• 한국응용과학기술학회지
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• 제5권1호
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• pp.41-51
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• 1988

Aliphatic aldehyde polyoxyethylene glycol acetals were synthesised through the reaction of aliphatic aldehydes such as caproic aldehyde, capryl aldehyde, capric aldehyde and lauric aldehyde with excess diethylene glycol, triethylene glycol and tetraethylene glycol, respectively. The acetal formation, in which water was azeotropically distilled by adding benzene to the reaction system, was gained a good yield of acetal type compounds. This reaction is found pseudo first order reaction at various temperatures such 70, 80, 90 and $97^{\circ}C$. Also these activation energies of reaction of acetal type products such as caproic aldehyde diethylene glycol acetal, capryl aldehyde diethylene glycol acetal, capric aldehyde diethylene glycol acetal, lauric aldehyde diethylene glycol acetal, caproic aldehyde triethylene glycol acetal and caproic aldehyde tetraethylene acetal were 17.3, 19.6, 21.2, 21.6, 15.5 and 14.7 Kcal/mole.

• 대한화학회지
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• 제28권5호
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• pp.335-341
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• 1984

${\alpha},{\beta}$-불포화 알데히드의 아세탈은 브롬화 방향족화합물들과 팔라듐 촉매와 트리에틸아민 존재하에서 쉽게 반응하여 방향족의 conjugated enals을 생성하였다. 불포화 아세탈로서 acrolein diethyl acetal과 methacrolein diethyl acetal을 사용하여 이들을 메틸기와 이소프로필기로 치환된 브롬화 방향족화합물들과 $100^{\circ}C$에서 반응시킨 뒤 생성물들을 옥살산 수용액으로 처리하여 방향족의 conjugated enals를 합성하였다. o-bromotoluene과 methacrolein diethyl acetal과의 반응을 제외하고는 모두 60% 이상의 좋은 수득율을 얻을 수 있었으며 생성물의 구조는 proton NMR과 IR스펙트럼으로 확인하였다. 3-bromopropenal dimethyl acetal 및 (E)-3-bromo-2-methylpropenal diethyl acetal을 할로겐화 비닐화합물의 반응 부위로 하고 1-알켄과 ethyl acrylate등을 올레핀 반응 부위로 하는 반응물들의 역조합(reverse combination)에 의하여 지방족의 2,4-dienals를 50% 이상의 수득율로 합성 할 수 있다.

• Rapid Communication in Photoscience
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• 제2권3호
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• pp.76-78
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• 2013

Photoaddition reactions of aromatic carbonyl compounds with silyl thioketene acetals have been explored. The results of this study show that the acetonphenone react with dimethyl substituted silyl thioketene acetal competitively via either single electron transfer (SET)-desilylation or [2+2]-cycloaddition pathways to produce b-hydroxyester and oxetanes. In contrast, photochemical reactions of the benzaldehyde with dimethyl substituted silyl thioketene acetal mainly lead to the formation of oxetanes arising by [2+2] cycloaddition. A comparison of the results with those of silyl ketene acetal revealed that replacement of sulfur atom in ${\alpha}$-silyl donor substrate bring about dramatic changes in chemoselectivities as well as excited state reaction mechanism.

• Tribology and Lubricants
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• 제16권1호
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• pp.1-8
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• 2000

Friction and wear tests have been performed on nylon, acetal resin, and PTFE (polytetrafluoroethylene), in reciprocating dry sliding conditions against steel discs. According to the results, acetal resin showed the lowest wear rates and PTFE exhibited the lowest friction coefficient. The prominent wear mechanisms found were adhesion and abrasion.

• 대한치과기공학회지
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• 제23권1호
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• pp.107-114
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• 2001

R.P.D fabrication can be made if the skills already is properly used in the manufacturing press. You may feel extremely comfortable to wear it. The material used has high elasticity that it can endure the hole process of Acetal Wax pattern casting without any deformation moreover its adaptability is not bad. Because of the poor financial condition of patterns and health insurance, Acetal R.P.D Framework can be one of the best alternatives used for setting clasp partial denture cheaply. R.P.D Framework is aesthetically excellent. The color caused by saliva is so similar to that of the rest of teeth that even dentists as well as patients can not recognize clasp arm. Clasp also helps to secure prosthesis ideally without damaging teeth due to its deep position downward. Since dentists and patients have a good reaction to clasp so far, we are encouraged to apply it to other technical fields.

• Bulletin of the Korean Chemical Society
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• 제23권1호
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• pp.154-156
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• 2002

• Bulletin of the Korean Chemical Society
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• 제19권8호
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• pp.862-868
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• 1998

The Lewis acid mediated intramolecular additions of allylsilanes to acetal substrates are described. Excellent regio- and diastereoselectivity are achieved by boron trifluoride promoted cyclization of allysilane-acetals 5 and 8 derived from hydroxy allysilances 3. Cyclizations occur in moderate to high yields, providing directr routes to cis-2, 6-disubstituted 4-methylenetetrahydropyrans 6 and 9.

• 대한기계학회논문집A
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• 제24권9호
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• pp.2387-2396
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• 2000

Wear and operation characteristics of Nylon and Acetal pinion against steel gear were studied to gain a better understanding of their tribological and mechanical behavior. Tests were conducted with power circulating gear test rig under unlubricated conditions. Specific wear rates were measured as a function of applied load and total revolution. The worn tooth surfaces were examined with a profile projector and camera. Nylon pinion showed lower specific wear rates than Acetal pinion, but it revealed breakage at high load. Principal wear depths were developed at tooth tip and below the pitch line of pinion. Life estimation for the Nylon pinion was made by taking into account steel gear equivalent Hertz stress and average sliding velocity. The dominant wear mechanisms were adhesion and abrasion.

• Tribology and Lubricants
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• 제8권1호
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• pp.48-55
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• 1992

The friction characteristic of plastics (PTFE, Nylon, Acetal and phenolic) was studied on the lubricated condition with a pin on disk machine. Mineral oil without additive (base oil) and water were used as liquid lubricants at the controlled temperature. From the experimental work, it was found out that the coefficient of friction of plastics was controlled by the mechanical properities of plastic more than that of liquid for various load and temperature. Viscosity of liquid has affected on the friction only at low temperature under lighb load. Among the tested plastics, the coefficient of friction of PTFE was the lowest under light load and at low temperature while Nylon at medium load and temperature, and Acetal at heavy load and high temperature. The coefficient of friction of soft plastics like PTFE and Nylon were increased as the load and temperature were increased, while that of hard plastic (Acetal) was decreased and that of thermo setting plastic (phenolic) was mixed. Also for soft plastics, the coefficient of friction under heavy load was always higher than that under light load, while hard plastic was vice versa.

• 대한기계학회논문집A
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• 제25권11호
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• pp.1720-1729
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• 2001

Wear characteristics of Nylon and acetal pinions against steel gears for different pitch line velocities was studied with a power circulating gear test rig under unlubricated condition. Specific wear rate was measured as a function of tooth number, module, tooth width and total revolution. The worn tooth surfaces were examined with a profile projector. The Nylon pinion showed lower specific wear rate than the acetal pinion. However, the Nylon pinion was fractured at high tooth loads, whereas the acetal pinion exhibited a steady wear behavior. The wear characteristics of Nylon pinion varied significantly with the Pitch line velocity. Wear occurred most severely at the tooth tip and the region immediately below the pitch line of pinion. The dominant wear mechanisms were adhesion and abrasion.