• Title/Summary/Keyword: acid attack

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Change of Fine Structure of Aliphatic Polyester fiber by strectching

  • 홍기정;박수민
    • Proceedings of the Korean Fiber Society Conference
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    • 1997.04a
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    • pp.328-332
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    • 1997
  • Hot stretching focused on the improvement of properties of poly(L-lactic acid) fiber. Some aliphatic polyesters are biodegradable under microbial attack and the new unique applications are expected. Generally, these materials have a somewhat low melting temperature and low mechanical properties compared with the aromatic polyesters. In this study, melt-spinning of poly(L-lactic acid) was conducted. We investigated effects of the stretching and the molecular orientation of aliphatic polyester fibers on the change of fine-structure. Glass transition temperature, molecular orientation and crystallinity increased according to the increase of stretching ratio.

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Acid Corrosion Resistance and Durability of Alkali-Activated Fly Ash Cement-Concrete (알칼리활성 플라이 애쉬 시멘트-콘크리트의 산저항성 및 내구성)

  • Kang, Hwa-Young;Park, Sang-Sook;Han, Sang-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.1
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    • pp.61-68
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    • 2008
  • A new cementitious material has been developed, called alkali-activated fly ash cement(AAFC), which is used to produce AAFC-concrete for construction. The effect of acid attack, sodium chloride solution, carbonation, freeze-thaw cycling, and SEM, XRD analysis of the AAFC-concrete prepared using alkali-activated fly ash cement and OPC-concrete were experimentally investigated. It was found that the acid resistance of AAFC-concrete(35 MPa) prepared from alkali-activated fly ash at 85$^{\circ}C$ for 24 hrs is far better than OPC-concrete(35 MPa). Also, the AAFC-concrete(35 MPa) had a similar resistance of OPC-concrete(35 MPa) to attack, such as sodium chloride solution, carbonation and freeze-thaw cycling.

Performance of eco-friendly mortar mixes against aggressive environments

  • Saha, Suman;Rajasekaran, Chandrasekaran;Gupta, Prateek
    • Advances in concrete construction
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    • v.10 no.3
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    • pp.237-245
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    • 2020
  • Past research efforts already established geopolymer as an environment-friendly alternative binder system for ordinary Portland cement (OPC) and recycled aggregate is also one of the promising alternative for natural aggregates. In this study, an effort was made to produce eco-friendly mortar mixes using geopolymer as binder and recycled fine aggregate (RFA) partially and study the resistance ability of these mortar mixes against the aggressive environments. To form the geopolymer binder, 70% fly ash, 30% ground granulated blast furnace slag (GGBS) and alkaline solution comprising of sodium silicate solution and 14M sodium hydroxide solution with a ratio of 1.5 were used. The ratio of alkaline liquid to binder (AL/B) was also considered as 0.4 and 0.6. In order to determine the resistance ability against aggressive environmental conditions, acid attack test, sulphate attack test and rapid chloride permeability test were conducted. Change in mass, change in compressive strength of the specimens after the immersion in acid/sulphate solution for a period of 28, 56, 90 and 120 days has been presented and discussed in this study. Results indicated that the incorporation of RFA leads to the reduction in compressive strength. Even though strength reduction was observed, eco-friendly mortar mixes containing geopolymer as binder and RFA as fine aggregate performed better when it was produced with AL/B ratio of 0.6.

Mechanical and durability properties of concrete incorporating glass and plastic waste

  • Abdelli, Houssam Eddine;Mokrani, Larbi;Kennouche, Salim;Aguiar, J.L. Barroso de
    • Advances in concrete construction
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    • v.11 no.2
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    • pp.173-181
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    • 2021
  • The main objective of this work is to contribute to the valorization of plastic and glass waste in the improvement of concrete properties. Waste glass after grinding was used as a partial replacement of the cement with a percentage of 15%. The plastic waste was cut and introduced as fibers with 1% by the total volume of the mixture. Mechanical and durability tests were conducted for various mixtures of concrete as compressive and flexural strengths, water absorption, ultrasonic pulse velocity, and acid attack. Also, other in-depth analyses were performed on samples of each variant such as X-ray diffraction (XRD), thermogravimetric analysis (DSC-TGA), and scanning electron microscope (SEM). The results show that the addition of glass powder or plastic fibers or a combination of both in concrete improved in the compression and flexural strengths in the long term. The highest compressive strength was obtained in the mix which combines the two wastes about 26.72% of increase compared to the control concrete. The flexural strength increased in the mixture containing the glass powder. Therefore, the mixture with two wastes exhibits better resistance to aggressive sulfuric acid attack, and incorporating glass powder improves the ultrasonic pulse velocity.

Deterioration Properties of Shotcrete as Tunnel Supporter was Exposed to Harmful Ions (터널 지보용 숏크리트의 유해이온에 대한 열화특성)

  • Jung, Ho-Seop;Kim, Dong-Gyou
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.5
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    • pp.55-64
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    • 2008
  • Shotcrete have become a deterioration which was exposed to harmful environments. In this study, in order to evaluate the deterioration properties of shotcrete, visual examination, compressive strength, adhesive strength, microstructural analysis were investigated up to the 60th weeks of exposure. The attack solutions for test are sodium sulfate and hydrochloric acid solution with different concentrations, respectively. From the results, although the compressive strength of shotcrete specimens and the adhesive strength between specimens and rocks were high at the early immersion age, they rapidly dropped in the subsequent phases, especially in 5% sodium sulfate and pH1 hydrochloric acid solution. With continued exposure, various harmful ions penetrated into the shotcrete specimen, reacted with the cement hydrate, and generated expansion substances. It was verified that the shotcrete specimens suffered a serious deterioration by chemical attack.

Pretreatment on Corn Stover with Low Concentration of Formic Acid

  • Xu, Jian;Thomsen, Mette Hedegaard;Thomsen, Anne Belinda
    • Journal of Microbiology and Biotechnology
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    • v.19 no.8
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    • pp.845-850
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    • 2009
  • Bioethanol derived from lignocellulosic biomass has the potential to replace gasoline. Cellulose is naturally recalcitrant to enzymatic attack, and it also surrounded by the matrix of xylan and lignin, which enhances the recalcitrance. Therefore, lignocellulosic materials must be pretreated to make the cellulose easily degraded into sugars and further fermented to ethanol. In this work, hydrothermal pretreatment on corn stover at $195^{\circ}C$ for 15 min with and without lower concentration of formic acid was compared in terms of sugar recoveries and ethanol fermentation. For pretreatment with formic acid, the overall glucan recovery was 89% and pretreatment without formic acid yielded the recovery of 94%. Compared with glucan, xylan was more sensitive to the pretreatment condition. The lowest xylan recovery of 55% was obtained after pretreatment with formic acid and the highest of 75% found following pretreatment without formic acid. Toxicity tests of liquor parts showed that there were no inhibitions found for both pretreatment conditions. After simultaneous saccharification and fermentation (SSF) of the pretreated corn stover with Baker's yeast, the highest ethanol yield of 76.5% of the theoretical was observed from corn stover pretreated at $195^{\circ}C$ for 15 min with formic acid.

The Effect of Gamma-Irradiation on Aqueous Solutions of Triglycine 3. Mechanism for Gamma-ray Induced Degradation Products (Triglycine 수용액에 미치는 감마선의 영향 3. 감마선에 의한 분해산물에 관하여)

  • ;LEONE, Charles A
    • The Korean Journal of Zoology
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    • v.7 no.2
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    • pp.1-5
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    • 1964
  • Carbonyl compounds, glycine, ammonia, carbon dioxide and hydrogen have been identified in gamma-irradiated oxygenated aqueous solutions of triglycine. The reactions occurring in this system are postulated only by representing the initial process and the final products. The triglycine molecule undergoes a reaction to form an intermediate giving rise to carbonyl compounds and acid amides. These compounds are decomposed to acetamide, glycine, glyoxylic acid, formic acid, oxalic acid, ammonia, and carbon dioxide by free radical attack in the primary and/or secondary reactions. It is also possible that the unrecognized reactions may give rise to products formed by radical-radical combinations. Satisfactory material balance for all the products have to wait until the completion of a study now in progress.ogress.

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Be study technical information protection in ubiqutious home networks (유비쿼터스 홈 네트워크에서의 정보보호 기술 연구)

  • Cheon, Jae-Hong;Park, Dea-Woo
    • KSCI Review
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    • v.15 no.1
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    • pp.65-75
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    • 2007
  • Analyzed about a matter and requirements to intimidate security of ubiquitous and home network threatening various security for personal information protection in ubiquitous home networks at these papers, and studied. Got authentication procedures and verification procedures acid user approach to be reasonable through designs to the home security gateway which strengthened a security function in the outsides, and strengthened protection of a home network. Also, execute a DoS, DDoS, IP Spoofing attack protective at home network security gateways proved, and security regarding an external denial of service attack was performed, and confirmed. Strengthen appliances and security regarding a user, and confirm a defense regarding an external attack like DoS, DDoS, IP Spoofing, and present a home network security model of this paper to the plans that can strengthen personal information protection in ubiquitous home networks in ubiquitous home networks through experiment.

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Sustainable construction material using nanosilica and multi-walled carbon nanotubes in cement concrete

  • Breetha Yesudhas Jayakumari;Elangovan Nattanmai Swaminathan;Pachaivannan Partheeban
    • Advances in nano research
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    • v.16 no.5
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    • pp.459-472
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    • 2024
  • Nanotechnology is a popular field in the construction industry due to its multiple functions. It mitigates CO2 emissions and enhances the desirable properties of concrete by replacing small amounts of cement with supplements. This study assess the sustainability impact of using two different nanoparticles partially replacing the cement with 0.3%, 0.6%, 1.0% of nano silica (NS) and 0.03%, 0.045%, 0.06% of Multi-Walled Carbon Nanotubes (MWCNT) in the green concrete mix developement. Nano-sized fragments at the atomic scale tends to modify the properties of concrete. Concrete may increase its strength, durability by adding nanocomposite materials, which will decrease the amount of nano and micropores in structural parts. The strength of the structural elements can be greatly improved and allowing them to withstand higher loads and resist deformation. It improved durability properties by 64.8% in water absorption, 56.4% in acid attack, 78.1% in sulphate attack, and 53.4% in chloride attack. There was an improvement in compressive strength of 37% and split tensile strength of 90%. SEM, FTIR, and XRD investigations have used to look at the microstructural characteristics of nanoconcrete dictated the microstructure characteristics may be made more consistent and dense by adding nanocomposite materials.

Naturally-Occurring Novel Anticatcinogens : Conjugated Dienoic Derivatives of Linoliec Acid (CLA) (새로이 분류된 천연 항암제 : Conjugated Dienoic Derivatives of Linoleic Acid (CLA))

  • 하영래;마이클파리자
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.20 no.4
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    • pp.401-407
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    • 1991
  • Anticarcinogenic conjugated dienoic derivatives of linoleic acid (CLA) is present in grilled beef, cheese, and related foods, CLA is generated via isomerization of linoleic acid in the cow's rumen by anaerobic bacteria and food proceessing as well. Another source of CLA is its endogenous generation via the carbon centered free radical oxdation of linoleic acid. We propose that the formation and generation of CLA in vivo represents a previously unrecognized in situ "defense mechanism" against membrane attack by oxygen free radicals. The cis, 9-trans, 11 CLS isomer is selectively incorporated into cellular phospholipid, which exhibits a potent antioxidant, reduces the activation of 2-amino-3-methylimidazo, [4,5-f] quinoline (IQ) for baxterial mutagenesis, and inhibits ornithine decarboxylase(ODC) activity induced by 12-0-tetradecanoylphorbol-13-acetate (TPA). We believe that at least these biological activities of CLA explain the anticarcinogenic activity of CLA.

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