• 제목/요약/키워드: acid gas

검색결과 2,062건 처리시간 0.07초

The Synthesis Method of Tin Dioxide Nanoparticles by Plasma-Assisted Electrolysis Process and Gas Sensing Property

  • Kim, Tae Hyung;Song, Yoseb;Lee, Chan-Gi;Choa, Yong-Ho
    • 한국분말재료학회지
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    • 제24권5호
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    • pp.351-356
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    • 2017
  • Tin dioxide nanoparticles are prepared using a newly developed synthesis method of plasma-assisted electrolysis. A high voltage is applied to the tin metal plate to apply a high pressure and temperature to the synthesized oxide layer on the metal surface, producing nanoparticles in a low concentration of sulfuric acid. The particle size, morphology, and size distribution is controlled by the concentration of electrolytes and frequency of the power supply. The as-prepared powder of tin dioxide nanoparticles is used to fabricate a gas sensor to investigate the potential application. The particle-based gas sensor exhibits a short response and recovery time. There is sensitivity to the reduction gas for the gas flowing at rates of 50, 250, and 500 ppm of $H_2S$ gas.

Cis-9-Octadecenoic acid와 trans-9-Octadecenoic acid의 열분해에 관한 연구 (STUDY ON THE PYROLYSIS OF TRANS-9-OCTADECENOIC ACID AND TRANS-9-OCTADECENOIC ACID.)

  • 이문수;이운철;곽재진
    • 한국연초학회지
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    • 제9권1호
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    • pp.57-64
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    • 1987
  • The pyrolysis of geometrical isomers of 9-octadecenoic acid were conducted at $600^{\circ}C$ under nitrogen, and its pyrolytic behaviors were investigated. The pyrolytic products of both fatty acids, cis-9-octadecenoic acid(oleic acid) and trans-9-octadecenoic acid(elaidic acid), were analyzed using a gas chromatograph and GC/MS spectrometer. Twenty-seven different compounds were identified from these pyrolyzates, and the chief products of them were ketones, alcohols and aromatic hydrocarbons. And also, the pyrolytic mechanisms of two geometrical isomers of this fatty acid were discussed by a comparison of experimental results.

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Production of Auxins and Auxin-like Compounds by Ginseng Growth-promoting Bacterium Pseudomonas fluorescens KGPP 207

  • Ten, Leonid N.;Lee, Mi Ja;Lee, Mee-Kyoung;Park, Hoon;Yoon, Jong Hyuk
    • Journal of Applied Biological Chemistry
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    • 제43권4호
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    • pp.264-268
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    • 2000
  • High activity of acidic ethylacetate extract from the culture supernatant of ginseng growth-promoting bacterium Pseudomonas fluorescens KGPP 207 and its fractions were demonstrated through wheat coleoptile bioassay. The following auxins and auxin-like compounds were identified in these fractions by combined gas chromatography-mass spectrometry: indole-3-acetic acid, indole-3-acetic acid methyl and ethyl ester, indole-3-butyric acid, indole-3-lactic acid and its methyl ester, indole-3-propionic acid, indole-3-pyruvic acid, p-hydroxyphenyl acetic acid, p-hydroxyphenyl acetic acid methyl and ethyl ester, phenyl acetic acid and its methyl ester. The bacterium KGPP 207 belongs to the strain of P. fluorescens which produces plant growth regulators and its beneficial effect on the ginseng growth may be due to the formation of the identified compounds.

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Comamonas terrigena의 균체지방산 조성 (Cellular fatty acid composition in comamonas terrigena)

  • 하덕모;안병학
    • 미생물학회지
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    • 제25권1호
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    • pp.67-72
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    • 1987
  • Cellular fatty acid composition of eight strains, indluding six strains of Comamonas terrigena, and two type strains of Pseudomonas acidovorans, and P. testosteroni was determined by gas-liquid chromatography. Almost the same composition was found in all the strains tested, and hexadecanoic acid, hexadecenoic acid, and octadecenoic acid were accounted more than 70% of total fatty acid. However, P. testosteroni differed from C. terrigena and P. acidovorans by the presence of comparatively large amonuts of 2-hydroxy-hexadecanoic acid, and C. terrigena contained three to eight times as much tetradecanoic acid in P. acidovorans and P. testosteroni. According to the similarity values calculated on the basis of fatty acid composition, C. terrigena strains were divided into three groups differentiated in the requirement of growth factors, and C. terrigena, P. acidovorans, and P. testosteroni strains occupied separate position each other in the dendrogram.

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아미노산을 이용한 망간 산화물 기공성 나노 구조의 합성 및 C3H8 가스에 대한 선택적 감응 특성 (Preparation of Manganese Oxide Porous Nanostructures using Amino-acid and its Selective C3H8 Sensing Properties)

  • 최권일;이종흔
    • 센서학회지
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    • 제20권1호
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    • pp.64-69
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    • 2011
  • Porous manganese oxide porous nanostructures were prepared by amino-acid-mediated solvothermal self assembly reaction and subsequent heat treatment at $600^{\circ}C$. When Mn-precursors were heat-treated at $400-550^{\circ}C$, the sensors did not show significant gas responses. In contrast, the manganese oxide heat-treated at $600^{\circ}C$ showed the significant gas responses, that is, the resistance decrease to 100 ppm $C_3H_8$ ($R_a/R_g$ = 2.17, $R_a$ : resistance in air, $R_g$ : resistance in gas) and the resistance increase to 100 ppm $C_2H_5OH$ ($R_g/R_a$ = 1.92). The opposite change of resistance upon exposure to $C_3H_8$ and $C_2H_5OH$ was discussed in relation to the mixed phases of manganese oxides with different valences.

초등학교 과학과 이산화탄소 발생실험의 개선에 관한 연구 (A Study About Improvement of Experiment of Carbon Dioxide Production on Elementary School Science Textbook)

  • 고영신;김세경;이혜경
    • 한국초등과학교육학회지:초등과학교육
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    • 제23권2호
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    • pp.152-158
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    • 2004
  • The purpose of this study was to find the difficulties and problems in the carbon dioxide production experiment and to suggest the device for the improvement. Many students have misconception for the smell of carbon dioxide. I found that the smell of carbon dioxide of producting through the experiment didn't concern with the quantity of calcium carbonate. I certificated that the smell of carbon dioxide was related with the concentration of hydrochloric acid. I built two trap applicaing suction in the gas production device to exclude fully the smell of carbon dioxide. So the smell of carbon dioxide was not present by passing the two trap. To find the ideal experimental conditions I perform the experiment step by step. As the result enough carbon dioxide to use for the property experiment was collected under the condition that is 60 mL of 3 molarity hydrochloric acid and 30 g calcium carbonate. I certificated to mesuring flowing quantity of carbon dioxide using the flow meter of carbon dioxide. In the improvement experiment of the property of carbon dioxide, I proposed the experiment device regarding as spreading of the gas and children's interest. To improve the problem of gas production experiment, I proposed the gas certification device using a thread.

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A1100 알루미늄 용접에서 실드가스의 종류에 따른 용입부의 변화 연구 (A Study on The Variation of Penetration According to The Shielding Gas in A1100 Aluminum Welding)

  • 김진수;김법헌;김규태;박용환
    • 한국기계가공학회지
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    • 제12권2호
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    • pp.49-54
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    • 2013
  • Recently welding of aluminum material is actively carried out to make lightweight in the fields of LNG vessels, aircraft, chemical plants, etc. To obtain high strength, hardness and elongation, elements such as manganese, zinc, silicon, etc should be added in aluminum alloy, which has been improved on the mechanical properties like precipitation hardening, age hardening, loosening, corrosion resistance acid resistance. Ar gas is used as a shielding gas of MIG welding for aluminum, also $N_2$, $O_2$, $CO_2$, $H_2$ etc can be added depending on the composition of the alloy. In this study, Ar + $O_2$, Ar, and He were used for welding, hardness, penetration status and changes in composition of penetrated parts were compared and analyzed. This made it possible to know the status and changes of the process in the penetrated parts depending on used gas throughout this study.

Highly Sensitive and Selective Trimethylamine Sensor Using Yolk-shell Structured Mo-doped Co3O4 Spheres

  • Kim, Tae-Hyung;Kim, Ki Beom;Lee, Jong-Heun
    • 센서학회지
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    • 제28권5호
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    • pp.271-276
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    • 2019
  • Pure and 0.5, 1, 2, 5, and 10 at% of Mo-doped $Co_3O_4$ yolk-shell spheres were synthesized by ultrasonic spray pyrolysis of droplets containing Co nitrate, ammonium molybdate, and sucrose and their gas sensing characteristics to 5 ppm trimethylamine (TMA), ethanol, p-xylene, toluene, ammonia, carbon monoxide, and benzene were measured at $225-325^{\circ}C$. The sensor using pure $Co_3O_4$ yolk-shell spheres showed the highest response to p-xylene and very low response to TMA at $250^{\circ}C$, while the doping of Mo into $Co_3O_4$ tended to increase the overall responses of gas sensors. In particular, the sensor using 5 at% Mo-doped $Co_3O_4$ yolk-shell spheres exhibited the high response to TMA with low cross-responses to other interfering gases. The high response and selectivity of Mo-doped $Co_3O_4$ yolk-shell spheres to TMA are attributed to the electronic sensitization by higher valent Mo doping and acid-base interaction between TMA and Mo components.

활성탄 섬유 필터를 전극으로 활용한 정전 방식의 공기정화장치의 가스 및 입자 제거 특성 분석 (Gas and particle removal characteristics of a novel electrostatic precipitation type air cleaner using an activated carbon filter as an electrode)

  • 임기택;김용진;한방우;우창규;신원규;김학준
    • 한국입자에어로졸학회지
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    • 제14권1호
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    • pp.9-16
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    • 2018
  • We have developed an electrostatic precipitation (ESP) type air cleaner for indoor air quality and investigated its performances regarding CADR (Clean air delivery rate), single-pass efficiency and gas removal efficiency. The ESP air cleaner used an ACF (Activated carbon fiber) filter for gas removal and the ACF as a high voltage electrode for particle removal. The ESP air cleaner was tested in a chamber with the volume of $1m^3$ regarding CADR and gas removal efficiency. The applied CADR area of the ESP was $1.8m^2$. Gas removal efficiency was tested with 3 gases (Acetaldehyde, Acetic acid, Ammonia). As the results of the gas removal efficiency, the ESP air cleaner shows the removal efficiencies of 90, 98 and 85% for acetaldehyde, acetic acid and ammonia, respectively.

기체투과막을 이용한 암모니아성 질소 회수방안 (Recovery of Ammonia Nitrogen using Gas-permeable Membranes)

  • 이상훈;채상엽
    • 멤브레인
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    • 제32권3호
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    • pp.191-197
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    • 2022
  • 기체투과막 기술을 이용하여 가축분뇨 폐기물 등으로부터 암모니아성 질소를 효과적으로 회수할 수 있다. 이는 폐기물 내 암모니아 기체가 폐기물에 함침된 기체투과막의 미세공극을 투과하여 막반대편에 도달하게 된다. 투과된 암모니아 기체분자는 막 반대편에 존재하는 용액 내 황산 등 산에 의해 포획 및 회수된다. 막 유입부 내 암모니아성 질소 제거 효과를 높이기 위해서는 우선 유입 폐기물 내 pH를 높게 유지해야 하는데 pH 상승에 필요한 염기성 약품 투입비용이 문제가 될 수 있다. 기존 연구에서는 보다 저렴한 소석회 투입하거나 폭기 혹은 질산화억제를 통해 높은 pH를 효과적으로 유지시키는 방안이 거론되고 있다. 한편 암모니아성 질소 회수에 쓰이는 기체투과막의 재질은 적절한 내열성이나 내화학성 이외에도 소수성을 띈다는 특징이 있으며 이를 통해 막기공을 통해 암모니아 기체를 선택적으로 투과시킬 수 있다. 향후 연구에서는 다양한 성상을 가진 현장 폐기물을 이용하여 실증 Test를 수행하고 이를 기반으로 최적 설계/운전 조건 규명 및 경제성 제고 방안을 수립하여야 한다.