• Korean Chemical Engineering Research
• /
• 제61권3호
• /
• pp.362-367
• /
• 2023

최근 고분자 전해질 연료전지(PEMFC)에서 고분자 막의 연구개발은 가격 저감과 성능 향상을 위해 박막화하는 방향으로 진행되고 있다. 그리고 상용차용 수소 전기 차량 수요가 증가하고 있는데, 승용차용보다 내구성이 5배 증가해야 한다. 막의 두께가 얇아짐에도 불구하고 내구성은 5배 증가해야 하므로, 막의 내구성 향상이 더 중요해진 상황이다. 가속 내구 평가 시간도 단축해야하기 때문에 기존 프로토콜에서 공기 대신 산소를 사용한 프로토콜을 10 ㎛ 박막에 적용해 내구성을 평가하였다. 가속 내구 평가(개회로 전압 유지)는 720시간에 종료하였다. 공기를 사용한 미국 에너지부(DOE) 프로토콜을 사용했다면 약 1,500시간의 내구성으로 운전시간 450,000 km 수명을 예상한다. 화학적 내구 평가중에 전극의 활성 면적이 51% 감소해 촉매 열화가 막 내구성 약화에 영향을 준 것으로 판단되고, 촉매 열화 속도를 감소시키면 막 내구성이 증가할 것으로 예상된다.

• Journal of Biosystems Engineering
• /
• 제30권2호
• /
• pp.89-94
• /
• 2005

The compression strength of corrugated fiberboard container for packaging the agricultural products rapidly decreases because of various environmental conditions during distribution of unitized products. Among various environmental conditions, the main factors affecting the compression strength of corrugated fiberboard are absorption of moisture, long-term accumulative load, and fatigue caused by shock and vibration. An estimated rate of damage for fruit during distribution is about from 30 to 40 percent owing to the shock and vibration. This study was carried out to characterize the durability of corrugated fiberboard container for packaging the fruit and vegetables under simulated transportation environment. The vibration test system was constructed to simulate the land transportation using truck. After the package with corrugated fiberboard container was vibrated by vibration test system at various experimental conditions, the compression test for the package was performed. The compression strength of corrugated fiberboard container decreased with loading weight and vibrating time. The multiple nonlinear regression equation for predicting the decreasing rate of compression strength of corrugated fiberboard containers were developed using four independent variables such as input acceleration level, input frequency, loading weight and vibrating time. The influence of loading weight on the decreasing rate of corrugated fiberboard container was larger than other variables.

• 한국철도학회:학술대회논문집
• /
• 한국철도학회 2009년도 춘계학술대회 논문집 특별세미나,특별/일반세션
• /
• pp.421-426
• /
• 2009

Recently, the design process for a railway bogie frame in Europe has been carried out according to the norm EN 13749. The activities in the norm EN shall demonstrate that the design of the bogie frame fulfills the acceptances of 4 steps of the program such as structural calculation, static tests, fatigue test and on-tracks tests. At the end of the acceptance program, the on-tracks tests have the aim to measure the real stress history generated in operation and to verify that they are reasonably next to those calculated and measured on the test rig. Therefore, in order to assure the safety of the railway vehicle, it is important to examined the durability of that under load histories measured from on-tracks tests. In this study, under variable amplitude loading based on the actual acceleration history, fatigue analysis of the welding bogie frame is investigated by using durability software. Moreover, the fatigue life of the frame under the loading in the norm EN fatigue test condition is evaluated and compared with the life under variable amplitude loading.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
• /
• pp.221-224
• /
• 2005

In order to traffic safety during winter season, snowfall and cold area has been spread the deicing chemicals, and the spraying amount is increasing every year. Use of deicing chemicals has been and will continue to be a major part of highway snow and ice control methods. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. Extensive use of chloride deicers is, however, the source of substantial cost penalties due to their corrosive action and acceleration to deterioration concrete structures. Deterioration due to de-icer salt occurs in practice in concrete pavement, dike, barrier and similar structure. This paper reports the results of effect of de-icer salt on durability of concrete structure in winter. To protect concrete structure from damage by de-icer salt in winter, the exposure test was performed using three methods such as increase in design strength upto 35MPa application of granulated blast furnace slag powder, and concrete sealer. Of these, the method of increase in design strength upto 35MPa showed better durability for deterioration by de-icer salt.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
• /
• pp.221-224
• /
• 2004

Several factors of concrete durability decline factor are acted as complex deterioration and is happened not that happen by simplicity deterioration. Specially, in case of sea construction, as complex salt damage, carbonation and freezing & thawing, concrete surface and pore structure is deteriorated. Therefore, analyzing concrete carbonation and pore structure after freezing and thawing test by fresh water and sea water in this research, we wish to study about acceleration of decline of durability and complex deterioration by concrete surface deterioration in sea environment.

• Korean Chemical Engineering Research
• /
• 제61권4호
• /
• pp.517-522
• /
• 2023

고분자전해질 연료전지 (PEMFC)에 공기와 수소를 공급하고 개회로전압 (OCV) 상태에서 가습/건조를 반복하는 고분자막의 화학적/기계적 내구성 평가법이 사용되고 있다. 이 프로토콜에서 가습/건조가 반복되면 전압 상승/감소가 반복되어 전극 열화도 발생한다. 막 내구성이 우수한 경우 전압 변화 횟수가 증가해, 전극 열화에 의해 평가가 종료되어 원래 목적인 막 내구성 평가를 할 수 없는 문제가 발생하기도 한다. 본 연구에서는 미국 에너지부 (DOE)와 동일한 프로토콜을 사용하되 cathode 가스로 공기대신 산소를 사용하고 가습/건조시간과 유량도 증가시켜 막의 화학적/기계적 열화 속도를 증가시켜서 고분자막 내구 평가 시간을 단축시킴으로서 이와 같은 문제를 개선하고자 하였다. Nafion 211 막전극접합체(MEA) 내구성 평가를 공기 대신 산소를 사용해서 가속화도를 2.6배 증가시켜 2,300 사이클만에 평가 종료하였다. 본 프로토콜에 의해 고분자막도 가속 열화되고, 전극 촉매도 가속 열화되어 고분자막과 전극의 내구성을 동시에 평가할 수 있는 이점도 있었다.

• Elastomers and Composites
• /
• 제45권4호
• /
• pp.291-297
• /
• 2010

차량에서 스트러트 인슐레이터는 도로노면으로부터 발생하는 소음과 진동을 방지하는 역할을 한다. 대부분의 점탄성 마운트들은 고무로 되어있으며 천연고무가 주성분이다. 이러한 고무 부품들은 초기에는 제 역할을 하지만 오랜 시간 고온과 반복하중에 노출되면 성능저하가 일어난다. 고무성능 변화는 NVH를 떨어뜨리고 승차감을 저하시킨다. 본 연구에서는 차량실험을 통해 스프링 변위를 측정하였고, 재현실험에서 가속도 센서를 이용하여 운행거리와 차량연식에 따른 인슐레이터 고무성능을 가속도 값, 고무 영구 변형량, 경도를 나타내었다.

• Corrosion Science and Technology
• /
• 제13권6호
• /
• pp.214-223
• /
• 2014

Interest in the durability assessment and structural performance has increased according to an increase of concrete structures in salt damage environment recent years. Reliable way ensuring the most accelerated corrosion test is a method of performing the rebar corrosion monitoring as exposed directly to the marine test site exposure. However, long-term exposure test has a disadvantage because of a long period of time. Therefore, many studies on reinforced concrete in salt damage environments have been developed as alternatives to replace this. However, accelerated corrosion test is appropriate to evaluate the critical chlorine concentration in the short term, but only accelerated test method, is not easy to get correct answer. Accuracy of correlation acceleration test depends on the period of the degree of exposure environments. Therefore, in this study, depending on the concrete mix material, by the test was performed on the basis of the composite degradation of the salt damage, and investigate the difference of corrosion initiation time of the rebar, and indoor corrosion time of the structure, of the marine environment of the actual environments were inuestigated. The correlation coefficient was derived in the experiment. Long-term exposure test was actually conducted in consideration of the exposure conditions submerged zone, splash zone and tidal zone. The accelerated corrosion tests were carried out by immersion conditions, and by the combined deterioration due to the carbonation and accelerated corrosion due to wet and dry condition.

• 한국철도학회논문집
• /
• 제9권6호
• /
• pp.717-724
• /
• 2006

The major objective of this study is to investigate the effects and application of improvement for railway steel plate girder bridge by resilient panel track system. It analyzed the mechanical behaviors of steel plate girder bridge with applying resilient panel track system on the finite element analysis and laboratory test for static & dynamic characteristics. As a result, the improvement of steel plate girder bridge with resilient panel track systems are obviously effective for the static & dynamic response which is non-ballast steel plate girder bridge. The analytical and experimental study are carried out to investigate resilient panel track system decrease vertical acceleration and deflection on steel plate girder bridge for serviceability. And the resilient panel track system reduced dynamic maximum displacements (about 59%) and stresses (about 82%), the increase of dynamic safety is predicted by adopting resilient panel track system. From the dynamic test results of steel plate girder bridge, it is investigated that vertical acceleration and deflection is very low with applying resilient panel track system. The servicing steel plate girder bridge with resilient panel track system has need of the reasonable improvement measures which could be reducing the effect of static and dynamic behavior that degradation phenomenon of structure by an unusual response characteristic and a drop durability.

• 한국철도학회:학술대회논문집
• /
• 한국철도학회 2006년도 추계학술대회 논문집
• /
• pp.437-446
• /
• 2006

The major objective of this study is to investigate the effects and application of improvement for railway steel plate girder bridge by resilient panel track system. It analyzed the mechanical behaviors of steel plate girder bridge with applying resilient panel track system on the finite element analysis and laboratory test for static & dynamic characteristics. As a result, the improvement of steel plate girder bridge with resilient panel track systems are obviously effective for the static & dynamic response which is non-ballast steel plate girder bridge. The analytical and experimental study are carried out to investigate resilient panel track system decrease vertical acceleration and deflection on steel plate girder bridge for serviceability. And the resilient panel track system reduced dynamic maximum displacements(about 59%) and stresses(about 82%), the increase of dynamic safety is predicted by adopting resilient panel track system. From the dynamic test results of steel plate girder bridge, it is investigated that vertical acceleration and deflection is very low with applying resilient panel track system. The servicing steel plate girder bridge with resilient panel track system has need of the reasonable improvement measures which could be reducing the effect of static and dynamic behavior that degradation phenomenon of structure by an unusual response characteristic and a drop durability.