• 제목/요약/키워드: acid resistance of concrete

검색결과 114건 처리시간 0.027초

Laboratory investigations on the effects of acid attack on concrete containing portland cement partially replaced with ambient-cured alkali-activated binders

  • Ramagiri, Kruthi K.;Patil, Swaraj;Mundra, Harsh;Kar, Arkamitra
    • Advances in concrete construction
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    • 제10권3호
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    • pp.221-236
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    • 2020
  • To reduce the CO2 emissions associated with the manufacture of portland cement (PC), an efficient alternative like an alkali-activated binder (AAB) is the requirement of the industry. To promote the use of AAB in construction activities, a practically implementable mix proportion is required. Owing to the several raw ingredients of AAB concrete and their associated uncertainties, partial replacement of PC by AAB may be adopted instead of complete replacement as per industrial requirements. Hence, the present study aims to determine an optimal proportion for partial replacement of PC with AAB and recommend a technique for it based on site conditions. Three modes of partial replacement are followed: combining all the dry ingredients for AAB and PC followed by the addition of the requisite liquids (PAM); combining the PC and the AAB concrete in two horizontal layers (PAH); and two vertical layers (PAV). 28-day old specimens are exposed to 10% v/v solutions of HCl, H2SO4, and HNO3 to evaluate changes in mechanical, physical, and microstructural characteristics through compressive strength, corrosion depth, and microscopy. Based on deterioration in strength and integrity, PAH or PAV can be adopted in absence of acid attack, whereas PAM is recommended in presence of acid attack.

The properties of hydrophobic concrete prepared by biomimetic mineralization method

  • Huang, Chung-Ho;Fang, Hao-Yu;Zhang, Jue-Zhong
    • Computers and Concrete
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    • 제23권5호
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    • pp.351-359
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    • 2019
  • In this study, the calcium hydroxide, an inherent product of cement hydration, was treated using biomimetic carbonation method of incorporating stearic acid to generate the hydrophobic calcium carbonate on concrete surface. Carbonation reaction was carried out at various $CO_2$ pressure and temperatures and utilizing the Scanning Electron Microscope (SEM), chloride-ion penetration test apparatus, and compression test machine to investigate the hydrophobicity, durability, and mechanical properties of the synthesized products. Experimental results indicate that the calcium stearate may change the surface property of concrete from hydrophilicity to hydrophobicity. Increasing reaction temperature can change the particles from irregular shapes to needle-rod structures with increased shear stress and thus favorable to hydrophobicity and microhardness. The contact angle against water for the concrete surface was found to increase with increasing $CO_2$ pressure and temperature, and reached to an optimum value at around $90^{\circ}C$. The maximum static water contact angle of 128.7 degree was obtained at the $CO_2$ pressure of 2 atm and temperature of $90^{\circ}C$. It was also found that biomimetic carbonation increased the permeability, acid resistance and chloride-ion permeability of the concrete material. These unique results demonstrate that the needle-rod structures of $CaCO_3$ synthetized on concrete surface could enhance hydrophobicity, durability, and mechanical properties of concrete.

황토 콘크리트의 배합조건에 따른 강도성상 및 내구성 (Characteristics of Strength and Durability of Hwangto-Concrete according to its Mixing Condition)

  • 황혜주;노태학;김진일
    • KIEAE Journal
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    • 제8권5호
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    • pp.55-60
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    • 2008
  • The purpose of this study is to increase the use of Hwangto and examine the strength according to what it is compounded with. Hwangto-concrete containing Hwanto without cement nor organic chemical products were compared to the traditional cement concrete through some durability experiments. We expect to gain more knowledge on the potentials of Hwangto-concrete as an architectural source. 1) As Hwangto binder amount rises, the value of slump increases too. The reason is that the increase of the quantity of cement causes the increase of the amount of material and the decrease of the amount of aggregate. 2) When the mixed component into Hwangto-concrete remains at 2%, the compress strength is generally dispersed high along the per unit fission, in case the amount of which is at $400(g/m^3)$. The highest compress strength is 39MPa. It means that it can be applied to common structures and we need to conduct a basic property test to ensure the strength and fluidness. 3) Hwangto-concrete is expected to be highly used in the ocean structure and chemical industry because it has better resistance to sulfuric acid and to hydrochloric acid than the cement-concrete has. The result of this study is as follows. It is expected that Hwangto-concrete will be widely applied and further research on its durability and tests for its basic substantial characteristics based on future component added to it.

국내.외산 메타카올린을 사용한 고강도 콘크리트의 내구특성에 관한 실험적 연구 (An Experimental Study on the Properties of Durability of High Strength Concrete Using Domestic.Foreign Meta-kaolin)

  • 이강필;이승민;이상수;송하영
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2009년도 춘계 학술논문 발표대회 학계
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    • pp.239-242
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    • 2009
  • As the high-rise building increase due to the gravitation of population to big cities recently, it requires high quality and high performance of Concrete. As a result, people are keenly interested in Meta-kaolin as new admixture favorable from an economic perspective, which has strength and endurance with admixture at the same level like Silica-fume. Accordingly, as to Meta-kaolin, this study was to set by three levels like domestic one, foreign one, and Silica-fume, the water-binding material ratio 25%, and four level substitute like 0, 10, 20, and 30(%) in order to compare and analyze the quality durability of high-concrete according to the substitute of Meta-kaolin applicable with replacement of Silica-fume. As a result of performing experiment it was found that when water-binding material ratio increases, resistance of neutralization, carbonation, salt damage and sulfate decrease, and when replacement ratio of mineral admixture increases, depth of accelerating carbonation gets greater. Also, the combination of SF and MK-B favored resistance to chloride ion penetration better than MK-A, and it was found that when replacement ratio of binding material increases, the resistance to sulphuric acid increases. Therefore, based on this study, it was understood that meta-kaolin is useable in replacement of silicafume.

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콘크리트 침투성 방수제의 실험적 연구 (An Experimental Study on Permeable Water Proof Admixtures of Concrete)

  • 구민세;박언규
    • 콘크리트학회지
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    • 제8권1호
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    • pp.138-144
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    • 1996
  • 현재 우리나라 교량의 겨우 상판의 열화현상을 극소화시키기 위하여 방수의 필요성이 절대적으로 요구되고 있다. 따라서 본 연구에서는 지금 현재 국내에서 시공되고 있는 교량 방수 공법 중 침투성 방수제를 실내실험을 통하여 자연적 및 인위적 조건에 저항하는 특성의 파악을 위한 실험을 수행하였다. 실험결과 방수제의 침투깊이의 감소로 인해서 고강도 콘크리트를 사용할 경우 이 공법의 적용은 재고할 필요가 있는 것으로 판단된다. 방수제를 사용하는 경우 콘크리트의 내산성이 우수하게 나타나므로 침투성 방수제는 산성비에 대한 저항성이 크다. 그러나 방수제의 성능은 자연상태로 노출되어 있는 경우 그 수명이 영구적이 아니므로 교량의 슬래브에는 반드시 아스팔트 콘크리트를 포장하여야 한다. 실험결과로 부터의 또다른 결론은 방수제로 인해 콘크리트의 내열성 및 내마모성이 증가됨을 알 수 있다.

액상 항균제를 도포한 하수시설용 단면복구재의 내구특성에 관한 실험적 연구 (An Experimental Study on the Durability Properties of Repair Mortar for Sewer Spread with Liquefied Antibiotic)

  • 이동혁;장재봉;나철성;조봉석;김재환;김무한
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2005년도 춘계 학술기술논문발표대회 논문집
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    • pp.211-214
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    • 2005
  • Recently, Deterioration of the concrete sewer concrete structures by biochemical corrosion has been issued and a development of the inhibition system of corrosion that has been demanded. The sulfuric acid may react with the hardened cement paste and originate expansive products which can induce swelling and breakless of concrete. Also, a sulphuric acid reacts with calcium hydroxide to from $CaSO_4\;\cdot\;2H_2O$. This reaction accounts for consumption of the calcium hydroxide present in hardened cement paste. In this study, To present from biochemical corrosion of the sewer repair mortar that was spread with liquefied antibiotic and then its experimental properties were experimentally investigated and to estimate the effect of absorbed condition of restorative mortar, the number of coating times and coating contents with antibiotic on the durability properties of restorative mortar spread with antibiotics. Also, testing items such as carbonation depth, choloride ion penetration depth and chemical resistance was tested to estimate the durability properties in third study. In results, the novellus bacillus inhabiting in sewer concrete structures was restrained by antibiotics developed in this study. And carbonation depth, choloride ion penetration depth and chemical resistance of restorative mortar spread with antibiotics was superior to that of plain mortar.

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Mechanical and durability properties of concrete incorporating glass and plastic waste

  • Abdelli, Houssam Eddine;Mokrani, Larbi;Kennouche, Salim;Aguiar, J.L. Barroso de
    • Advances in concrete construction
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    • 제11권2호
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    • pp.173-181
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    • 2021
  • The main objective of this work is to contribute to the valorization of plastic and glass waste in the improvement of concrete properties. Waste glass after grinding was used as a partial replacement of the cement with a percentage of 15%. The plastic waste was cut and introduced as fibers with 1% by the total volume of the mixture. Mechanical and durability tests were conducted for various mixtures of concrete as compressive and flexural strengths, water absorption, ultrasonic pulse velocity, and acid attack. Also, other in-depth analyses were performed on samples of each variant such as X-ray diffraction (XRD), thermogravimetric analysis (DSC-TGA), and scanning electron microscope (SEM). The results show that the addition of glass powder or plastic fibers or a combination of both in concrete improved in the compression and flexural strengths in the long term. The highest compressive strength was obtained in the mix which combines the two wastes about 26.72% of increase compared to the control concrete. The flexural strength increased in the mixture containing the glass powder. Therefore, the mixture with two wastes exhibits better resistance to aggressive sulfuric acid attack, and incorporating glass powder improves the ultrasonic pulse velocity.

항균제를 도포한 하수시설 콘크리트의 생화학적 부식특성 평가를 위한 폭로시험 (An Exposure Experiment for the Evaluation of Corrosion Properties of Sewage Concrete Covered with Antibiotics)

  • 노경민;이의배;김영덕;이병기;김규용;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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    • pp.73-76
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    • 2006
  • Sewage facilities mainly consisted of concrete structures are being deteriorated seriously by biodeterioration originated from sulfur-oxidizing bacteria. To prevent biochemical corrosion of the sewage concrete, antibiotics which prevent growth of sulfur-oxidizing bacteria were developed. Recently, to evaluate biochemical corrosion properties of concrete, antimicrobial performance and resistance to sulfuric acid were investigated respectively. But, in this study, to evaluate it complexly, concrete specimen covered with antibiotics were exposed in the actual sewage environment and were investigated about corrosion properties after three months. As a result, weight change ratio, nature potential and sulfuric ratio of concrete covered with antibiotics were less than plain concrete.

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플라이 애시를 혼입한 콘크리트의 물리.역학적 특성에 관한 실험적 연구 (Experimental Study on physical and Mechanical Properties of Concrete with Fly Ash)

  • 성찬용
    • 한국농공학회지
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    • 제42권3호
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    • pp.107-113
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    • 2000
  • This study is performed to examine the physical and mechanical properties of concrete with fly ash. Test results show that the unit weights of concrete with fly ash are decreased 1-3% and the highest strength is achieved by 10% filled fly ash concrete with it is increased 7% than that of the normal cement concrete. the ultrasonic pulse velocity is in the range of 3.705~4.204m/s and the dynamic and static modulus of elasticity is in the range of 271$\times$103 ~289$\times$103kgf/cm2 and 208$\times$103 ~262$\times$103kgf/cm2 respectively. The acid-resistance is increased with increase of the content of fly ash. It is 1.2 times of the normal cement concrete by 10% filled fly ash concrete and 1.7 times by 30% filled fly ash concrete respectively.

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폴리머 시멘트 모르타르를 이용한 철근콘크리트 흄관 라이닝에 관한 연구 (A Study on the Lining of Reinforced Concrete Pipe Using Polymer-Modified Mortar)

  • 김영집;김한엽;조영구;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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    • pp.333-338
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    • 2000
  • At present, reinforced concrete pipe has been widely used as drain pipe. However, many reinforced concrete pipe is exposed at deteriorated environment by the growth of a sulfur-oxidizing bacterium isolated from corroded concrete. The purpose of this study is to evaluate the effects of lining by polymer-modified mortar on the development in durability of reinforced concrete pipe. Polymer-modified mortars ate prepared with various polymer typer as cement modifier and polymer-cement ratio and rested for compressive and flexural strengths, adhesion in tension, acid resistance test, freezing and thawing test, and lining test of product in the field. From the rest results, it is apparent that polymer-modified mortars have good mechanical properties and durability as lining material. In practice, all polymers can be used as lining materials for reinforced concrete pip, and type of polymer, and polymer-cement ratio and curing conditions are controlled for good lining product.

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