• Textile Coloration and Finishing
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• v.12 no.1
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• pp.44-51
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• 2000

The conventional one bath exhaust dyeing system of nylon]/cotton blends with acid dye/direct dye involves a lot of neutral salt which affect dyeability of acid dyes. Because of conventional one bath exhaust dyeing system of nylonl/cotton blends with acid dye/direct dye needs acid dyes adjusted at a neutral liquor, suitable acid dye is limited. To improve dyeing property of nylon/cotton blends, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate dyeing possibilities of nylon/cationized cotton blends with acid dye/direct dye in a non-neutral salt dyebath by one bath two step method. The concentration of direct dye was 1.0%, 0.7%, 0.3%o.w.f. respectively at a non, 1%, 3%owf of reserving agent for being almost equal color strength between nylon and 3% cationized cotton when nylon/3% cationized cotton blends was dyed with acid dye/direct dye at concentration of acid dye(1%o.w.f.) by one bath two step method.

• Textile Coloration and Finishing
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• v.27 no.2
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• pp.105-112
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• 2015

In order to detect gas phase strong acid on fabrics, a hexyl-substituted monoazo yellow dye, which was the modified form of a conventional pH-indicating dye, Methyl Yellow, was studied in view of acid-gas sensing properties and its fastness. The dye was printed on polypropylene non-wovens for protective coveralls and examined under various conditions of strong acid such as hydrochloric acid. The dye showed color change from yellow to red on exposure to gas phase hydrochloric acid as low concentration as 1~3 ppm very instantly. Considering reuse of the dye-printed non-wovens, the repeatability of color change was tested on the same sample for 50 repeats and 100 days. The acid-gas sensing function was maintained almost the same level of initial performance. The color fastness of the dye on polypropylene non-wovens was very good showing higher than ratings 4 except for 3~4 to rubbing under wet condition.

• Analytical Science and Technology
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• v.19 no.1
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• pp.31-38
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• 2006

Micellar electrokinetic capillary chromatography(MECC) and HPLC with ion-pairing mechanism were applied for the separation of the well known environmental wastes from dye industry. These compounds include H-acid, J-acid, ${\gamma}$-acid, orthanilic acid, sulfanilic acid and 2-naphthylamine-1,5-disulfonic acid, and are known to be the diazo components of the azo dye. MECC method was also applied to separate few acid dyes including Acid Orange 7, Acid Orange 5 and Acid Blue 92 and direct dye such as Direct Red 80. Informations about the diazo components of any azo dye could be obtained by comparison of electropherogram of the reduction solution of a given dye with those obtained from standard materials such as H-acid, J-acid, ${\gamma}$-acid, orthanilic acid, sulfanilic acid and 2-naphthylamine-1,5-disulfonic acid. It has been concluded that MECC and HPLC with ion-pairing mechanism could be successfully applied for the analysis of unknown dyes and their diazo components.

• Fibers and Polymers
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• v.7 no.2
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• pp.117-122
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• 2006

The dye-resist effect and leveling properties of hetero-mulifunctional dye-resist agents in acid dyeing of wool were investigated. The dye-resist agent with dichlorotriazinyl group achieved better resist effectiveness than those with monochlo-rotriazinyl group. The resist effectiveness was improved by increasing the number of sulfonate group in dye-resist agents. Also, the resist agents with more sulfonate groups showed better dye-assist effectivness, attributable to the increased electrostatic attraction between dye-resist agents and the cationic dye. However, the leveling properties of dye-resist agents decreased with the number of sulfonate groups in the molecule.

• Textile Coloration and Finishing
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• v.1 no.1
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• pp.47-53
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• 1989

The effect of organic solvent in the dyeing of silk fiber by acid dye was investigated. Acetophenone and benzyl alcohol were shown to be the most effective for the rate of dyeing of silk fiber by Milling Cyanine 5R (C.I. Acid Blue 113), a milling type acid dye, but, with benzyl alcohol, the equilibrium dye uptake was much lower than that in the absence of it. In the presence of solvent, maximum dye uptake shifted to lower temperature than 6$0^{\circ}C$, while without solvent, it was shown at about $60^\circ{C}$. When dyed by Orange II (C.I. acid Orange 7) under same condition equilibrium dye uptake of silk fiber was lower than that for milling type acid dye, and in the presence of benzyl alcohol, still much lower uptake resulted. All these fact reveals that organic solvents in the solvent-assisted dyeing of silk fiber broaden micelle spacings too much, resulting in increased rate of dyeing, and decreased equilibrium dye uptake, contrary to wool.

• Fibers and Polymers
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• v.5 no.3
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• pp.239-244
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• 2004

Solution-cast films of polymethylmethacrylate (PMMA) and polyurethane (PU) containing polymeric styryl dye up to 5 % by weight were prepared to investigate their acid-sensitivity and mechanical and thermal properties. Original red samples due to styryl dye turned out yellow very rapidly as they were exposed to acid vapor of hydrochloric acid or p-toluenesulfonic acid. According to UV/VIS spectroscopic measurements, characteristic peak intensities near 430 nm and 520 nm increased or decreased relatively with exposed amounts of acid, respectively. Both PMMA and PU samples showed uniform color distribution due to a good miscibility between polymer and dye which can be evidenced by measurements of glass transition temperature. No significant difference in acid-sensitivity was found between PU and PMMA except relative absorbance. However, dependence of their mechanical properties on dye content was somewhat different with PU or PMMA. In case of PMMA, modulus and breaking stress increased up to about 50 % with increasing dye content, whereas those of PU samples showed only slight increase. It was ascribed to whether the matrix polymer was in the glassy or rubbery state.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.4
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• pp.74-80
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• 2009

Effect of dye wastewater on heavy metal removal using carboxylated alginic acid bead was performed. When carboxylated alginic acid bead was used as support, effect of dye wastewater on adsorption of $Pb^{2+}$ and $Cu^{2+}$ ions was very small. Also, when $Pb^{2+}$ was coexisted with dye wastewater, adsorption process was almost completed within 2-3 hrs and $Pb^{2+}$ ions (50 ppm) was almost removed with 0.3g of bead. This result means that carboxylated alginic acid bead has effective adsorbent for heavy metal removal in dye wastewater.

• Journal of the Korean Society of Clothing and Textiles
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• v.24 no.3
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• pp.385-392
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• 2000

The adsorption ability of dyes on chitin, a natural polymer was investigated for decolorization of dye wastewater. Chitin was manufactured in lab by decalcification in dilute aqueous HCI solution and deproteination in dilute aqueous NaOH solution with shrimp shells. Absorbance of residue solution of dyebaths after dye adsorptions of chitin were measured in varieties of dye concentration and dipping periods. Four kinds of dyestuffs were used, C.I.Acid Blue 29. C.I.Direct Blue 6, C.I.Reactive Orange 12 and C.I.Basic Red 18. When chtin 1g was dipped in 0.05% of dyebath with stirring, maximum adsorption ratio of each kind of dyes was exhibited as 91.6% for C.I.Acid Blue 29, 95% for C.I.Direct Blue 6, 58.2% for C.I.Reactive Orange 13 and 75.8% for C.I.Basic Red 19. It shows that chitin has better adsorption abilities of ionic dyes of acid, direct and basic dye than non-ionic reactive dye. And chitin has better adsorption abilities of anionic acid direct dyes than cationic basic dye because of the presence of nitrogen atoms. All kinds of dyestuffs used showed speedy absorption effects by chitin, so chitin can absorb much amount of dyes in 5 mimutes reach to equilibrium of adsorption in 2 hours after dipping. Basic dye was absorbed the most speedily in 5 minutes, although maximum adsorption ratio is not high. That reason can be thought that chitin surface is essentially negatively charged due to polar funtional groups.

• Analytical Science and Technology
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• v.19 no.1
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• pp.50-57
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• 2006

Well known environmental wastes from dye industry were separated by the micellar electrokinetic capillary chromatography(MECC). These wastes include H-acid modifier and 2-naphthylamine-1,5-disulfonic acid, and are known to be the diazo components of the azo dye. The results of the separation were compared with the result obtained by the HPLC using ion-pairing mechnism. MECC method was also applied to separate a few direct dyes including Direct Blue 2, Direct Blue 6 and Direct Blue 15, and reactive dye such as Reactive Orange 4. Informations about the diazo components of any azo dye could be obtained by comparison of electropherogram of the reduction solution of given dye with those obtained from standard materials such as H-acid, J-acid, ${\gamma}$-acid, orthanilic acid, sulfanilic acid and 2-naphthylamine-1,5-disulfonic acid which are used as diazo components of the typical azo dyes. It has been concluded that MECC and HPLC with ion-pairing mechanism could be successfully applied for the analysis of unknown dyes and their diazo components.

• Textile Coloration and Finishing
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• v.3 no.3
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• pp.34-43
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• 1991

The dyeing property of milling type acid dyes with various chemical constitution were studied in one bath dyeing of Wool/Nylon blended fabrics and the proper dyeing condition to get solid color by using reserving agent was also examined. The result of the experiments can be summarized as follows; 1) Although the effect of pH on dyeing of wool with a highly hydrophiilic dye is great in the dyeing of wool and nylon, the proper pH of dyeing bath is weakly acidic 5, in which levelling dye can be obtained by increasing the solubility product. 2) Under a constant pH, the dye with fewer numbers of sulfonic acid groups increases the dyeing amount of nylon as the concentration of the dye is increased. Thus the appropriate dye for light color is the one with many numbers of sulfonic acid groups and the proper dye for medium and deep color is of fewer sulfonic acid groups for one-bath dyeing. 3) When the dye concentration is greater than the critical depth, the K/S value of wool and nylon was almost not effected or slightly increased.