• Title/Summary/Keyword: accumulation buffer

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Si-buffer pinholes in the SEPOX (selective poly oxidation) process (SEPOX (selective poly oxidation) process에서 Si-buffer layer에 발생하는 pinhole 현상에 대한 연구)

  • 윤영섭
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.6
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    • pp.151-157
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    • 1996
  • We propose a mechanism for the formation of pinholes in the Si-buffer layer, through the observations with varying the process- and structure variables in the SEPOX (selective poly-oxidation) process, an isolation method for sub-u DRAMs. Pinholes are formed through the accumulation of Si vacancies generated by the oxidation of Si, in which Si atoms leave the sites (vacancies) at the Si/SiO$_{2}$ interfaces and diffuse into the oxide to be oxidized near interface. In the course of the accumulation of Si-vacancies, the stress induced in the Si-buffer layer affects the migration of vacancies to result in the final size and distribution of pinholes. This paper may be, to our knowledge, the first report about the oxidation-induced pinhole in the Si/SiO$_{2}$ system.

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An Efficient Latency Hiding method using accumulation buffer (누적 버퍼를 활용한 효율적인 Latency Hiding기법)

  • Lee, Min-Woo;Han, Tack-Don
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2012.07a
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    • pp.297-300
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    • 2012
  • 현재 cache의 성능 향상을 위한 많은 기법들이 제안되고 있으며, Latency Hiding 기법 역시 cache의 효율적인 사용을 위해 많은 연구가 진행 되어 왔다. write buffer를 사용한 write Latency hiding기법이나 multi threading을 사용한 Latency Hiding 방법 등 여러 기법들이 연구되어 왔으며, 지금도 Latency hiding을 위한 많은 연구들이 지속적으로 진행되고 있다. 본 논문 역시 효율적인 Latency Hiding을 위한 누적 버퍼를 제안한다. 본 논문은 누적 버퍼의 활용도를 조사하여 얼마나 효율적으로 Latency를 은폐했는지, 또 버퍼를 사용함으로써 얻는 다른 이점에 대해 집중적으로 연구하였다.

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Adsorptive Stripping Voltammetric Determination of Ruthenium (흡착 벗김법에 의한 루테늄 정량)

  • Hong, Tae-Kee;Kwon, Young-Soon;Czae, Myung-Zoon
    • Analytical Science and Technology
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    • v.10 no.2
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    • pp.119-125
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    • 1997
  • A stripping voltammetric procedure for determining ruthenium was developed, based on the adsorptive accumulation of ruthenium in the presence of hydrazine in acidic acetate buffer. After preconcentration of ruthenium compelex and reduction, the ruthenium-catalyzed hydrogen current at -0.84V was measured by differential pulse voltammetry. Optimal experimental conditions were found to be a stirred acetate buffer solution(pH 2.0) containing 0.01M acetate and 0.01M hydrazine, accumulation potential of -0.76V, and a scan rate of 5mV/s. The detection limit was $2{\times}10^{-9}M$ for a 7 min accumulation period. The possible interferences by other platinum group metals were also investigated.

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Impact of Solution-Processed BCP Buffer Layer on Efficient Perovskite Solar Cells (페로브스카이트 태양전지에서의 저온 용액 공정의 BCP 버퍼층 효과)

  • Jung, Minsu;Choi, In Woo;Kim, Dong Suk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.1
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    • pp.73-77
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    • 2021
  • Inorganic-organic hybrid perovskite solar cells have demonstrated considerable improvements, reaching 25.5% of certified power conversion efficiency in 2020 from 3.8% in 2009. In normal structured perovskite solar cells, TiO2 electron-transporting materials require heat treatment process at a high temperature over 450℃ to induce crystallinity. Inverted perovskite solar cells have also been studied to exclude the additional thermal process by using [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as a non-oxide electron-transporting layer. However, the drawback of the PCBM layer is a charge accumulation at the interface between PCBM and a metal electrode. The impact of bathocuproin (BCP) buffer layer on photovoltaic performance has been investigated herein to solve the problem of PCBM. 2-mM BCP-modified perovskite solar cells were observed to exhibit a maximum efficiency of 12.03% compared with BCP-free counterparts (5.82%) due to the suppression of the charge accumulation at the PCBM-Au interface and the resulting reduction of the charge recombination between perovskite and the PCBM layer.

Improvement of Hybrid EL Efficiency in Nanoparticle EL Devices by Insertion of the Layers of PVK and BaF2

  • Lee, Jun-Woo;Cho, Kyoung-Ah;Kim, Hyun-Suk;Park, Byoung-Jun;Kim, Sang-Sig;Kim, Sung-Hyun
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.3
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    • pp.101-105
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    • 2005
  • Electroluminescence(EL) and current-voltage(I-V) characteristics of hybrid EL devices containing Pr and Mn co-doped ZnS nanoparticles were investigated in this study. For the insertion of a hole transport layer of poly (N-vinyl carbazole)(PVK), the current level became lower due to the accumulation of electrons at the interface between PVK and nanoparticles. When both PVK and buffer layer $BaF_2$ were simultaneously introduced, the enhanced EL efficiency and improved I-V characteristics were obtained. This results from the additional increase of hole injection owing to the internal field induced by the significant accumulation of electrons at the interface. The presence of buffer layer $BaF_2$ together with PVK makes it possible the charge accumulation enough to induce the sufficient internal field for further hole injection.

Effects of Ionic Strength in the Medium on Sample Preconcentration Utilizing Nano-interstices between Self-Assembled Monolayers of Gold Nanoparticles

  • Nguyen, Ngoc-Viet;Wu, Jian-Sheng;Jen, Chun-Ping
    • BioChip Journal
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    • v.12 no.4
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    • pp.317-325
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    • 2018
  • This paper investigated the effects of ionic strength in the medium on a preconcentrator for a protein sample with low concentration. The preconcentration chip was designed and fabricated using a polydimethylsiloxane replica through standard lithophotography. A glass substrate is silanized prior to functionalizing the nanoparticles for self-assembly at a designed region. Due to the overlap of electrical double layers in a nanofluidic channel, a concentration polarization effect can be achieved using an electric field. A nonlinear electrokinetic flow is induced, resulting in the fast accumulation of proteins in front of the induced ionic depletion zone, so called exclusion-enrichment effect. Thus, the protein sample can be driven by electroosmotic flow and accumulated at a specific location. The chip is used to collect fluorescein isothiocyanate-labeled bovine serum albumin (FITC-BSA) diluted in phosphate-buffered saline (PBS) buffer solution. Different concentrations of the buffer media were studied herein. Fluorescence intensity images show that the buffer concentration of 4 mM is more appropriate than all the other ones. The sample of FITC-BSA with an initial concentration of $10{\mu}M$ in the 4 mM PBS solution increases its concentration at the desired region by up to 50 times within 30 min, demonstrating the results in this investigation.

Effect of pH Buffer and Carbon Metabolism on the Yield and Mechanical Properties of Bacterial Cellulose Produced by Komagataeibacter hansenii ATCC 53582

  • Li, Zhaofeng;Chen, Si-Qian;Cao, Xiao;Li, Lin;Zhu, Jie;Yu, Hongpeng
    • Journal of Microbiology and Biotechnology
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    • v.31 no.3
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    • pp.429-438
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    • 2021
  • Bacterial cellulose (BC) is widely used in the food industry for products such as nata de coco. The mechanical properties of BC hydrogels, including stiffness and viscoelasticity, are determined by the hydrated fibril network. Generally, Komagataeibacter bacteria produce gluconic acids in a glucose medium, which may affect the pH, structure and mechanical properties of BC. In this work, the effect of pH buffer on the yields of Komagataeibacter hansenii strain ATCC 53582 was studied. The bacterium in a phosphate and phthalate buffer with low ionic strength produced a good BC yield (5.16 and 4.63 g/l respectively), but there was a substantial reduction in pH due to the accumulation of gluconic acid. However, the addition of gluconic acid enhanced the polymer density and mechanical properties of BC hydrogels. The effect was similar to that of the bacteria using glycerol in another carbon metabolism circuit, which provided good pH stability and a higher conversion rate of carbon. This study may broaden the understanding of how carbon sources affect BC biosynthesis.

Adsorptive Stripping Voltammetrical Determination of Zirconium (흡착벗김 전압전류법적 지르코늄의 정량)

  • Choi, Won Hyung;Lee, Jin Sik;Kim, Do Hoon;Kim, Jong Cheol
    • Analytical Science and Technology
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    • v.6 no.5
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    • pp.425-433
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    • 1993
  • Adsorptive stripping voltammetric determination method of trace zirconium using oxine as a ligand was studied. Optimal conditions found to be $2.5{\times}10^{-3}M$ borax buffer solution(pH 8.5) containing oxine concentration of $4{\times}10^{-8}M$. Accumulation potential was -0.2V, accumulation time was 400sec and scan rate was 4mV/sec. Calibration plots for zirconium are linear over the range of $1{\sim}100{\mu}g/L$ in optimal condition.

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The study of Germanium analysis by Adsorption Stripping Voltammetry (흡착벗김 전압전류법을 이용한 게르마늄 분석에 관한 연구)

  • Yun, Young Ja;Jeong, David;Namgung, Mi Ok
    • Analytical Science and Technology
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    • v.8 no.2
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    • pp.171-179
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    • 1995
  • This is an analytical study of germanium by adsorption stripping squarewave voltammetry. Tannic acid was used as a ligand. The accumulation potential was -0.2V, accumulation time was carried out for 60 second under constant stirring, followed by a 20 second quiescent period, and frequency was 10Hz. A hanging mercury drop electrode was used as a working electrode and acetate buffer solution, pH=4.5, as supporting electrolyte. The proper conditions of ligand for germanium analysis was established. The effect of metal ions(lead, cupper, silicon, tin, gallium) on germanium peak was also studied.

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Electrochemical Determination of Ciprofloxacin Based on the Enhancement Effect of Sodium Dodecyl Benzene Sulfonate

  • Zhang, Shenghui;Wei, Shuang
    • Bulletin of the Korean Chemical Society
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    • v.28 no.4
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    • pp.543-546
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    • 2007
  • Herein, a new electrochemical method was described for the determination of ciprofloxacin based on the enhancement effect of an anionic surfactant: sodium dodecyl benzene sulfonate (SDBS). In pH 4.0 phosphate buffer and in the presence of 1.0 × 10-4 mol/L SDBS, ciprofloxacin yields a well-defined and sensitive oxidation peak at the carbon paste electrode (CPE). Compared with that in the absence of SDBS, the oxidation peak current of ciprofloxacin remarkably increases in the presence of SDBS. The experimental parameters, such as supporting electrolyte, concentration of SDBS, and accumulation time, were optimized for ciprofloxacin determination. The oxidation peak current is proportional to the concentration of ciprofloxacin over the range from 8.0 × 10-8 to 5.0 × 10-6 mol L-1. The detection limit is 2.0 × 10-8 mol L-1 after 2 min of accumulation. This new voltammetric method was successfully used to detect ciprofloxacin in drugs.