• 방사선산업학회지
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• 제5권4호
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• pp.377-382
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• 2011

Poly(vinyl alcohol) (PVA) is an interesting material with good biocompatibility, high elasticity and hydrophilic chacrateristics. In this study, crosslinked hydrogels based on PVA, and poly(acrylic acid) (PAAc) were prepared by gamma-ray irradiation. PVA and PAAc powders were dissolved in deionized water, and then irradiated by a gamma-ray with a radiation dose of 50 kGy to make hydrogels. The hydrogels were then annealed in an oven at $120^{\circ}C$ for 10 min, 30 min and 50 min under nitrogen atmosphere. The properties of a hydrogel such as gel fraction, swelling behavior, thermogravimetric analysis (TGA) and adhesive strength as a function of PAAc content and annealing time were investigated. The gel fraction decreases with decreasing PAAc content and increasing annealing time. The thermal behaviors have shown different patterns according to the annealing time. The adhesive strength increases with increasing PAAc content.

• 대한치과기공학회지
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• 제41권3호
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• pp.177-185
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• 2019

Purpose: This study was to investigate the effect of three different surface treatments on the shear bond strength of lithium disilicate ceramics to enamel. Methods: Totally 60 lithium disilicate ceramic disc specimens were fabricated with IPS e.max press (Ivoclar Vivadent, Schaan, Liechtenstein) and Mazic Claro (Vericom, Korea). 30 specimens in each lithium disilicate ceramic were assigned to 3 groups of the each following surface treatment: 1) $50{\mu}m$ airborne particle abrasion+silane, 2) 9.5% hydroflouric acid etching (HF)+silane, 3) $50{\mu}m$ airborne particle abrasion+9.5% HF+silane. Lithium disilicate ceramic surfaces after surface treatments were AFM examined. The shear bond strength was measured in a universal testing machine at 0.5mm/min crosshead speed. All data were analyzed using a two-way ANOVA and Tukey's test(${\alpha}=0.05$). Results: The mean surface roughness of lithium disilicate ceramics ranged from $0.178{\mu}m$ to $0.441{\mu}m$. The mean shear bond strengths ranged from $23.81{\pm}2.78MPa$ to $33.99{\pm}4.85MPa$. Conclusion: 1. Mazic Claro showed higher shear bond strength than IPS e.max press at 3 different surface treatments, and no statistically significant was observed. 2. The shear bond strength of IPS e.max press was strongly enhanced as surface treated with $50{\mu}m$ airborne particle abrasion and 9.5% hydroflouric acid etching. And there was no statistical significance at the shear bond strength of Mazic Claro with surface treatments.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 제5회 학술대회 논문집 일렉트렛트 및 응용기술연구회
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• pp.69-71
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• 2003

Mechanical Properties, such as tensile strength, elongation, and tear strength, decreased according to increasing the load of ATH, volume resistivity, AC break down strength, and tracking resistance for HVI SC contained ATH treated by vinyl Silane were better than those for HVI SC were contained ATH treated by other surface treatment agent, such as stearic acid and acryl silane.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.245-248
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• 2006

This study investigated the strength of shotcrete with aluminate accelerator to connect with the proper repair methods or monitoring skills in subway, cable tunnel and underground storage. In order to approach these goals, the shotcrete specimens were exposed to acid, sulfate and seawater environments, and strength properties of the shotcrete suffering from the attacking sources were examined.

• Advances in concrete construction
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• 제9권1호
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• pp.55-70
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• 2020

In this research article, acid resistance, sulphate resistance and sorptivity of self compacted concrete (SCC) prepared from C&D waste have been discussed. To improve the above properties of self compacted recycled aggregate concrete (SCRAC) along with mechanical and durability properties, different two stage mixing approaches (TSMA and TSMAsfc) were followed. In the proposed two stage mixing approach (TSMAsfc), silica fume, a proportional amount of cement and a proportional amount of water were mixed in premix stage which fills the pores and cracks of recycled aggregate concrete (RAC). The concrete specimen prepared using above mixing approaches were immersed in 1% concentration of sulphuric acid (H2SO4) and magnesium sulphate (MgSO4) solution for 28, 90 and 180 days for evaluating the acid resistance of SCRAC. Experimental results concluded that the proposed two stage mixing approach (TSMAsfc) is most suitable for acid resistance and sulphate resistance in terms of weight loss and strength loss due to the elimination of pores and cracks in the interfacial transition zone (ITZ). In modified two stage mixing approach, the pores and cracks of recycled concrete aggregate (RCA) were filled up and make ITZs of SCRAC stronger. Microstructure analysis was carried out to justify the reason of improvement of ITZs by electron probe micro analyser (EPMA) analysis. X-ray mapping was also done to know the presence of strength contributing elements presents in the concrete sample. It was established that SCRAC with modified mixing approach have shown improved results in terms of acid resistance, sulphate resistance, sorptivity and mechanical properties.

• 한국식품과학회지
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• 제39권2호
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• pp.158-163
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• 2007

본 연구는 curdlan 복합필름을 제조하고 물성을 비교하기 위해 수행되었다. 우선 low set 방식과 high set 방식 중 적절한 방식을 선정하였고, 순차적으로 AMG나 oleic acid 중에서 적절한 방습소재를 선정하였으며, PB와 PIB 중에서 적절한 물성개량제를 선정하고자 하였다. 그 결과 high set 필름이 low set 필름보다 신장율은 다소 작지만 인장강도가 높고 수증기 투과도가 낮기 때문에 curdlan 복합필름 제조에는 high set 방법이 더 적합하며 이때 PEG는 2.0g 첨가하는 것이 유리할 것으로 판단하였다. 또한 oleic acid 첨가군이 AMG 첨가군보다 인장강도와 신장율이 더 크고, 수증기투과도는 더 낮은 편이며 특히 oleic acid 0.3g 첨가한 경우 신장율과 수증기 차단성 면에서 유리하므로 방습소재로서 oleic acid를 0.3g 첨가하는 것이 적합할 것을 판단하였다. PIB 첨가군이나 PB 첨가군 모두 인장강도와 수증기투과도는 비슷하나 신장율의 경우는 PIB 첨가군이 PB 첨가군보다 더 큰 것으로 나타났으므로 유연성과 관련된 물성개량 측면에서는 PIB 첨가가 더 유리할 것으로 판단하였다. 종합적으로 curdlan에 가소제 PEG와 방습소재 oleic acid와 물성개량제 PIB를 첨가하는 것이 유연성과 관련된 물성 면에서 가장 유리할 것으로 판단하였다.

• Current Research on Agriculture and Life Sciences
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• 제15권
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• pp.83-91
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• 1997

페놀성 화합물들은 단백질이나 금속 이온들과 결합하는 성질을 지녀 식품분야에서는 영양 저해물질 혹은 갈변의 원인물질로 알려져 있으며 또 이들물질이 상수원에 유입시 염소와 결합하여 악취나 발암물질을 형성하는 등 환경적으로 유해한 물질로 알려져 있다. 그러나 최근에는 이들 물질들의 항미생물 효과, 항암효과 등이 밝혀짐에 따라 유용한 물질로 이용될 가능성이 매우 높아졌다. 이들 물질들의 제거 또는 회수는 곧 유해물질의 제거 혹은 유용성분의 분리의 의미가 된다. 따라서 본 실험에서는 연속식 고정층 흡착을 다성분계 페놀산 용액에서 행하여 실제 흡착공정에 적용시 필수적인 자료인 파과곡선 및 파과점을 nonlinoar curve fitting방법을 이용하여 산정하였다. 흡착질의 종류가 증가할수록 파과곡선의 적합성은 점점 낮아졌으며 흡착속도에 있어서는 gallic acid가 가장 빨리 파과점을 지나고 ferulic acid, p-coumaric acid의 순으로 나타났다. 이들 결과로부터 다성분계에서의 연속식 고정층 흡착은 흡착제와 흡착질간의 ionic strength와 흡착질간의 분자량의 차이가 흡착량과 파과속도에 영향을 미치는 것으로 생각된다.

• Bulletin of the Korean Chemical Society
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• 제11권5호
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• pp.403-406
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• 1990

Two types of new silica catalysts modified with benzenesulfonic acid derivatives were prepared by esterification or phenylation followed by sulfonation. Both catalysts thus prepared were tested as acid catalysts for 2-propanol dehydration and cumene dealkylation reactions. B catalyst () were more active than A catalyst (). Highter catalytic activity for B catalyst may be accounted for by higher resistance to water, higher acid strength, more acidity, and better thermal stability as compared with A catalyst.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2003년도 봄 학술발표회 논문집
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• pp.189-196
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• 2003

Soil-cement column is often used as a contaminant barrier. This study presents the results of experimental study performed to investigate the changes of properties of soil-cement column under the attack of acids. Sulfuric nitric, and ascetic acid were used as contaminants. Specimen were made of clayey and sandy soils with addition of cement and water Permeability of soil-cement decreased with time during permeability test. When significant amount of acid percolated the specimen, permeability increased and compressive strength decreased due to the dissolution and leaching of cement and its chemical reaction compounds. Sulfuric and nitric acid were more effective than ascetic acid in deteriorating soil-cement column. Amount of acid required to lower the pH of soil cement below 12 was calculated from the results of permeability tests. This leads to a conclusion that, under the conditions employed in this study, the chemical stability of soil-cement column could be maintained against acid attack for longer than generally accepted lifetime of contaminant barriers.

• 한국건설순환자원학회논문집
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• 제5권4호
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• pp.106-113
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• 2010

본 연구에서는 고로슬래그 미분말 제조시 혼입되는 최적의 석고량을 도출하고, 분말도 및 제조환경에 관한 제반물성을 실험적으로 검토함으로서 고로슬래그 미분말의 품질향상 방안과 사용성 확대를 위한 기초자료로 활용하고자 하였다. 실험결과, 유동성은 석고첨가량이 높을수록 저하하는 경향이었고 천연석고와 석회 소성슬러지의 경우에는 첨가량 2.6%이상에서 KS 기준을 만족하지 못하였다. 압축강도는 인산석고, 탈황석고, 불산석고의 화학석고가 초기 강도가 높게 형성되었고 석회 소성슬러지와 석회석 미분말은 강도발현에 큰 영향이 없는 것으로 분석되었다. 분말도가 높아지면 유동성이 감소하고 압축강도는 증가하기 때문에 석고첨가량을 2.0%이하로 관리하는 것이 경제적일 것으로 판단된다. 저온에서는 불산석고, 고온에서는 탈황석고가 유동성 확보에 유리한 것으로 나타났고 동절기인 $10^{\circ}C$에서는 2.6%, 서중기인 $30^{\circ}C$에서는 2.0%이하로 사용하는 것을 적정 사용량으로 결정하였다.