• 제목/요약/키워드: acid gas

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동(銅)이 주종을 이루는 조형물 보존용 왁스의 산성강하물 및 부식 가스에서의 영향성 연구 (Study on the Effect of Corrosion Gas and Acidic Falling Materials for Conservational Wax on the Copper based Sculpture)

  • 오승준;위광철
    • 보존과학회지
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    • 제26권4호
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    • pp.437-443
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    • 2010
  • 화석 연료의 생성물인 유해 부식 가스와 이들의 원인으로 나타나는 산성 강하물이 야외 동(銅) 조형물을 보호하고 있는 왁스에 미치는 환경에 대한 영향성을 연구하였다. 부식이 유해 가스보다는 체류성이 강한 산성 강하물에 의해 급격히 진행되는 것으로 볼 수 있었으며, 이 부식의 시작이 코팅된 왁스의 백화 현상으로부터 시작되는 것을 알 수 있었다. 산성도가 증가할수록 백화 현상이 크게 발생하였으며 결과적으로 산성강하물 및 부식 가스에 의해 백화 현상의 시작으로 내부 금속의 노출 현상이 나타나게 되어 부식이 진행되는 것으로 알 수 있었다. 왁스가 코팅된 동 시편은 유해 부식 가스와 산성비, 0.1 M의 산들에 노출되었으며 이의 결과로 가장 변화가 적고 산성도에 대한 저항성이 큰 왁스로는 황산의 결과를 제외하고는 모든 실험에서 Renaissance wax의 변화가 가장 작은 것으로 나타났다.

인산형 연료전지의 다공성전극 제조에 관한 기초적연구 (Fundamental Studies on the Manufactruring of prouse Electrode for Plosphoric Acid Fuel Cell.)

  • 김영우;박정일;이주성
    • 한국표면공학회지
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    • 제22권2호
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    • pp.55-61
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    • 1989
  • A fuel cell which causes electrochemical ratio of conventional with oxygen consists of mainly there parts, such as electrolyte, fuel and oxidant electrode. IN this paper, most efforts were delivered to manufacturing PETE-bonded gas-diffusion electrode, and preparation methods of the porous electrodes has been discussd. A medio temperature, phosphoric acid fuel cell (PAFC) provided with fuel (hydrogen) and oxygen showed oxygen showed excellent performance characteristics with made electrodes. Performance data obtained from hydrgen-oxygen cell were presented to illustrate their properties. It was found that the optimum amounts of platinum in clectrode for hydrgen-oxygen PAFC were about 3mg/cm3 and the PTFE content of gas diffusion layer and catalyst layer were 25% and 15%, respectively.

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한국산 산초열매와 나무의 휘발성 향기성분 (Volatile Flavor Components of Korean Sancho Fruit and Tree(Zanthoxylum schinfolium))

  • 이종원
    • 한국식품영양학회지
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    • 제11권5호
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    • pp.493-498
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    • 1998
  • An attempt was in this to analyzer volatile flavor components of sancho(Zanthoxylum schinfolium). Essential oils in sancho tree and fruit isolated by a simulataneous steam distillation (SDE) methods using n-pentane/diethyl ether as solvent. A total of 57 and 44 components were identified by gas chromatography(GC) and combined gas chromatography spectrometry (GC-MS), respectively. Granyl acetate(29.23%) geraniol (6.80%, p-isopropyl-2-chclohexenone(5.53%), phellandral (4.10%) in sancho fruit and 4, 6, 6-trimethyl-bicyclo(7.47%), T-carvelo(4.60%, ${\alpha}$-cypernone(3.58%) in sancho tree were found to be major volatile flavor. 22 compnents including myrcene, limonene, 1, 8-cinol in sancho fruit and 10 components including 4-(1-methylethyl)-cyclohexanol, methyl undecyl ketone in sancho tree were identified. The contents of unsaturated fatty acids of palmitic acid(24.34%), myristic acid(3,68%) in sancho tree was higher than that of the sancho fruit.

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Konig 반응을 이용한 CK 작용제 탐지젤 개발에 관한 연구 (A Study on Hydrogel-Based CK Agent Detecting Gel Using Konig Reaction)

  • 김경민;김경필
    • 한국군사과학기술학회지
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    • 제18권6호
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    • pp.829-834
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    • 2015
  • A simple and sensitive hydrogel-based detecting gel has been presented for the qualitative determination of cyanogen chloride(CK) using Konig reaction. To optimize Konig reaction conditions, the effects of pyridine and barbituric acid concentration were investigated. Under the optimized conditions, CK gas concentration was directly related with absorbance change at 567 nm. Based on aqueous solution test results, we finally prepared CK detecting hydrogel by absorbing pyridine and barbituric acid solution. Color change of the prepared CK detecting hydrogel was clearly observed when the detecting gel was exposed to 10 ppm CK gas.

FeMgO 촉매를 이용한 산성가스 정제 특성 (Acid-gas Removal Characteristics of Coal Gasification System using FeMgO catalyst)

  • 박준성;황상연;이승종
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.457-460
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    • 2007
  • 석탄가스화 기술은 석탄을 고온/고압 조건에서 가스화 반응시켜 CO와 $H_2$가 주성분인 합성가스(syngas)로 전환시키는 기술이다. 그러나 가스화 반응으로 인해 합성가스 내에는 불순물인 $H_2S$, COS, $NH_3$ 등의 오염 물질이 발생하게 되며, 가스터빈의 부식, 촉매의 피독, 전극의 성능 저하 현상 등을 일으켜 효율을 저하시키게 된다. 이에 본 연구에서는 FeMgO 촉매를 제거용매로 사용하여 $H_2S$를 효과적으로 제거하기 위하여 Lab-scale 탈황 설비를 제작하였으며, 석탄 가스화 운전에 연계하여 합성가스 내 포함된 산성가스 정제 특성에 관한 연구를 진행하였다.

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유리모세관칼럼에 의한 담배연기응축물중의 cis-trans형 지방산의 분리정량에 관한 연구 (STUDIES ON THE SEPARATION & DETERMINATION OF CIS-TRANS FATTY ACIDS IN CIGARETTE SMOKE CONDENSATE BY GLASS CAPILLARY GAS CHROMATOGRAPHY)

  • 이문수;이운철;김찬호
    • 한국연초학회지
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    • 제7권1호
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    • pp.67-74
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    • 1985
  • Cis-trans forms of fatty acids in cigarette smoke condensate were separated and characterized using SP 2340 glass capillary gas chromatography. The transforms of fatty acids, palmitoeladic , 1-vaccenic, eladic and linoeladic acid were identified. These components were not present only 3% of the total fatty acid fraction, but they showed a very low transfer rate.

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The Future of Planetary Entry Technology

  • Park, Chul
    • International Journal of Aeronautical and Space Sciences
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    • 제12권3호
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    • pp.211-224
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    • 2011
  • This is a written version of an hour-long lecture delivered by the author on June 30, 2011, as Plasmadynamics and Lasers Award Lecture at the AIAA 2011 summer conference in Honolulu, Hawaii. The author proposes that two areas of planetary entry physics be pursued in the future: outer planet aero-capturing and study of aerodynamics of meteoroid entries, both for the purpose of advancing the understanding of the possible extraterrestrial seeding of building blocks of life. For outer planet aero-capturing, the author proposes to develop new shock tube facilities that will produce up to 30 km/s of shock speed without causing photo-ionization of the driven gas by the radiation from the hot driver gas. Regarding meteors, the author proposes to carry out laboratory testing of the Tunguska event and of the seeding of amino acid molecules using a ballistic range which shoots a snowball laden with amino acid molecules toward a water surface.

가스 크로마토그라피에 의한 아미노산 광학 이성질체의 분리(III) -(S)-5-isobutyl-$N^3$-phenyl-2-thiohydantoin의 광학 활성 고정상으로의 응용- (Separation of Amino Acid Enantiomers by Gas Chromatography (III) -(S)-5-isobutyl-$N^3$-phenyl-2-thiohydantoin as chiral stationary phase-)

  • 박만기;양정선;고창범
    • 약학회지
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    • 제32권2호
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    • pp.112-116
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    • 1988
  • The resolution of N-trifluoroacetyl (N-TFA) ter-isopropylesters of Ala, Ile, Leu, Val and Phe by gas chromatography on the (S)-5-isobutyl-$N^3$-phenyl-2-thiohydantoin as stationary phase was investigated. The phase was employed at several column temperatures $(140^{\circ}C{\sim}200^{\circ}C)$ and the separation factors were $1.18{\sim}1.45$ range for five amino acid enantiomers. The possible mechanism of chiral recognition was investigated by NMR technique and the association constant$(K_c)$ was calculated as 201.3(r=0.98) for alanyl derivative.

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복어간 폐기물로부터 Tetrodotoxin, DHA 및 EPA의 분리 (Separation of Tetrodotoxin, DHA and EPA from Pufferfish Liver Waste)

  • 차병윤;최진석;임정규;이동익;이원갑;이은열;김희숙;김동수
    • 생명과학회지
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    • 제10권2호
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    • pp.115-124
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    • 2000
  • The present study was undertaken to separate the available components effectively, such as tetrodotoxin(TTX), docosahexaenoic acid(DHA, C22:6,ω-3) and eicosapentaenoic acid (EPA, C20:5,ω -3) from pufferfish liver waste, which are known to have high values as bioactive materials. By using ultrafiltration, it was possible to separate high contents of 68mg TTX from pufferfish liver waste. In contrast, by activated charcoal column, it was to obtain about 54mg TTX. The recovering ratios were 65.3% and 45.0% in the two different methods of ultrafiltration and activated charcoal column, respectively. From the results of HPLC and gas chromatography-mass spectrometry(GC-MS), the obtained toxins were identified to be TTX and its derivatives. In addition, it was also possible to obtain 72.3g DHA and 11.4g EPA from 1kg of pufferfish liver by high performance liquid chromatography (HPLC). These amounts of DHA and EPA were also 17.70% and 1.04% in the total lipid of pufferfish liver oil from analysis of gas chromatography(GC), respectively.

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