study. The teeth were embedded in acrylic resin and were grounded with 320 to 600 grit silicon carbide paper to create a flat dentin surface. The teeth were divided into SIX groups. The experimental procedures in six groups were as follows; Group l(GF) : Samples bonded to dentin surface with Fuji II LC after 10% polyacrylic acid treatment. Group 2(BGF) : Samples bonded to dentin surface with Fuji II LC after 10% polyacrylic acid treatment and blood contamination. Group 3(MD) : Samples bonded to dentin surface with Dyract after 10% maleic acid treatment. Group 4(BMD) : Samples bonded to dentin surface with Dyract after 10% maleic acid treatment and blood contamination. Group 5(PV) : Samples bonded to dentin surface with Variglass VLC after 10% phosphoric acid treatment. Group 6(BPV) : Samples bonded-to dentin surface with Variglass VLC after 10% phosphoric acid treatment and blood contamination. Group 1,3 and 5 were classified into the control groups, while group 2,4 and 6 were classified into the experimental groups. Each group contained 30 samples. After 24 hours water storage at $37^{\circ}C$, all smples were subjected to a shear load to fracture at a cross head speed of 1.0 mm/min with Instron universal testing machine(No. 4467). Debonded surfaces were observed under Scanning Electron Microscope(Hitachi S-2300) at 20kvp. The data were evaluated statistically at the 95% confidence level with Student's t-test. The following results obtained; 1. Shear bond strengths were higher in the control groups(1,3,5 group) than in the experimental groups(2,4,6 group). 2. The shear bond strength of group 5(PV) was the highest in the control groups, and the group 5 was significantly higher than the group l(GF) on the shear bond strength. 3. The group 4(BMD) was the highest on the shear bond strength, and the group 2(BGF) was the lowest in the experimental groups. The group 4(BMD) and 6(BPV) showed a significant difference with the group 2 on the shear bond strength. 4. All the groups showed an adhesive-cohesive failure. except the group 2(BGF) showing adhesive failure.

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Square CFST columns under cyclic load and acid rain attack: Experiments

  • Yuan, Fang;Chen, Mengcheng;Huang, Hong
    • Steel and Composite Structures
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    • 제30권2호
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    • pp.171-183
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    • 2019
  • As China's infrastructure continues to grow, concrete filled steel tubular (CFST) structures are attracting increasing interest for use in engineering applications in earthquake prone regions owing to their high section modulus, high strength, and good seismic performance. However, in a corrosive environment, the seismic resistance of the CFST columns may be affected to a certain extent. This study attempts to investigate the mechanical behaviours of square CFST members under both a cyclic load and an acid rain attack. First, the tensile mechanical properties of steel plates with various corrosion rates were tested. Second, a total of 12 columns with different corrosion rates were subjected to a reversed cyclic load and tested. Third, comparisons between the test results and the predicted ultimate strength by using four existing codes were carried out. It was found that the corrosion leads to an evident decrease in yield strength, elastic modulus, and tensile strain capacity of steel plates, and also to a noticeable deterioration in the ultimate strength, ductility, and energy dissipation of the CFST members. A larger axial force ratio leads to a more significant resulting deterioration of the seismic behaviour of the columns. In addition, the losses of both thickness and yield strength of an outer steel tube caused by corrosion should be taken into account when predicting the ultimate strength of corroded CFST columns.